• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1995년도 하계학술대회 논문집 C
• /
• pp.1317-1319
• /
• 1995

In this paper, we studied reduction characteristics of NOx gas produced from diesel engine combustion using by point-plane electrode. Here, input voltage forms were types of three [DC, AC, DC Positive pulse] and NOx gas of 1700ppm was composed of NO 1665ppm, $NO_2$ 35ppm on balance of $N_2$. We investigated NOx reduction characteristics as various of parameters, are gas flow rate, input voltage form and, humidity. From the results of study, reduction characteristics of NOx exhibited good when gas flow rate was small, input voltage was DC and much humidity were contained to NOx gas.

• 한국연소학회지
• /
• 제12권4호
• /
• pp.22-30
• /
• 2007

The NOx emission characteristics were studied in an oscillating combustion burner equipped with a specially designed proportioning valve. The effects of various parameters on the NOx emission which are important in oscillating combustion were investigated. Also, the effects of coincident application of flue gas recirculation(FGR) were evaluated. The results show that oscillating combustion is an efficient tool for reducing NOx in the burner. Up to 53% of NOx reduction could be acquired in low frequency and small duty ratio conditions. The coincident application of FGR further reduced the NOx emission up to 74%. Thus, this study assured that oscillating combustion technology with FGR could be a fascinating method for NOx reduction in industrial burners.

• Journal of Advanced Marine Engineering and Technology
• /
• 제29권6호
• /
• pp.628-636
• /
• 2005

In this paper. the effects of a WI(Water Injection) in the intake pipe for a 4-cylinder Dl(Direct Injection) diesel engine are investigated experimentally, The WI system was controlled by the duty cycle from the intake manifold's temperature and MAF(Manifold Air Flow) First. effect of EGR on NOx reduction was investigated. Then WI system was applied to reduce NOx As the results. we can make the NOx map and visualize the NOx results by variation of engine speed and engine load It was known that effect of WI system on NOx reduction without the EGR was better than the with EGR base engine except of low load and speed condition.

• 대한환경공학회지
• /
• 제22권11호
• /
• pp.1977-1983
• /
• 2000

천연가스를 사용하는 복합화력발전소에서 발생되는 질소산화물(NOx)에 대한 귀금속촉매(Pt/Zeolite)의 활성을 디젤유를 환원제로 사용하여 파일럿 규모의 선택적촉매환원장치(selective catalytic reduction)에서 환원제 주입량, 반응온도, 공간속도에 따라 고찰하였다. 시험결과, 디젤유의 주입량을 증가시킬수록 NOx의 전환율은 증가하였으며 C/N비(C/N비: 배기가스 중에 포함된 NOx의 분자수에 대한 환원제 탄소 원자수의 비) 5.5 이상에서는 일정한 전환율을 유지하였다. NOx 전환율에 대한 반응온도의 영향을 알아본 결과, 온도가 증가함에 따라 NOx의 전환율이 증가하여 $190^{\circ}C$의 온도에서 최고 50%의 전환율을 보였다. 7,200/hr~27,000/hr의 범위에서 NOx 전환율에 대한 공간속도의 영향은, 18,500/hr까지 일정한 전환율을 유지하였으며 그 이상에서는 감소하였다. 이상의 결과에서 디젤유를 환원제로 사용하는 질소산화물 제거를 위한 SCR 공정의 적용 가능성을 확인할 수 있었다.

• 한국해양환경ㆍ에너지학회지
• /
• 제7권2호
• /
• pp.57-63
• /
• 2004

본 논문에서는 국내 선박 디젤엔진의 NOx 배출 현황과 그 저감기술에 대해서 살펴보고자 하였다. 우선, 국내 선박 디젤엔진의 생산현황에 대해서 살펴보고, 다음으로 NOx 배출현황에 대해서 조사를 하였다. 마지막으로 NOx 배출 저감기술의 현황을 조사해 보았다. 본 연구를 통하여 국내에서 생산되는 선박용 디젤엔진이 IMO의 현재 NOx 배출 규제안을 만족하고 있는 것으로 파악이 되었다. 그러나 향후 더욱 엄격해질 IMO의 NOx 배출 규제안에 대응하기 위해서는 보다 더 고도화된 NOx저감기술의 개발이 필요할 것으로 예상된다.

• 해양환경안전학회지
• /
• 제28권7호
• /
• pp.1209-1215
• /
• 2022

선택적 촉매 환원법(SCR)은 질소산화물(NO_x)을 저감하는 매우 효율적인 방법으로 알려져 있으며 발생된 질소산화물(NO_x)을 질소(N₂)와 수증기(H₂O)로 환원시키는데 촉매 작용을 한다. 질소산화물(NO_x) 저감 성능을 결정하는 요소 중 하나인 촉매는 셀 밀도가 증가하면 촉매효율이 증가하는 것으로 알려져 있다. 본 연구에서는 실습선 세계로호에 설치되어 있는 발전 기관의 배기가스 조건을 모사한 실험장치를 통하여 100CPSI(60Cell)촉매의 부하에 따른 질소산화물(NO_x) 저감 성능을 확인하고 세계로호에 설치되어 있는 25.8CPSI(30Cell) 촉매의 기존 연구 자료와의 비교를 통해, 셀 밀도가 질소산화물(NO_x)의 저감에 미치는 영향에 대하여 고찰하였다. 실험용 촉매는 셀 밀도만 변화를 주었고 형태는 벌집형(honeycomb), 조성물질은 V₂O₅-WO₃-TiO₂를 동일하게 사용하여 제작하였다. 실험결과 100CPSI(60Cell) 촉매의 질소산화물(NO_x) 농도 저감율은 평균적으로 88.5%이며 IMO specific NOx 배출량은 0.99g/kwh로 IMO Tier III NOx 배출기준을 만족하였다. 25.8CPSI(30Cell) 촉매의 경우, 질소산화물(NO_x) 농도 저감율은 78%, IMO specific NOx 배출량은 2.00g/kwh 이었다 두 촉매의 NOx 농도 저감율과 IMO specific NOx 배출량을 비교하였을 때, 100CPSI(60Cell)촉매가 25.8CPSI(30Cell) 촉매보다, NOx 농도 저감율은 10.5% 높고 IMO specific NOx 배출량은 약 2배 적은 것을 확인하였다. 따라서 촉매의 셀 밀도를 높임으로써 효율적인 탈질효과를 기대할 수 있으며 향후 실선 테스트를 통하여 검증한다면 촉매의 부피 저감을 통한 제작 비용을 줄이고 협소한 선박 기관실을 효율적으로 사용하기 위한 실용적인 자료로서 기대된다.

• 한국대기환경학회지
• /
• 제6권1호
• /
• pp.31-42
• /
• 1990

In order to suggest an efficient catalyst systems for NOx reduction of flue gases from industrial boilers, $TiO_2$ supported $WO_3-V_2O_5, V_2O_5$ and $WS_2$ catalysts were tested for the performances of NOx reduction at high reactin temperature range (250-500$^\circ$C) using a simulated flue gas system. It was found that while the proposed $WO_3/TiO_2$ and $WO_3-V_2O_5/TiO_2$ catalysts showed a significant high NOx reduction efficiency at about 350-400$^\circ$C, the conventional commercial catalyst of $V_2O_5/TiO_2$ showed a significant drop in NOx reduction efficiency due to the excessive $NH_3$ oxidation. From the measurement of surface acidities of those catalysts, it was found that the acidity are well correlated with the activities of NOx reduction. The reason of high activity of $WO_3$ series catalysts at high reaction temperature seems due to the low value of surface excess oxygen compared with that of $V_2O_5/TiO_2$ seems equivalent to the acid site of that catalyst.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2008년도 추계학술대회B
• /
• pp.3096-3101
• /
• 2008

Selective Catalytic Reduction (SCR) technology is well-known to be effective for the reduction of NOx emission. So car manufacturers has adopted Ures-SCR system to be satisfied with emission regulation. This paper discusses the effective of $NH_3/NOx$ ratio and SCR catalyst temperature in the $NH_3$-SCR reactor on DeNOx performance. So it is shown the characteristic of NOx conversion and ammonia slip using the $NH_3$ instead of Urea-Solution. From the result of this study, it is found to optimize $NH_3/NOx$ ratio to have the best case of high NOx conversion and low ammonia slip at variable SCR catalyst temperatures. Lastly, it is also found the characteristics of NOx conversion and ammonia slip with compared with Urea.

• Bulletin of the Korean Chemical Society
• /
• 제17권10호
• /
• pp.885-892
• /
• 1996

The effects of NOx reduction by advanced fuel staging in a small scale combustor (6.6 kWT) have been investigated using propane gas flames laden with ammonia as fuel-nitrogen. The variables which had the greatest influence on NOx reduction were temperature, reducing stoichiometry (relate to main combustion zone stoichiometry, air fraction and reburning fuel fraction) and residence time of reducing zone. NOx reduction was best at the reburning zone temperature of above 1,000 ℃ and reburning zone stoichiometry was 0.85. In terms of residence time of the reburning zone, NOx reduction was effective when burnout air was injected at the point where the reburning zone had been already established. In the advanced fuel staging NOx reduction was relatively large at the burning of higher Fuel-N concentration in the fuel. Under optimum reburning conditions, fuel nitrogen content had a relatively minor impact on reburning efficiency.

• 한국연소학회지
• /
• 제14권4호
• /
• pp.17-24
• /
• 2009

Reburning is one of the most useful technologies for reducing nitric oxide in economically and technically. The reburning process was demonstrated as an effective NOx reduction method through injection of a secondary hydrocarbon fuel. An experimental study has been conducted to evaluate the effect of biomass reburning on NOx and CO formation in a light oil flamed combustion furnace. Reburning tests on NOx reduction of air-carried rice husk powder as the reburn fuel and light oil as the main fuel were performed in flames stabilized by a co-flow swirl and fuel staged burner, which was mounted at the front of the furnace. The results included flue gas emissions and temperature distribution in the furnace for several kinds of experimental conditions. It was observed clearly that NOx concentrations in the exhaust have considerably decreased due to effect of biomass reburning. The maximum NOx reduction rate was 42% when the reburn fuel fraction was 0.18. The CO emissions were kept under 42 ppmv in all experimental tests. And this paper makes clear that in order to decrease NOx concentration in the exhaust when the biomass reburning system is adapted, the control of some factors such as reburn fuel fraction and reburn zone fraction is very important.