• 한국연소학회:학술대회논문집
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• 한국연소학회 2000년도 제20회 KOSCO SYMPOSIUM 논문집
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• pp.26-34
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• 2000

Geometry change of burner nozzle has influence on fuel atomizing and combustion characteristics. NOx reduction technologies can be divided into two method; Before combustion method(NOx treatment of fuel) and After combustion method(NOx treatment of flue gas). In this study, experiments are carried out using difference nozzle and combustion condition change to reduce NOx in heavy oil fired thermal utility boiler. These methods have advantage like easy application and low installation cost. By this method NOx can be reduced by 18% and maintain CO emission level.

• Korean Chemical Engineering Research
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• 제47권1호
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• pp.111-118
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• 2009

Hybrid SNCR/SCR 공정개발을 위해 $1,000\;Nm^3/hr$ 용량의 실증 플랜트를 제작하였다. 1단계로 SNCR의 최적운전 조건을 규명하기위해 환원제의 당량비(NSR, 0.5~5.0), 반응온도($850{\sim}1,100^{\circ}C$), 노즐형태(벽노즐, 관통노즐), 노즐위치를 변수로 SNCR 실험하였다. 벽노즐은 NSR 2.5에서 87%까지 NOx 저감효율이 급증하고 이후 증가 폭이 둔화되었다. 관통노즐 상향분사와 비교해, 적용 가능한 반응온도 범위도 적었다. 관통노즐 상향은 NSR 1.5에서 77%까지 NOx 저감효율이 급증되는 현상을 보였다. 그러나 관통노즐 하향은 NOx 저감효과가 없을 뿐만 아니라 오히려 NOx 발생이 증가하였다. 관통노즐에서 환원제를 상향분사했을 때, NSR 0.5~1.5 범위에서 NOx 저감효율은 50~75%로 나타났고, $890{\sim}1,000^{\circ}C$ 범위의 반응온도변화에도 NOx 저감효율의 증감없이 일정한 효율을 보였다. Urea 5% 용액을 NSR 1.2 에서 관통노즐로 상향 분사했을 때 이며, 이때 200 ppm의 NOx가 약 60 ppm으로 저감되고, 미반응 $NH_3$는 50~100 ppm이었다. 이 조건에서 SNCR 후단의 SCR에 추가적인 $NH_3$ 공급 없이도 90 % 이상의 NOx 저감효율이 기대된다.

• 한국자동차공학회논문집
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• 제17권2호
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• pp.180-186
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• 2009

To meet the NOx limit without a penalty of fuel consumption, urea SCR system is currently regarded as promising NOx reduction technology for diesel engines. SCR system has to achieve maximal NOx conversion in combination with minimal $NH_3$ slip. In this study, as a basic research to develop an algorithm for urea injection control, the characteristics of engine out NOx emission and behavior of NOx reduction during steady-state and transient conditions were investigated using 2L DI diesel engine. Test results show that on increasing the catalyst temperature the variations in the outlet NOx concentration are faster and maximal allowable $NH_3$ storage exponentially decreases. For change from a low to high engine load, it can be seen that a few seconds after load-step is required to reach full NOx conversion and the adsorbed amount of $NH_3$ at lower temperature desorb during the next temperature increase, causing $NH_3$ slip. Engine out NOx emission needs to be corrected because NOx emissions just after step load is lower than that of steay state condition.

• 한국연소학회지
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• 제4권2호
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• pp.97-108
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• 1999

This numerical study was to investigate the effect of $CO_2$ addition on the structures and NOx formation characteristics in $CH_4$ counterflow diffusion flame. The importance of radiation effect was identified and $CO_2$ addition effect was investigated in terms of thermal and chemical reaction effect. Also the causes of NOx reduction were clarified by separation method of each formation mechanisms. The results were as follows : The radiation effect was intensified by $CO_2$ addition. Thermal effect mainly contributed to the changes in flame structure and the amount of NO formation but the chemical reaction effect also cannot be neglected. The reduction of thermal NO was dominant with respect to reduction rate, but that of prompt NO was dominant with respect to total amount.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2001년도 춘계학술대회 논문집
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• pp.187-191
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• 2001

In the paper, an approach to the development of the selective catalytic reduction process of NOx is presented. The reduction process can be efficiently controlled using a conventional combination of feed-forward and feed-back control structures. The aim of this paper is to test and verify an approach to the SCR process which is based on an industrial pilot plant of combustion and nitric oxide formation. The systems are based on measurements of a NOx removal ratio and the fuel flow rate, and NH$_3$slip which are usually available as a part of de-NOx control system.

• Journal of Advanced Marine Engineering and Technology
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• 제27권3호
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• pp.373-380
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• 2003

According to the NOx regulations of annex Vi to IMO MARPOL 73/78, all diesel engines with a power output of more than 130 kW should be delivered so as to comply with the IMO speed dependent NOx limit. It is inevitable to adopt this regulations for marine engines Therefore, most of diesel engines which are being currently built should be designed and tested in accordance with the NOx technical code In this study, NOx concentrations of 4 type engines were measured with portable NOx measuring system recommended by ISO-8178. As the results NOx concentrations of each engine by variation of engine speed and engine load were visualized Also these results can be utilized for the basic design and development of diesel engine for NOx reduction.

• Journal of Biosystems Engineering
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• 제24권6호
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• pp.465-472
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• 1999

To remove nitrogen oxides(NOx) in exhaust gas of diesel engine, three-way catalytic process with plasma discharger has great possibilities. Characteristics of NOx removal depends on NO conversion to NO$_2$and/or HNO$_3$due to high activation energies for NO oxidation and reduction. NOx removal efficiency by using three-way catalytic with plasma discharger indicated about 50% at 40watt power consumption condition.

• 한국자동차공학회논문집
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• 제7권8호
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• pp.83-90
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• 1999

To remove nitrogen oxides(NOx) in exhaust gas of diesel engine, three-way catalytic process with plasma discharger has great possbilities. Characteristics of NOx removal depends on NO conversion to $NO_2$ and/or $HNO_3$ due to high activation energies for NO oxidationand reduction. NOx removal efficiency by using three-way catalytic with plasma dischager indicated about 50% at 40 watt power consumption condition.

• 융복합기술연구소 논문집
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• 제7권1호
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• pp.15-18
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• 2017

As emission gas regulation of deisel vehicles is strengthened to Euro-6, It becomes difficult to deal with NOx regulated value mainly by EGR without additional after-treatment system. In addition, RDE(Real Driving Emissions) test will be introduced after september 2017. Therefore, It is essential to develop the after-treatment of diesel vehicles which reduce NOx emissions. It is possible to use DOC, DPF, LNT or DOC, DPF and SCR as a after-treatment system for reducing NOx. However, It is expected that the SCR will be applied widely because LNT alone does not have sufficient NOx purification efficiency. In this study, It tried to analyze the efficiency of reducing NOx emissions during the mode test by attaching a NOx sensor to test vehicle. As a result, It was confirmed that NOx emissions was significantly reduce through the after-treatment system from engine. And the NOx reduction efficiency of SCR was about 4.5 times better than DOC, DPF.

• 한국재료학회지
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• 제16권5호
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• pp.323-328
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• 2006

In situ electrical conductivity measurements on $V_2O_5WO_3/TiO_2$ catalysts were carried out at between 100 and $300^{\circ}C$ under pure oxygen, NO and $NH_3$ to investigate the reaction mechanism for ammonia SCR (selective catalytic reduction) de NOX. The electrical conductivity of catalysts changed irregularly with supply of NO. It was, however, found that the electrical conductivity change with ammonia supply was regular and the increase of electrical conductivity was mainly caused by reduction of the labile surface oxygen. The electrical conductivity change of catalysts showed close relationship with the conversion rate of NOx. Variation of conversion rate in atmosphere without gaseous oxygen also showed that labile lattice oxygen is indispensable in the initial stage of the de NOx reaction. These results suggest that liable lattice oxygen acts decisive role in the de NOx mechanism. They also support that de NOx reaction occurs through the Eley?Rideal type mechanism. The amount of labile oxygen can be estimated from the measurement of electrical conductivity change for catalysts with ammonia supply. This suggests that measurement of the change can be used as a measure of the de NOx performance.