• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.2
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• pp.225-232
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• 2012

A chemical reactor network (CRN) was developed for a lean premixed gas turbine combustor to predict the emission of pollutants such as NOx and CO. In this study, the predictions of NOx and CO emissions from lean premixed methane-air combustion in the gas turbine were carried out using CHEMKIN and a GRI 3.0 methane-air combustion mechanism, which includes the four NO formation mechanisms for various load conditions. The calculated results were compared with experimental data obtained from a modified test combustor to validate the model. The contributions of the four NO pathways were investigated for various load conditions. The effects of nonuniformity of the mass flux and of the equivalence ratio of the injector on the NOx formation were investigated, and a method of reducing the pollutant formation was suggested for the development of a sub-10 ppm gas turbine combustor.

• 한국연소학회:학술대회논문집
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• 2002.06a
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• pp.185-191
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• 2002

The influence of N2 addition on soot formation, flame temperature and NOx emissions is investigated experimentally with methane fuel co-flow diffusion flames. The motivation of the present investigation is the differences in NOx reduction reported between fuel-side and oxidizer-side introduction of N2. To determine the influence of dilution alone, fuel was diluted with nitrogen while keeping the adiabatic flame temperature fixed by changing the temperature of the reactants. And to see the thermal effect only, air was supplied at different temperature without N2 addition. N2 addition into fuel side suppressed the soot formation than the case of oxidizer-side, while flame temperature enhanced the soot formation almost linearly. These results reveals the relative influences of the thermal, concentration effects of N2 additives on soot formation In accordance with experimental study, numerical simulation using CHEMKIN code was carried out to compare the temperature results with those acquired by CARS measurement, and we could find that there is good agreement between those results. Emission test revealed that NOx emissions were affected by not only flame temperature but also N2 addition.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.3108-3113
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• 2008

This paper investigated the behaviors of combustion characteristics at part load condition with various intake charge motions induced by the port masking schemes in the CVVT (Continuously Variable valve Timing) engine. Time resolved in-cylinder and exhaust emissions were measured by the fast response HC and NOx analyzers to examine their formation mechanisms and behavior characteristics. As a result, in-cylinder HC decreased with the advanced intake valve timings but HC at the exhaust port increased due to the worse combustion stabilities. However HC reduction could be achieved by the application of the port maskings with a enhancement of the engine stability. NOx also decreased with early intake timings by internal EGR but increased with the charge motion controls which enhance the combustion behavior.

• The Plant Pathology Journal
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• v.38 no.4
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• pp.345-354
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• 2022

NADPH oxidase (Nox) complexes are known to play essential roles in differentiation and proliferation of many filamentous fungi. However, the functions of Noxs have not been elucidated in Colletotrichum species. Therefore, we set out to characterize the roles of Nox enzymes and their regulators in Colletotrichum scovillei, which causes serious anthracnose disease on pepper fruits in temperate and subtropical and temperate region. In this study, we generated targeted deletion mutants for CsNox1, CsNox2, CsNoxR, and CsNoxD via homologous recombination. All deletion mutants were normal in mycelial growth, conidiation, conidial germination, and appressorium formation, suggesting that CsNox1, CsNox2, CsNoxR, and CsNoxD are not involved in those developmental processes. Notably, conidia of 𝜟Csnox2 and 𝜟Csnoxr, other than 𝜟Csnox1 and 𝜟Csnoxd, failed to cause anthracnose on intact pepper fruits. However, they still caused normal disease on wounded pepper fruits, suggesting that Csnox2 and CsnoxR are essential for penetration-related morphogenesis in C. scovillei. Further observation proved that 𝜟Csnox2 and 𝜟Csnoxr were unable to form penetration peg, while they fully developed appressoria, revealing that defect of anthracnose development by 𝜟Csnox2 and 𝜟Csnoxr resulted from failure in penetration peg formation. Our results suggest that CsNox2 and CsNoxR are critical for appressorium-mediated penetration in C. scovillei-pepper fruit pathosystem, which provides insight into understanding roles of Nox genes in anthracnose disease development.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.5
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• pp.659-669
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• 1997

The effects of exhaust gas recirculation on diesel engine combustion and soot/NOx emissions are numerically studied. The primary and secondary atomization is modelled using the wave instability breakup model. Autoignition of a diesel spray is modelled using the Shell ignition model. Soot formation is kinetically controlled and soot oxidation is represented by a model which account for surface chemistry. The NOx formation is based on the extended Zeldovich NOx model. Effects of injection timing and concentration of $O_{2}$ and CO$_{2}$ on the pollutant formation and the combustion process are discussed in detail.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2005.11a
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• pp.13-14
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• 2005

Multi-dimensional combustion analysis and experiment has been carried out to investigate the effects of the injector nozzle hole diameter and number on the NOx formation and fuel consumption in HYUNDAI HiMSEN engine. The behavior of spray and combustion phenomena in diesel engine was examined by FIRE code. Wave breakup and Zeldovich models were adopted to describe the atomization characteristics and NOx formation. Wallfilm model suggested by Mundo, et al. and auto-ignition model suggested by Theobald and Cheng were adopted to investigate the spray-wall interaction characteristics and ignition delay. The information of spray angle and spray tip penetration length was extracted from fuel spray visualization experiment and the fuel injection rate profile was extracted from fuel injection system experiment as an input and verification data for the combustion analysis. Next, the nine different nozzle configurations were simulated to evaluate the effect of injector hole diameter and number on the NOx formation and fuel consumption.

• Journal of the Korean Society of Combustion
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• v.12 no.4
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• pp.14-21
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• 2007

In order to enhance combustion efficiency, oxygen-enriched combustion is used by increasing the oxygen ratio in the oxidizer. However, since the flame temperature increases, NOx formation in the furnace seriously increases for low oxygen enrichment ratio. In this case, reburning is a useful technology for reducing nitric oxide. In this research, experimental studies have been conducted to evaluate the hybrid effects of reburning/selective non-catalytic reaction (SNCR) and reburning/air staging on NOx formation and also to examine heat transfer characteristics in various oxygen-enriched LPG flames. Experiments were performed in flames stabilized by a co-flow swirl burner, which were mounted at the bottom of the furnace. Tests were conducted using LPG gas as main fuel and also as reburn fuel. The paper reported data on flue gas emissions, temperature distribution in furnace and various heat fluxes at the wall for a wide range of experimental conditions. Overall temperature in the furnace, heat fluxes to the wall and NOx generation were observed to increase by low level oxygen-enriched combustion, but due to its hybrid effects of reburning, SNCR and Air staging, NOx concentration in the exhaust have decreased considerably.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.3007-3012
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• 2008

Multidimensional simulation has been carried out to be clear the role of initial combustion in a marine diesel engines on reduction of NOx and soot emissions by different pilot injection condition. Pilot injection can shorten the ignition delay, thus it reduces the premixed combustion phase. Since most NOx is formed during premixed combustion, pilot injections is one of reliable strategies to reduce the NOx. The formation of NOx consists of that formed by pilot injection and that formed by main injection. The result explains that 25-3-75 among the pilot injection conditions is effective to reduce the NOx, due to optimal combination pilot injection with main injection. The purpose of this study is to explain the characteristics of combustion with pilot injection of the marine diesel engine on reduction of exhaust emissions by examining the combustion process in a cylinder and to explore the formation mechanism of NOx between pilot injection and main injection.

• Clean Technology
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• v.14 no.2
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• pp.117-122
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• 2008

Theoretical analysis was conducted on the combustion and the NOx formation characteristics of the coal-derived synthetic gases with medium-BTU heating value. The synthetic gas was assumed to contain the major species of CO, $H_2,\;CO_2$, and $N_2$ and the minor species of $CH_4$ and $NH_3$. Through thermochemical analysis on the combustion of the synthetic gas, the flame temperature, major and minor species of exhaust gas, and thermal and fuel NOx emissions were computed. In addition, the effects of the $CH_4$ and the $NH_3$ components in syngas fuel on combustion and NOx emission were investigated. Based on the computed results on the synthetic gases, basic direction and guidelines were provided fur the low NOx design of gas turbine combustor.

• Journal of Environmental Science International
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• v.16 no.1
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• pp.1-8
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• 2007

Atmospheric photochemistry of $O_3-NOx-RH$ were considered theoretically, to clarify the reasons for the different trends of between the formation of photochemical oxidants (Ox) and its primary pollutants for the Low-and High-NOx regimes. Equations of OH, $HO_2$, and production of ozone ($O_3$) as a function of nitrogen oxides (NOx) and reactive hydrocarbons (RH) were represented in this study. For the Low-NOx regime, $HO_2$ radical is proportional to RH but independent of NOx. OH radical is proportional to NOx but inversely-proportional to RH. $O_3$ production is proportional to NOx but has a weak dependence on RH. For the High-NOx regime, OH and $HO_2$ radicals concentrations and $O_3$ production are proportional to RH but inversely-proportional to NOx. In addition, the Osaka Bay and surrounding areas of Japan were evaluated with the mass balance of odd-hydrogen radicals (Odd-H) using CBM-IV photochemical mechanism, in order to distinguish the Low- and High-NOx regimes. The Harima area (emission ratio, RH/NOx = 6.1) was classified to the Low-NOx regime. The Hanshin area (RH/NOx = 3.5) and Osaka area (RH/NOx = 4.3) were classified to the High-NOx regime.