• Title/Summary/Keyword: NOx

Search Result 2,533, Processing Time 0.115 seconds

An Experimental Study on the Combustion Characteristics in Low Emission Multi-Staged Oil Burner (다단연소를 이용한 저 NOx 버너의 연소특성에 관한 연구)

  • An, Guk-Yeong;Kim, Han-Seok;Jo, Eun-Seong
    • 연구논문집
    • /
    • s.27
    • /
    • pp.101-108
    • /
    • 1997
  • The characteristics of combustion and emissions in multi-staged oil burner have been experimentally studied for the various range of equivalence ratios, drop sizes and fuel formulations. Malvern system was used to measure droplet size of fuel. Light fuel oil and light fuel oil doped with pyridine($C_5H _5N$) were used to investigate the effects on fuel NOx emission. The emissions of NO and CO in exhaust gas and the flame temperatures were measured by the gas analyzer and thennocouples. NOx emissions were increased by increasing the excess air ratio (range:$lambda=1.1-1.4$) or decreasing the SMD of droplet in single-staged burner. In comparison with the single-staged burner, the emission of NOx in multi-staged burner was reduced by 50% but CO emission was slightly increased. It is found that multi-staged burner has a good capability in reducing thermal NOx resulting from the distributed heat release rate and lower flame temperature in fuel-rich and fuel-lean combustion zone. Moreover, the fuel NOx emission of the multi-staged burner is lower than that of single-staged burner, because multi-staged burner has fuel rich zone where fuel N is converted to $N_2$ more than NO. In 3-staged burner, the percentage of each stage combustion air have strong influence on emission characteristics. It is also found that NOx emission can be reduced by decreasing inner and outer air percentage or increasing middle air flow rate and CO emission is vice versa.

  • PDF

NOx Formation Characteristics of the Coal-derived Synthetic Gas Containing $CH_4$ and $NH_3$ Components (메탄 및 암모니아를 포함하는 석탄 합성가스의 NOx 발생 특성)

  • Lee, Chan
    • Clean Technology
    • /
    • v.14 no.2
    • /
    • pp.117-122
    • /
    • 2008
  • Theoretical analysis was conducted on the combustion and the NOx formation characteristics of the coal-derived synthetic gases with medium-BTU heating value. The synthetic gas was assumed to contain the major species of CO, $H_2,\;CO_2$, and $N_2$ and the minor species of $CH_4$ and $NH_3$. Through thermochemical analysis on the combustion of the synthetic gas, the flame temperature, major and minor species of exhaust gas, and thermal and fuel NOx emissions were computed. In addition, the effects of the $CH_4$ and the $NH_3$ components in syngas fuel on combustion and NOx emission were investigated. Based on the computed results on the synthetic gases, basic direction and guidelines were provided fur the low NOx design of gas turbine combustor.

  • PDF

Effect of Dielectrics on NOx Removal of Metal Particle-AI2O3 Barrier Reactor (금속파티클-AI2O3Barrier 반응기의 NOx 제거에 미치는 유전체 영향)

  • 박재윤;김종석;고희석;김형만;배명환
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.16 no.3
    • /
    • pp.247-252
    • /
    • 2003
  • In this paper, we made four types of metal particle $Al_2$O$_3$ barrier reactors with and without dielectric of BaTiO$_3$ between metal particle and $Al_2$O$_3$ barrier to investigate NOx removal characteristic and the effect of dielectric on Nox removal. And Nox removal rate is measured when sludge pellets are put at down stream of plasma reactor. Nox removal rate in the reactor with $Al_2$O$_3$ barrier is much better than that in the reactor without $Al_2$O$_3$ barrier, Nox removal rate is not so good in metal particle-Al$_2$O$_3$ barrier reactor with BaTiO$_3$ between metal particle and $Al_2$O$_3$ barrier, however, Nox removal rate is about 40% in metal particle-Al$_2$O$_3$ barrier reactor with TiO$_2$. The most of NO is conversed to NO$_2$ in these kind of reactor. When sludge pellets are put at down stream of plasma reactor, Nox removal rate is greatly improved up to 90%. It indicates that sludge pellets have great effect on the NO$_2$ removal and the improvement of Nox removal rate, however, dielectric materials between metal particle and $Al_2$O$_3$ barrier have not effect. Organic materials included in sludge may react with NO$_2$ and ozone so that Nox removal rate is greatly improved.

The Effect of Supply Patterns of Overfire Air on Generation of NOX and CO in a Wood pellet Fired Boiler (우드펠릿 보일러에서 2단 연소용 공기 공급방식이 질소산화물 및 일산화탄소 발생에 미치는 영향)

  • Jung, Kwang-sung;Yoo, Hoseon
    • Plant Journal
    • /
    • v.15 no.3
    • /
    • pp.35-41
    • /
    • 2019
  • In this study, we investigated the effect of the generation of NOx and CO by adjusting the overfire air supply position and ratio using the boiler that was converted from coal burning to wood pellet boiler. When the amount of the overfire air is relatively increased, the amount of NOx is slightly decreased but CO is sharply decreased when burning at low excess air ratio (1.10) that is due to a small fuel particle size. However, NOx slightly increased when burning at high excess air ratio (1.33) due to the large fuel size, but CO was hardly affected. Also, When the amount of overfire air was same, The more supply position was concentrated to upper portion of the main combustor, the more NOx and CO was lowered. And in case of the excess air ratio was high, the generation of NOx and CO I can see that it keeps the level irrelevant to the amount of air for the second stage combustion.

Evaluation of the Removal Performance of Nitrogen Oxides of Foam Composites Using Activated Carbon and Titanium Dioxide (활성탄소와 이산화 타이타늄을 활용한 폼 복합체의 질소산화물의 제거 성능 평가)

  • Choi, Hyun-Chul;Choi, Young-Cheol
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.26 no.6
    • /
    • pp.120-127
    • /
    • 2022
  • Nitrogen oxide(NOx) is a major cause of air pollution, exists in the form of nitrogen monoxide and nitrogen dioxide, and is harmful to the human body. Recently, a number of studies to reduce NOx in the atmosphere have been conducted, and these efforts have been the same in the field of construction materials. It is known that NOx can be efficiently removed by using a photocatalytic reaction. In this study, the NOx removal performance of the foam composite using activated carbon(AC) and titanium dioxide(TiO2) was investigated. AC was used to enhance the photocatalytic reaction of TiO2 by increasing the internal specific surface area of the foam composite. In this study, foam composites were prepared using the substitution rate of AC as the main variable. The NOx removal performance of specimen was evaluated according to the test method presented in ISO-22197-1. The specific surface area of the foam composite showed a tendency to increase according to the AC content, but decreased at 15% or more. Also, when the AC substitution rate was 15%, the NOx removal efficiency was the highest.

Case Study on NOx Emissions from Cement Kiln before and after Applying Multi-stage Combustion Technology (다단연소 기술 적용 전후 시멘트 소성설비의 NOx 배출 사례 연구)

  • Jae-Won, Choi;Ju-Ik Back;Jang-Jung Kim;Phil-Sung Won
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.11 no.3
    • /
    • pp.267-275
    • /
    • 2023
  • The cement industry has been contributing to solve the wastes problem by using various combustible wastes as alternative fuel to replace natural coal. To use more alternative fuels such as waste plastics, in the cement manufacturing process, it is necessary to stably burn alternative fuels and reduce air emissions such as NOx. This study is a case study on the multi-stage combustion calciner process, which is a technology that decreases the amount of NOx while increasing the use of alternative fuels. This study is a case study on the multi-stage combustion process, a technology that reduces the amount of harmful air emissions such as NOx while increasing the use of alternative fuels. Along results of comparing before and after applying the technology to actual cement manufacturing facilities, the amount of coal consumption decreased by 38 %, waste plastics consumption increased by 122 %, and NOx emissions decreased by 17 %. Results show that increasing the use of alternative fuels and reducing NOx emissions by multi-stage combustion is effective.

Lean Burn de-NOx Properties of Pt-TiO2 Bifunctioncal Catalyst by Propylene (희박연소 상태에서 프로필렌 환원제에 의한 Pt-TiO2 이원기능 촉매의 NOx 제거 특성)

  • Jeong, Tae-Seop;Chae, Soo-Cheon
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.22 no.3
    • /
    • pp.511-521
    • /
    • 2000
  • Investigation was carried out lean burn de-NOx properties of Pt-$TiO_2$ bifunctional catalyst by propylene in order to get the high de-NOx activity and the wide temperature window under coexistence of $SO_2$ and $H_2O$. Only noncatalyst and carrier catalyst themselves had NOx conversion activity at high temperature over $400^{\circ}C$. NOx conversion activity of catalysts exchanged copper ion resulted in Cu-$TiO_2$>Cu-ZSM-5>Cu-$Al_2O_3$>CU-YZ>Cu-AZ. Catalysts impregnated with platinum based on titania gave the results of high NOx conversion activity at low temperature. $250^{\circ}C$. Bifunctional catalysts based on Pt-$TiO_2$ showed high NOx conversion activity both at a low zone of $300^{\circ}C$ and a high zone of $500^{\circ}C$. Pt-$TiO_2$/$Al_2O_3$ catalyst gave the highest NOx conversion activity at a low temperature zone. and Pt-$TiO_2$/$Mn_2O_3$(21) catalyst gave the highest NOx conversion activity at a high temperature zone. Under the coexistence of $SO_2$ and $H_2O$. NOx conversion activities of 0.55wt%Pt-$TiO_2$/5wt%Cu-ZSM-5 catalyst was high both at a low and high temperature zone, and increased depending on oxygen concentration. 0.55wt%Pt-$TiO_2$/5wt%Cu-ZSM-5 catalyst showed the best correlation between de-NOx activities and the propyl ere conversion rates to CO on the log function.

  • PDF

Estimating On-road NOx Emissions of Euro 6 Light-duty Diesel Vehicles (Euro6 소형 경유자동차의 실제 도로 주행 NOx 배출량 평가)

  • Park, Yeon-Jae;Park, Junhong;Lee, Jai-Young
    • Journal of ILASS-Korea
    • /
    • v.21 no.4
    • /
    • pp.207-213
    • /
    • 2016
  • To protect air pollution of urban area from motor vehicles, emission limits for diesel vehicles have been dramatically lowered in short period. But recent studies have shown that on-road NOx emissions of light-duty diesel vehicles are considerably higher than the values measured with laboratory test procedures used for emission certification. To tackle with this issue, Ministry of Environment have a plan to introduce EU RDE-LDV (Real-driving Emission-Light-duty Vehicle) regulation. In this study, 4 Euro 6 diesel vehicles have been tested with the new test procedures published by EU to estimate on-road NOx emissions using PEMS (Portable Emission Measurement System). The results have shown that the requirements of EU RDE-LDV could be met in driving condition of metropolitan area for constitution of test routes and validity of test results. In analysing with Moving Averaging Window method the completeness and normality of test data were validated with the requirement. On-road NOx emissions were quite deviated as test vehicles and higher than the new limit of on-road NOx emission enforced from Sept. 2017, which means that RDE-LDV can effectively reduce NOx emission of diesel vehicles in real driving conditions of Korea.

NOx Emission Characteristics of Diesel Passenger Cars Met Euro 6a, 6b and 6d Regulations on Off-cycles (Off-cycle에서 Euro 6a, 6b 및 6d 규제 만족 디젤 자동차의 NOx 배출 특성)

  • Kim, Jeonghwan;Kim, Sungwoo;Kim, Kiho
    • Journal of ILASS-Korea
    • /
    • v.23 no.3
    • /
    • pp.136-148
    • /
    • 2018
  • Major countries have tighten their NOx regulation of diesel passenger cars. In the case of the EU, the regulation has been toughen up to 6.25 times since 2000. Despite the regulation the NOx concentration of the ambient has not been reduced proportionally. As these issues, to reduce NOx emission practically, Korea and the EU introduced the real-world driving emission (RDE) regulation and the test method that will be applied after 2017. In this paper, for the regulation to make a soft landing in Korea, 6 diesel passenger cars which met Euro 6a~6d regulation and were equipped with LNT/SCR were tested at a chassis dynamometer with environmental chamber applying the off-cycles (FTP, US06, SC03, HWFET and CADC) and several ambient conditions (-7 and $14^{\circ}C$) as well as certification modes (NEDC, WLTC@ $23^{\circ}C$). The result of the test showed that the ambient temp. and the engine load as a test mode impacted the NOx emission of the cars while the vehicles with SCR emitted NOx lower than with LNT. Additionally, to propose an effective RDE test method, the above result was compared with the results of the other papers which tested RDE using the same cars.

In Silico Sequence Analysis Reveals New Characteristics of Fungal NADPH Oxidase Genes

  • Detry, Nicolas;Choi, Jaeyoung;Kuo, Hsiao-Che;Asiegbu, Fred O.;Lee, Yong-Hwan
    • Mycobiology
    • /
    • v.42 no.3
    • /
    • pp.241-248
    • /
    • 2014
  • NADPH oxidases (Noxes), transmembrane proteins found in most eukaryotic species, generate reactive oxygen species and are thereby involved in essential biological processes. However, the fact that genes encoding ferric reductases and ferric-chelate reductases share high sequence similarities and domains with Nox genes represents a challenge for bioinformatic approaches used to identify Nox-encoding genes. Further, most studies on fungal Nox genes have focused mainly on functionality, rather than sequence properties, and consequently clear differentiation among the various Nox isoforms has not been achieved. We conducted an extensive sequence analysis to identify putative Nox genes among 34 eukaryotes, including 28 fungal genomes and one Oomycota genome. Analyses were performed with respect to phylogeny, transmembrane helices, di-histidine distance and glycosylation. Our analyses indicate that the sequence properties of fungal Nox genes are different from those of human and plant Nox genes, thus providing novel insight that will enable more accurate identification and characterization of fungal Nox genes.