• Title/Summary/Keyword: NOx(Nitrogen Oxides)

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Emissions of Marine Heavy Fuel Oil in the Spray Flame

  • An, Suk-Heon
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.7
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    • pp.1030-1035
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    • 2008
  • Recently, the International Maritime Organization makes an effort for an effective solution against the emissions from shipping in the international maritime industry. The objective of the study was to quantify the exhaust emissions of marine heavy fuel oil in the combustion process of the spray flame. An experiment was performed to measure CO, $CO_2$, NOx, $SO_2$, ${N_2}O$, DS, SOF and the other components with the flame temperature. The sampling probe was directly set up in the flame fields at each position of 103, 324, 545, 766 and 987mm vertically apart from the fuel-injected nozzle in the burner furnace. From the results of the study, it was estimated that approximately 270ppm of oxides of nitrogen (NOx), $1000{\sim}1400ppm$ of sulfur dioxide ($SO_2$), 8ppm of nitrous oxide (${N_2}O$), $2.0{\sim}2.5g/m^3$ of particulate matter (PM) divided with dry soot (DS) and soluble organic fraction (SOF) and $60{\sim}80mg/m^3$ of sulfuric acid. With respect to further development of this work, the emission quantification could also be applied to assessing emission reduction from the international shipping.

A Study on the Combustion and Exhaust Emission Characteristics with the Variations of Mixing and Air-fuel Ratio of Bio-ethanol - Gasoline in a SI Engine (SI엔진에서 바이오에탄올-가솔린 혼합율 및 공연비 변화에 따른 연소 및 배기배출물 특성에 관한 연구)

  • Yoon, Seunghyun;Ha, Sungyong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.24 no.3
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    • pp.358-364
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    • 2016
  • The combustion and exhaust emission characteristics in a spark ignition (SI) engine with various test fuels (bioethanol - gasoline blends) and air-fuel ratio were investigated in this research. To investigate the influence of the excess air ratio and ethanol blends on the combustion characteristics such as the cylinder pressure, rate of heat release (ROHR), and fuel consumption rate were analyzed. In addition, the reduction effects of exhaust emissions such as carbon monoxide (CO), unburned hydrocarbon (HC), and oxides of nitrogen (NOx) were compared with those of neat gasoline fuel under the various excess-air ratios. The results showed that the peak combustion pressures and the ROHR of bioethanol fuel cases were slightly higher than those of gasoline fuel at all test ranges and fuel ratio. As compared with gasoline fuel (G100) at each given excess air ratio, BSFC of bio-ethanol was increased. The CO, HC, NOx emissions of bio-ethanol blends were lower than those of gasoline fuel under overall experimental conditions.

Services of Algae to the Environment

  • Rai, Lal-Chand;Har Darshan Kumar;Frieder Helmut Mohn;Carl Johannas Soeder
    • Journal of Microbiology and Biotechnology
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    • v.10 no.2
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    • pp.119-136
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    • 2000
  • Being autotrophic, algae occupy a trategic place in the biosphere. They produce oxygen both directly and indirectly through the chloroplasts of all green plants. The chloroplasts are believed to have originated from archaic prokaryotic algae through endosymbiosis with primitive eukaryotic cells. Phytoplankton and other algae regulate the global environment not only by releasing oxygen but also by fixing carbon dioxide. They affect water quality, help in the treatment of sewage, and produce biomass. They can be used to produce hydrogen which is a clean fuel, and biodiesel, and fix $N_2$ for use as a biofertilizer. Some other services of algae to the environment include restoration of metal damaged ecosystems, reducing the atmospheric $CO_2$ load and citigating global warming, reclamation of saline-alkaline unfertile lands, and production of dimethyl sulphide (DMS) and oxides of nitrogen (NOx) involved in the regulation of UV radiation. ozone concentration, and global warming. Algae can be valuable in understanding and resolving certain environmental issues.

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Numerical Analysis of Flow Uniformity in Selective Catalytic Reduction (SCR) Process Using Computational Fluid Dynamics (CFD)

  • Shon, Byung-Hyun
    • International Journal of Advanced Culture Technology
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    • v.10 no.3
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    • pp.295-306
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    • 2022
  • The NOx removal performance of the SCR process depends on various factors such as catalytic factors (catalyst composition, shape, space velocity, etc.), temperature and flow rate distribution of the exhaust gas. Among them, the uniformity of the flow flowing into the catalyst bed plays the most important role. In this study, the flow characteristics in the SCR reactor in the design stage were simulated using a three-dimensional numerical analysis technique to confirm the uniformity of the airflow. Due to the limitation of the installation space, the shape of the inlet duct was compared with the two types of inlet duct shape because there were many curved sections of the inlet duct and the duct size margin was not large. The effect of inlet duct shape, guide vane or mixer installation, and venturi shape change on SCR reactor internal flow, airflow uniformity, and space utilization rate of ammonia concentration were studied. It was found that the uniformity of the airflow reaching the catalyst layer was greatly improved when an inlet duct with a shape that could suppress drift was applied and guide vanes were installed in the curved part of the inlet duct to properly distribute the process gas. In addition, the space utilization rate was greatly improved when the duct at the rear of the nozzle was applied as a venturi type rather than a mixer for uniform distribution of ammonia gas.

A Study on the Deactivation of Commercial DeNOx Catalyst in Fired Power Plant (화력발전소 상용 탈질 촉매의 활성저하 원인에 관한 연구)

  • Park, Kwang Hee;Lee, Jun Yub;Hong, Sung Ho;Choi, Sang Hyun;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.19 no.4
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    • pp.376-381
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    • 2008
  • The deactivation of $V/TiO_2$ catalyst used in SCR (Selective Catalytic Reduction) using ammonia as a reductant to remove the nitrogen oxides (NOx) in the exhaust gas from fired power plant has been studied. The activity and surface area of the catalyst (Used-cat) which was exposed to the exhaust gas for long period have considerably decreased. The characterizations of these SCR catalysts were performed by XRD, FT-IR, FE-SEM, and IC/ICP. The crystal structure of $TiO_2$ both fresh and used catalyst has not been changed. However, $(NH_4)HSO_4$ deposited on the used catalyst surface verified from FT-IR, FE-SEM, and IC/ICP analysis. Moreover, the durability of $SO_2$ was increased by diminishing sulfate ($SO_4^{-2}$)f form.

A Study on the Remanufacturing of the Waste Three-way Catalysts (폐삼원촉매의 재제조에 관한 연구)

  • Huh, Been;Park, Hea-Kyung;Lee, Choul-Ho
    • Clean Technology
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    • v.15 no.3
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    • pp.147-153
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    • 2009
  • Waste three-way catalysts were remanufactured by ultrasonic wave treatment followed by active component re-impregnation and the catalytic activities and surface properties of remanufactured catalysts were measured at various remanufacturing conditions. In case of the catalyst prepared by ultrasonic wave cleaning, the optimal period for elimination of surface contaminants from the waste catalyst was found to be about 5 minutes. The proper re-impregnation amounts of the active components for the best catalytic performance were investigated and the catalytic performance tests were also carried out with various temperature for the total hydrocarbon (THC), carbon monoxide (CO) and nitrogen oxides (NOx) conversions. The experimental results showed that the catalytic performances of the remanufactured catalysts were recovered almost the same level as those of the fresh catalyst except those of the NOx conversion.

Eco-friendly selection of ship emissions reduction strategies with emphasis on SOx and NOx emissions

  • Seddiek, Ibrahim S.;Elgohary, Mohamed M.
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.6 no.3
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    • pp.737-748
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    • 2014
  • Increasing amounts of ships exhaust gases emitted worldwide forced the International Maritime Organization to issue some restricted maritime legislation for reducing the adverse environmental impacts arising from such emissions. Consequently, ships emission reduction became one of the technical and economical challenges that facing the ships, operators. The present paper addresses the different strategies that can be used to reduce those emissions, especially nitrogen oxides and sulfur oxides. The strategies included: applying reduction technologies onboard, using of alternative fuels, and follows one of fuel saving strategies. Using of selective catalytic reduction and sea water scrubbing appeared as the best reduction technologies onboard ships. Moreover, among the various proposed alternative fuels, natural gas, in its liquid state; has the priority to be used instead of conventional fuels. Applying one of those strategies is the matter of ship type and working area. As a numerical example, the proposed methods were investigated at a high-speed craft operating in the Red Sea area between Egypt and the Kingdom of Saudi Arabia. The results obtained are very satisfactory from the point of view of environment and economic issues, and reflected the importance of applying those strategies.

Framework to Compute Vehicle Emission Costs Associated with Work Zones

  • Shrestha, K. Joseph;Adebiyi, Jeremiah;Uddin, Mohammad Moin;Sturgill, Roy
    • International conference on construction engineering and project management
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    • 2022.06a
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    • pp.952-959
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    • 2022
  • Active construction work zones will result in longer travel time and/or longer travel distances for road users because of reduced speed limits and/or detours. This results in increased fuel consumption and increased emissions of harmful gases such as Carbon Monoxide (CO), Nitrogen Oxides (NOx), and Sulfur Oxides (SOx), which causes discomfort to the environment and road users around the work zone. The impact of such emissions should be considered while designing work zones or determining the number of days the roadway will be allowed to be closed partially or fully. This study develops a methodology to compute additional road user costs associated with such work zones. To achieve this goal, a) an extensive literature review is conducted, b) a framework to compute emission cost is developed, c) emission rates are computed for all counties (95) of the state of Tennessee, and d) a case study is conducted to demonstrate the use of the framework to estimate the additional impact of emission because of the work zone. For the case study conducted, the emission cost was computed to be $10,653.60 for the duration of the project. State DOTs can account for such road user costs while selecting contractors using A+B bidding. Accounting for such impact of emission will also indicate the agency's willingness to consider sustainability as a part of the business practices.

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A Study on Estimating Air Pullution in the Port of Incheon (인천항의 대기오염물질 배출량 산정 연구)

  • Lee, Jeong-Uk;Lee, Hyang-Suk
    • Journal of Korea Port Economic Association
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    • v.37 no.1
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    • pp.143-157
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    • 2021
  • International organizations such as the World Health Organization, the Organization for Economic Development and Cooperation, and major developed countries recognize the seriousness of air pollution. International organizations such as the International Maritime Organization have also implemented various regulations to reduce air pollution from ships. In line with this international trend, the government has also enacted a special law on improving air quality in port areas, and is making efforts to reduce air pollution caused by ports. The purpose of the Special Act is to implement comprehensive policies to improve air quality in port areas. This study sought to identify the emissions of each source of air pollutants originating from the port and prepare basic data on setting the policy priorities. To this end, the analysis was conducted in six categories: ships, vehicles, loading and unloading equipment, railways, unloading/wild ash dust, road ash dust, and the methodology presented by the European Environment Agency(EEA) and the United States Environmental Protection Agency(EPA). The pollutants subject to analysis were analyzed for carbon monoxide(CO), nitrogen oxides (NOX), sulfur oxides(SOX), total airborne materials(TSP), particulate matter(PM10, PM2.5), and ammonia(NH3). The analysis showed a total of 7,122 tons of emissions. By substance, NOX accounted for the largest portion of 5,084 tons, followed by CO (984 tons), SOX (530 tons), and TSP (335 tons). By source of emissions, ships accounted for the largest portion with 4,107 tons, followed by vehicles with 2,622 tons, showing high emissions. This proved to be the main cause of port air pollution, with 57.6% and 36.8% of total emissions, respectively, suggesting the need for countermeasures against these sources.

Freezing and Melting Phenomena of Urea-water Solution for Diesel Vehicle SCR System (디젤차량 SCR 시스템용 요소수용액의 동결과 해동 현상)

  • Choi, B.C.;Seo, C.K.;Myong, K.J.
    • Journal of Power System Engineering
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    • v.13 no.4
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    • pp.5-10
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    • 2009
  • Urea-SCR system, the selective catalytic reduction using urea as reducing agent, is a powerful technique to reduce nitrogen oxides(NOx) emitted from diesel engines. However, a tank of urea(32.5 wt%)-water solution can be frozen in low ambient temperature levels of below $-11^{\circ}C$. The purpose of this study is to understand freezing and melting phenomena of the urea-water solution, and its can be applied to get the urea-water solution from frozen it within 5 minutes after cold start. Factors considered were the type of heater and the urea tank shape. From the results, it was found that melting volume of cartridge heater B during 5 minutes of heating period was 83ml when supplying electric power of 150W. Horizontal heater B, which was put in the narrow bottom space of the tank T1, had fast melting characteristics.

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