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Crab shell, chitin, chitosan을 이용한 수중의 중금속 제거에 관한 연구

  • 신주남;안희경;김동석
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2000.05a
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    • pp.195-200
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    • 2000
  • Chitin과 탈아세틸화된 chitosan은 중금속 제거에 효과적인 생물흡착제로 잘 알려져 있다. 그러나 본 연구의 결과 crab shell에 있어서의 중금속 제거효율이 순수 chitin과 chitosan에서 보다 더 뛰어남을 알 수가 있었다. 납, 카드뮴, 망간이온 제거실험에서 crab shell은 초기 2시간 이내에 모두 제거되었으나, chitin과 chitosan의 흡착 실험에선 14시간이 경과되어도 이들 중금속의 대부분 수용액 내에서 거의 제거되지 않았다. 구리의 경우 염의 형태에 따른 흡착의 영향을 chitosan에선 제거된 량이 Cu($SO_{4})_{2}$ > Cu($NO_{3})_{2}$ > Cu($Cl_{2}$)의 순으로 나타났으나 chitin에선 모두 흡착이 거의 안된 상태로 나타났다. 주사현미경 분석 결과 crab shell의 표면에 납이 축적되어 있는 상태를 확인하였다.

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A study on the demodulator of canceling pilot interference signals from neighboring base stations in CDMA mobile communication (CDMA 이동통신에서 인접 기지국의 파일럿 간섭 신호를 제거하는 복조기에 관한 연구)

  • 전형구;이숭희;장종욱
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.28 no.8C
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    • pp.771-778
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    • 2003
  • A mobile station in a cell receives interference signals from neighboring base stations. Due to the interference signals, the forward link capacity of the cellular system is reduced. Pilot signal received from a neighboring base station is one of the interference signals. Since the pilot signal is a known signal for all the mobile stations, the pilot interference signal can be cancelled by interference cancellation techniques. In this paper, we propose a demodulator with interference canceller to cancel pilot interference signals received from neighboring base stations. The simulation results show that Eb/No value to obtain BER = 10-2 is lowered by 3㏈ in the propose demodulator.

The Effect of Hypochlorous Acid on the Nitrogen Removal in Sea Water (차아염소산이 해수 내 암모니아 제거에 미치는 영향)

  • Kim, Young-Jun;Jang, Jae-Eun;Lee, Sang-Wook;Cha, Seok-Jun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.21 no.1
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    • pp.45-52
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    • 2013
  • In this study, we had analyzed the ammonia removal efficiency in sea animal-culturing aquarium water using hypochlorous acid (HOCl) which is very reactive, no harm to human, and with no formation of toxic trihalomethane. The amount of hypochlorous acid for the removal of ammonia varied with the concentration of ammonia in samples, with 90% of removal efficiency for 30 minute reaction time in the sea water where the ratio of hypochloous acid to ammonia (w/w) is about 8.5 ~ 9.0, and 100% removal in the sample with the ratio of 9.8 ~ 10.1. The removal efficiency with the time was shown to be 90% within 10 minute in the ratio of 9.0 ~ 10.0. These results will effectively be used for the proper management and protection of sea animals in large aquarium through water clarification with hypochlorous acid by calculating the right amount and reaction time.

Comparison of efficiency in Mainstream ANAMMOX process for ratio of ammonium to nitrite (암모니아성 질소 대비 아질산성 질소 비율에 따른 Mainstream A NAMMOX 공정 효율 비교)

  • Gil, Kyung Ik;Lee, Da Won;Lee, Ji Won
    • Proceedings of the Korea Water Resources Association Conference
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    • 2021.06a
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    • pp.421-421
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    • 2021
  • 도시화, 산업화로 인해 하수처리장 유입하수 내 질소 농도가 증가하면서 그에 따른 부영양화 발생, 수생태계에 독성을 미치는 등의 악영향 또한 증가하게 되었다. 하수 내 고농도 질소를 처리하기 위해 1990년 초 연구가 시작되어 현재 보편적으로 사용되고 있는 생물학적 질소 제거 공정은 산소공급과 외부탄소원 보충 과정에서 상당한 비용이 소요된다. 이와 같은 문제점이 대두됨에 따라 고도의 질소 제거 공정이 요구되면서, 경제적으로 개선이 이루어져 기존의 질산화·탈질 공정보다 효율적인 혐기성 암모늄 산화 공정(ANaerobic AMMonium OXidation, ANAMMOX)이 제안되었다. ANAMMOX 공정은 혐기성 조건 아래 전자공여체와 전자수용체로써 암모니아성 질소와 아질산성 질소를 이용해 질소가스 형태로 질소를 제거하는 공정이다. 질산화·탈질 공정과 비교했을 때, 폭기과정에서의 산소요구량 감소, 외부탄소원 불필요, 질소 제거 과정 단축 등의 장점을 가진다. 본 연구는 수처리공정에서의 ANAMMOX 공정의 적용 가능성을 확인하고, 암모니아성 질소대비 아질산성 질소 비율에 따른 Mainstream ANAMMOX 공정의 효율 비교를 통해 공정의 안정성과 높은 제거효율을 확보할 수 있는 NH4+ 대비 NO2- 비율을 도출하는데 목적이 있다. 실험실 규모의 Mainstream ANAMMOX 반응조에 적용한 비율은 선행연구를 비롯한 화학양론식에서 제시된 비율을 바탕으로 산정하였다. 1.00부터 1.30의 전체적인 비율을 Initial과 Advanced 2개의 구간으로 나누어 운전한 결과, 각 구간의 NH4+ 제거효율은 각각 58~86%, 94~99%였다. NH4+ 대비 NO2- 비율이 증가함에 따라 공정의 안정성이 확보되고, NH4+ 및 총질소(TN) 제거효율이 증가하는 경향이 나타났다. 본 연구의 결과는 수처리공정에서의 안정적인 ANAMMOX 공정 적용을 유도하고, ANAMMOX 공정의 성능개선을 도모하는 연구의 기초로 활용될 수 있다.

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Optimization for Removal of Nitrogen Using Non-consumable Anode Electrodes (비소모성 Anode(산화전극)을 이용한 질소 제거 최적화)

  • Hyunsang, Kim;Younghee, Kim
    • Clean Technology
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    • v.28 no.4
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    • pp.309-315
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    • 2022
  • Research was conducted to derive the optimal operation conditions and the optimal cathode for using a DSA electrode as an anode to minimize electrode consumption during the removal of nitrogen from wastewater by the electro-chemical method. Of the various electrodes tested as cathodes, brass was determined to be the optimal electrode. It had the highest NO3-N removal rate and the lowest concentration of residual NH3-N, a by-product when Cl is present in the solution. Investigating the effect of current density found that when the initial concentration of NO3-N was 50 mg L-1, the optimal current density was 15 mA cm-2. In addition, current densities above 15 mA cm-2 did not significantly affect the NO3-N removal rate. The effect of electrolytes on removing NO3-N and minimizing NH3-N was investigated by using Na2SO4 and NaCl as electrolytes and varying the reaction times. When Na2SO4 and NaCl are mixed at a ratio of 1.0 g L-1 to 0.5 g L-1 and reacted for 90 min at a current density of 15 mA cm-2 and an initial NO3-N concentration of 50 mg L-1, the removal rate of NO3-N was about 48% and there was no residual NH3-N. On the other hand, when using only 1.5 g L-1 of NaCl as an electrolyte, the removal rate of NO3-N was the highest at about 55% and there was no residual NH3-N.

$NO_x$ Removal Using the Catalysts Impregnated Fibrous Ceramic Filters (촉매 담지 섬유형 세라믹 필터를 이용한 $NO_x$ 제거)

  • 정일철;홍민선;이동섭;이재춘
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.209-210
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    • 1999
  • 오존 precursor인 NOx의 배출기준은 점차 강화되고 있고 NOx의 처리기술로는 선택적 촉매환원법 (Selective Catalytic Reduction; SCR)이 가장 널리 사용되고 있다. 국내 SCR 적용공정의 경우, 100% 수입에 의존하고 있어 support 촉매의 국산화가 절실히 요구되고있다. 이에 본 연구에서는 support로 섬유형 세라믹 필터를 사용하여 CuO, V$_2$O$_{5}$ 촉매를 담지시켜 NOx의 제거실험을 수행하였다.(중략)

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Removal of NO/SO2 by the low temperature plasmas and photocatalysts (저온 플라즈마와 광촉매에 의한 NO/SO2 제거)

  • Kim, Dong-Joo;Kim, Kyo-Seon
    • Journal of Industrial Technology
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    • v.26 no.A
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    • pp.181-188
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    • 2006
  • In this study, we analyzed the effects of several process variables on the removal efficiencies of NO and $SO_2$ by the dielectric barrier discharge process combined with photocatalysts. The $TiO_2$ photocatalysts were coated onto the spherical-shaped glass beads as dielectric materials by the dip-coating method to analyze the effects of photodegradation reaction on the NO and $SO_2$ removal. As the voltage applied to the plasma reactor increases, or as the pulse frequency of applied voltage increases, the NO and $SO_2$ removal efficiencies increase. Also as the residence time increases, or as the initial concentration of NO decreases, the NO and $SO_2$ removal efficiencies increase. The higher the amount of $TiO_2$ particles coated onto the glass bead is, the larger the surface area of $TiO_2$ particles for the photodegradation reaction is and the NO and $SO_2$ are removed more quickly by the faster photodegradation reactions.

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Removal Improvement in Water Treatment Plant for Occurrence of Diatoms (Synedra sp.) in the Nakdong River (낙동강유역 상수원의 규조류 발생에 따른 정수장에서 제거율 향상 방안)

  • Kim, Min-Chai;Kim, Ji-Hoon;Seo, Gyu-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.1
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    • pp.29-34
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    • 2014
  • This study was conducted to investigate removal characteristics for Synedra sp. and filter run time (FRT) according to the cell length in the Nakdong River. When used alone flocculent, the removal efficiency for Synedra tenera (around $100{\mu}m$) was constant with 90.9~94.4%, while Synedra acus (around $300{\mu}m$) had the lower removal efficiency as 60~70%. $PACS_2$ and PAC showed 5~6% higher removal for S. acus than others (HiB and LAS). When added coagulant aid, loess had no effect and also needed more amount of flocculent. Sodium Silicate increased the removal rate by max 10.6%. On the other hand, 2.5 mg/L of Polyamine showed 96.9% removal efficiency for S. acus increasing up to 25% more than $PACS_2$ alone. In the effect of water temperature, the removal for S. acus at $15^{\circ}C$ were 6% higher than at $4^{\circ}C$. There was no significant correlation between the removal efficiencys of turbidity and S. acus. The results of this study was similar to the actual water treatment process's removal characteristics for Synedra sp. depending on the cell length and temperature. In the actual process, the numbers of Synedra in settled water was established natural logarithm function with the filter run time (FRT), so we can predict FRT as Synedra numbers.

THE EFFICACY OF CHEMO-MECHANICAL REMOVAL OF DENTIN CAR10US LESION (치아 우식부의 기계화학적 제거 효과에 대한 연구)

  • Lim, Soon-Bin;Choi, Kyung-Kyu;Park, Sang-Jin
    • Restorative Dentistry and Endodontics
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    • v.30 no.3
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    • pp.149-157
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    • 2005
  • Mechanical removals in decayed teeth have been performed using drill and sharp hand instruments. These methods have some disadvantages such as pain, local anesthesia and overextended cavities Therefore chemo-mechanical excavation of dentin carious lesions has been introduced. The purpose of this study was to evaluate the efficacy of traditional mechanical methods using burs and chemo-mechanical methods (Carisolv) of caries dentin. Mechanical caries removal was carried with low speed round bur Chemo-mechanical caries excavation was performed with Carisolv (Medi-team), using the Carisolv hand instruments. The mean time to remove caries with two different methods was evaluated and the data analyzed with SPSS software (ver 11.5) by t-test (p < 0.05). For histomorphometry of caries removal were also carried with mechanical or chemo-mechanical (Carisolv) methods from 20 extracted caries permanent molars. Complete caries removal was verified with a $\#$23 sharp explorers, Caries Detector (Kuraray Co. Japan), and standard apical radiography. 1. Chemo-mechanical method was taken more times than mechanical method (1.5 fold) (p < 0.05) 2. Excavation for caries took more time for molar lesion than premolar lesion, and the least time was taken to remove the caries in incisor lesion (p < 0.05). 3. There were no significant differences to remove the caries between the maxilla and mandible (p > 0.05). 4. The remaining carious dentin was detected after the ckemo-mechanical removal of the carious dentin, and no smear layer were seen after the mechanical and chemo-mechanical removal of the carious dentin.