• Title/Summary/Keyword: NO 분자

Search Result 1,427, Processing Time 0.028 seconds

The Crystal and Molecular Structure of Ammonium p-Methylbenzenesulfonate (암모늄 파라-메칠벤젠슬폰네이트의 결정 및 분자구조)

  • Choong Tai Ahn;Gene B. Carpenter
    • Journal of the Korean Chemical Society
    • /
    • v.32 no.4
    • /
    • pp.297-300
    • /
    • 1988
  • Ammonium p-methylbenzenesulfonate, $C_7H_11NO_3S$, Mr = 189.23, orthorhombic, space group $Pna2-1$, a = 20.406(4), b = 6.271(1), c = 7.067(2)${\AA}$, V = 904.19 ${\AA}^3$, Z = 4, $D_x$ = 1.39, $D_m =1.38g{\cdot}cm^{-3}$, ${\lambda}(M_o K_{\alpha})$ = 0. 71069 ${\AA}$, ${\mu}=3.1 cm^{-1}$, T = 298K, F(000) = 400, final R = 0.057 for 994 unique observed reflections with I > $16{\sigma}(I)$. The methylbenzene portion including the sulfur atom is nearly planar. Between the $SO_3$ groups and the ammonium ion, there are three unique hydrogen bonds; two of which make the anions linked along the c-axis and the remaining one along the b-axis. These hydrogen bonds make two-dimensionally hydrogen-bonded molecular layers. Among these hydrophilic layers, the methylbenzene moieties cluster together to form hydrophobic layers.

  • PDF

A Study on the Velocity Distribution of Gas Molecules by the Molecular Dynamics Method (분자동역학법에 의한 기체분자의 속도분포에 관한 연구)

  • 최순호
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.28 no.3
    • /
    • pp.441-450
    • /
    • 2004
  • The velocity distribution of gas molecules from the experimental results was confirmed as the same with the Maxwell-Boltzmann's theoretical results within the experimental error. This study is on the realization of the Maxwell-Boltzmann's velocity distribution of gas molecules by the molecular dynamics(MD) method. The Maxwell-Boltzmann's velocity distribution of gas molecules is extremely important to confirm the equilibrium state because the properties of a thermodynamic system shall be obtained from the system's equilibrium configuration in the MD method. This study is the first trial in the successive researches to calculate the properties of a thermodynamic system by the computer simulations. We confirmed that the maxwell-boltzmann's velocity distribution is developed in some transient time after starting a simulation and dependent on the size of a system. Also it is found that the velocity distribution has no relation with an initial configuration of gas molecules.

Molecular Species of Triglycerides in Camellia japonica Seed Oil (동백종실유(冬柏種實油)의 트리글리세리드의 분자종(分子種)에 관한 연구(硏究))

  • Kim, Seong-Jin;Choi, Eun-Jin;Lim, Hee-Ryeong;Kim, Tae-Sook;Joh, Yong-Goe
    • Journal of the Korean Applied Science and Technology
    • /
    • v.8 no.1
    • /
    • pp.27-34
    • /
    • 1991
  • 동백종실유(冬栢種實油)에서 컬럼크로마토그래피로 지질(脂質) 성분(成分)을 상호(相互) 분리(分離)하였다. 여기서 얻은 트리글리세리드의 일부(一部)를 취하여 알칼리로 가수분해(加水分解)하거나 또는 pancreatic lipase로 가수분해(加水分解) 하여, 트리글리세리드의 구성(構成) 지방산(脂肪酸) 또는 1, 3- 위치(位置)와 2-위치(位置)에 급합(給合) 한 지방산(脂肪酸) 조성(組成)을 조사(調査)하였다. 나머지 트리글리세리드는 16% $AgNO_3$ TLC로 이중결합선(二重結合敾)별로 나누었으며, 이렇게 나누어진 분획(分劃)을 다시 HPLC로 PN별로 재분획(再分劃) 하였다. 여기서 얻어진 획분(劃分)들 중 PN이 같은 것은 모두 모아서 알칼리 가수분해(加水分解)로 PN의 총지방산(總脂肪酸) 조성(組成)을, pancreatic lipase로 1,3 위치(位置)에 결합선(結合敾)한 지방산(脂肪酸)의 조성(組成)을 조사(調査) 하였다. 여기서 얻어진 결과(結果)로 부터 구성(構成) 트리그리셀리드 분자종(分子種)을 산출(算出)하였더니 다음과 같은 결과(算出)를 얻었다. 1) 종실유(種實油)는 투명(透明)한 액체(液體)로 그 함량(含量)이 73.5%였으며, 그 중 트리글리세리드가 94.8%, 극성(極性) 지질(極性)이 2.0%, 탄화(炭化) 수소(水素)가 1.8%였다. 2) $AgNO_3$-TLC로 트리글리세리드를 분획(分劃)하였더니 5개의 획분(劃分)을 얻었으며, 대부분(大部分)의 트리글리세리드가 이중(二重) 결합선(結合敾) 3${\sim}$5개인 band 2와 band 3에 80% 이상 존재(存在)하였다. 3) $AgNO_3-TLC$에서 얻은 각 획분(劃分)은 모두가 HPLC상에서 PN 46, 48 및 50으로 나누어졌으며 전체(全體) 분획(分劃)에서 PN 48이 78.13%로 제일 많았으며, 다음으로 PN 50이 12.04%였으며, PN 46이 9.83%였다. 4) 전체(全體) 트리글리세리드 분자종(分子種) 중에서 0.1mol% 이상을 차지하고 있는 분자종(分子種)이 43종(種)이었으며, OOO와 POO가 각각 39.8mol%와 25.8mol%로 제일 많았으며, 그 다음으로 OPO가 5.5 mol%, OOL가 4.8 mol%, POS가 3.9mol%, SOO가 3.5mol%. POL이 3.0mol%였다. 또 동백종실유(冬栢種實油)에 존재(存在)하는 트리글리세리드의 분자종(分子種)의 조성(組成)은 1,3-random, 2-random 분포설(分布說)에 따라 구성(分布說)되어 있었다.

Electrophoretic Patterns of Myofibrillar Proteins by Sugar Addition and Heat Treatment (당첨가 및 가열처리에 의한 근원섬유 단백질의 전기영동 Pattern 변화)

  • Yang, Jong-Beom;Yoon, Won-Ho;Ko, Myung-Soo;Kim, Chang-Han
    • Korean Journal of Food Science and Technology
    • /
    • v.22 no.6
    • /
    • pp.640-645
    • /
    • 1990
  • Changes of the electrophoretic patterns of myofibrillar proteins by sugar audition and heat treatment was studied. In the electrophoretic patterns of myofibrills prepared from no sugar added meat, as the intensity of higher molecular weight band such as myosin heavy chain showed a remarkable decrease by heating, that of lower molecular weight band such as actin showed no change. That from sugar added meat showed more remarkable decrease in the intensity of higher molecular weight band than that from no sugar added meat and this tendency was most noticeable in case of glucose addition. The effect of digestion with proteases after sugar addition and heat treatment on the electrophoretic patterns exhibited the descending order of trypsin >chymotrypsin >peptidase. By digestion with these three enzymes at one time myosin produced 27.000 dalton and 32.000 dalton components, and actin showed 16,000 dalton component. in the case of heat treatment, a part of actin was not digested. And in the case of glucose addition the myosin aggregates was not digested with these three enzymes at a time.

  • PDF

pH와 용존산소량이 Aureobasidium pullulans에 의한 pullulan의 생산성과 분자량에 미치는 영향에 대한 연구

  • Lee, Ji-Hyeon;Kim, Jeong-Hwa;Kim, Mi-Ryeong;Lee, Jin-U;Kim, Seong-Gu
    • 한국생물공학회:학술대회논문집
    • /
    • 2000.04a
    • /
    • pp.283-286
    • /
    • 2000
  • The effects of dissolved oxygen and pH on the cell growth and mass production of high-molecular weight pullulan by A. pullulans ATCC 42023 were evaluated. For the production of commercially useful pullulan with high-molecular weight, the influence of pH control on the pullulan production and growth of A. pullulans was studied in batch fermentation. It was found that the productivity of high-molecular weight pullulan with pH control at 6.5 was higher than that with no pH control. The influence of dissolved oxygen on the pullulan production and growth was studied. It was found that pullulan yield and synthesis rate increased with oxygen availability.

  • PDF

New PCR of DNA Computing (DNA 컴퓨팅의 새로운 PCR 연산)

  • 김정숙
    • Journal of the Korea Computer Industry Society
    • /
    • v.2 no.10
    • /
    • pp.1349-1354
    • /
    • 2001
  • In the Traveling Salesman Problem(TSP), a set of N cities is given and the problem is to find the shortest route connecting them all, with no city visited twice and return to the city at which it started. Since TSP is a well-known combinatorial optimization problem and belongs to the class of NP-complete problems, various techniques are required for finding optimum or near optimum solution to the TSP. Especially DNA computing, which uses real bio-molecules to perform computations supported by molecular biology, has been studied by many researchers to solve NP-complete problem using massive parallelism of DNA computing. Though very promising, DNA computing technology of today is inefficiency because the effective computing models and operations reflected the characteristics of bio-molecules have not been developed yet. In this paper, I design new Polymerase Chain Reaction(PCR) operations of DNA computing to solve TSP.

  • PDF