• Title/Summary/Keyword: NI ring

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A Study on the Evaluation of the Friction and Wear Properties of the Sprayed Coating Layer (용사피막의 마찰.마모 특성 평가에 관한 연구)

  • 김영식;김윤해;김종호;최영국;강태영
    • Journal of Welding and Joining
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    • v.14 no.3
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    • pp.66-74
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    • 1996
  • In this study, friction and wear properties of flame sprayed specimens and hard Cr plating specimens were tested, and their properties were compared each other in dry and lubrication condition. Ni-Cr powder and steel powder were used as the spray powder and sprayed on the steel(S45C) substrate by flame sprayed method. Each wear surface was observed with SEM after friction and wear test. The friction coefficient of the as-forged steel specimens was the highest among surface treatment specimens, and the other specimens appeared in order as follows ; hard Cr-plating specimens, Ni-Cr powder sprayed specimens, steel powder sprayed specimens. Comparing the wear volumes in dry condition, as forged steel specimens appeared the greatest wear volume, and the other specimens appeared wear volume in order as follows ; Ni-Cr powder sprayed specimens, steel powder sprayed specimens, hard Cr plating specimens. In friction and wear test, the hard Cr plating specimens were worn by the abrasive phenomenon, involving the cracks. The wear volume of steel powder sprayed specimens was lower than that of Ni-Cr powder sprayed specimens. Comparing the tensile strength of both sprayed coating layers, the steel powder sprayed coating layer was better than Ni-Cr powder sprayed coating layer.

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Effect of friction from differing vertical bracket placement on the force and moment of NiTi wires (브라켓의 수직적 변위에 따른 마찰이 NiTi wire의 힘과 모멘트에 미치는 영향)

  • Park, Jea-Beom;Yoo, Ji-A;Mo, Sung-Seo;Choi, Kwang-Cheol;Kim, Yoon-Ji;Han, Seong-Ho;Kook, Yoon-Ah
    • The korean journal of orthodontics
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    • v.41 no.5
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    • pp.337-345
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    • 2011
  • Objective: The purpose of this study was to evaluate the effect of force and moment produced by Nickel-titanium wires of different sizes at activation and deactivation according to differing vertical bracket displacement. Methods: Superelastic NiTi wires of 3 different sizes (0.014", 0.016", and 0.016" ${\times}$ 0.022") were tied with elastomeric or 0.009-inch stainless steel ligations in a twin-bracket, 0.018-inch slot. A testing machine recorded the effects of simulated activation of 5 distances from 1 to 5 mm and deactivation of 5 distances from 4 to 0 mm, in increments of 1 mm. Results: Frictional force increased the wire stiffness during loading. Ligation of 0.014-inch NiTi wire with O-ring resulted in a significant increase in the stiffness. On application of orthodontic force for 5 mm of vertical displacement of teeth, the effective displacement in the case of the 0.014", 0.016", and 0.016" ${\times}$ 0.022" NiTi wires was 2 mm, 3 mm, and 4 mm, respectively. Conclusions: Our results showed that movement of teeth with large vertical displacement was ineffective because of excessive friction. This finding might contribute to the understanding of the force system required for effective teeth movement and thereby facilitate the application of the appropriate light wire for leveling and alignment.

Suppression of the leakage current of a Ni/Au Schottky barrier diode fabricated on AlGaN/GaN hetero-structure by oxidation (Ni/Au 쇼트키 접합의 산화를 통해, AlGaN/GaN heterostructure 웨이퍼 위에 제작한 쇼트키 장벽 다이오드의 누설전류 억제)

  • Lim, Ji-Yong;Lee, Seung-Chul;Ha, Min-Woo;Han, Min-Koo
    • Proceedings of the KIEE Conference
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    • 2005.11a
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    • pp.3-5
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    • 2005
  • Ni/Au 쇼트키 접합의 산화를 통해 항복전압이 증가하고 누설 전류가 감소한 수평방향 GaN 쇼트키 장벽 다이오드를 제작하였다. 산화 과정 후, 턴-온 전압이 미세하게 증가하였으며 높은 애노드 전압하에서 애노드 전류가 증가하였다. 5분과 10분의 산화 과정 후, 누설 전류는 1nA 이하 수준으로 현저히 감소하였다. Edge Termination 방법으로 Floating Metal Ring을 사용하고, 산화 과정을 적용하여 제안된 GaN 쇼트키 장벽 다이오드의 항복전압은 750볼트의 큰 값을 얻을 수 있었다. 상온과 $125^{\circ}C$ 에서 제작한 GaN 쇼트키 장벽 다이오드의 역방향 회복 파형도 측정하였으며, 제작한 소자는 매우 빠른 역방향 회복 특성을 보였다.

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Design of Matching Condition for Ni-Zn Ferrite/Rubber composite Absorber (Ni-Zn Ferrite/Rubber 복합형 흡수체의 정합조건 설계)

  • Shin, K.H.;Kim, H.G.;SaGong, G.
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1406-1408
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    • 1994
  • In recently, there is growing demand for microwave absorbing matrial, and for the design method of microwave absorber. We developed a new method to design the matching frequency and matrial thick for ferrite/rubber composite absorber. Ni-Zn ferrite prepared with coprecipitation was compounded with silicon rubber, and, subsequently, pressed to ring specimen. The matrial constant of the ferrite/rubber composite absorber was used to design the matching frequency and matrial thick with matching map. In this study, we could predict matching condition from the design method. Foremore, using matching boundary map, we could also predict the condition of over 20[dB] attenuation.

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Synthesis and Structure of Nickel(II) Complex with N-Benzylisonitrosoacetylacetone Imine (N-Benzylisonitrosoacetylacetone Imine Ni(II) 착물의 합성 및 구조)

  • Byung Kyo Lee;Dae Sub O;Heung Lark Lee
    • Journal of the Korean Chemical Society
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    • v.32 no.6
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    • pp.536-542
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    • 1988
  • A nickel(Ⅱ) complex, Ni(IAA-NBz) (IAA-NBz') with ligand, N-benzylisonitrosoacetyl acetone imine (H-IAA-NBz) has been synthesized. This complex is very stable at room temperature and has cis-form and trans-form isomers. The ratio of nickel (Ⅱ) ion and ligand combined is 1 : 2. The elemental analysis, ir, nmr. electronic spectra and mass spectra have been studied. It is suggested from these studies that the isonitroso group of one ligand, H-IAA-NBz coordinates to nickel(Ⅱ)ion through the nitrogen atom to form five-membered ring, while that of the other ligand, H-IAA-NBz coordinates to nickel (Ⅱ) ion through the oxygen atom to form six-membered ring in square-planar complex.

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Three-Dimensional Metal Complex Host with Alternating Arrangement of the Occupied and Vacant Channels. The Crystal Structure of Cd(NH₂CH(CH₃)CH₂NH₂)Ni(CN)₄· 0.25G (G=$CH_3C_6H_5, p-(CH_3)_2C_6H_4$)

  • 박기민;이욱;Toschitake Iwamoto
    • Bulletin of the Korean Chemical Society
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    • v.17 no.10
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    • pp.919-924
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    • 1996
  • Crystal structure of two inclusion compounds Cd(pn)Ni(CN)4·0.25G (G=toluene and p-xylene, pn=1,2-diaminopropane) have been determined from single-crystal X-ray diffraction data; toluene clathrate: monoclinic P21/n, a=13.838(6), b=26.893(5), c= 7.543(5) Å, γ=90.92(3)°, Z=4, R=0.0616; p-xylene clathrate: monoclinic P21/n, a=13.895(2), b=26.900(3), c=7.613(1) Å, γ=91.06(1)°, Z=4, R=0.0486. The host structures determined for toluene- and pxylene-guest clathrates are substantially identical to the U-type structures observed for the straight chain aliphatic-guest clathrates. However, the alternating arrangement of occupied channels with the guest molecules and vacant channels appears in the host structure. The non-centrosymmetric toluene molecules are distributed about the inversion center to give an image like p-xylene molecule. The guests, toluene and p-xylene, prefer the U-type channel, favoring the interaction between the π-electrons of the aromatic ring and the pn-amino groups to hold the aromatic ring vertical to the cyanometallate meshes.

Improved evaluation of ring tensile test ductility applied to neutron irradiated 42XNM tubes in the temperature range of (500-1100)℃

  • Gurovich, B.A.;Frolov, A.S.;Fedotov, I.V.
    • Nuclear Engineering and Technology
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    • v.52 no.6
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    • pp.1213-1221
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    • 2020
  • Chromium-nickel alloy 42XNM (XHM-1, Bochvalloy) is considered as a promising material for future generations of nuclear reactors, primarily as a material for the fuel elements shells in the development of accident tolerant fuel. However, as with most nickel-based alloys, 42ХNМ is characterized by a sharp decrease in plastic properties in the temperature range of (500-900)℃. This effect is enhanced by neutron irradiation. Preliminary tests of ring samples of 42XNM alloy (after irradiation as a part of the VVER-1000 control system) in the temperature range of ductility failure showed that the standard technique for processing tensile diagrams does not allow to evaluate the plastic properties correctly at low strains. Therefore, in this work, the alternative method for testing ring samples from materials with low plastic characteristics was developed. It was shown that the minimum value of the permanent strain of the irradiated 42XNM alloy in the temperature range of (500-1100)℃, determined by the alternative method, was ~1.6% at 750 ℃.

Metal Complexes of Ambidentate Ligands (I). Nickel(II) Complexes of Isonitrosobenzoylacetone Imine Derivatives (Ambidentate Ligand의 금속 착물 (제1보). Isonitrosobenzoylacetone Imine 유도체와 니켈(Ⅱ)의 착물)

  • Man Ho Lee;Dae Sub Oh;Kwang Woo Lee
    • Journal of the Korean Chemical Society
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    • v.22 no.1
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    • pp.19-24
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    • 1978
  • Novel nickel(II) complexes of the type Ni(IBA-NH)(IBA-NR), where IBA-NH and IBA-NR (R=H, methyl, ethyl, n-propyl, iso-propyl, n-butyl or benzyl) represent isonitrosobenzoylacetone imine and its N-alkyl derivative respectively, have been prepared. The ir, nmr, and electronic spectra and magnetic moment of the nickel(II) complexes have been studied. It has been determined that the isonitroso group of IBA-NH coordinates to nickel through the oxygen to form 6-membered chelate ring and that of IBA-NR coordinates to nickel through the nitrogen to form 5-membered ring in square-planar Ni(IBA-NH) (IBA-NR). The coordination manner of the ligands is similar to that of isonitrosoacetylacetone imines obtained by Bose, et al.

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Selective Silylation Reaction of Aldehydes with 1,1'-Bis(dimethylsilyl)ferrocene in the Presence of Ni/Pt Catalyst (니켈/백금 촉매에 의한 1,1'-Bis(dimethylsilyl)ferrocene과 Aldehydes의 선택적 Silylation 반응)

  • Kim, Jin-Sik;Choi, Sung-Keun;Lee, Jung-Hyun;Kong, Young-Kun
    • Journal of the Korean Chemical Society
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    • v.51 no.3
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    • pp.232-239
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    • 2007
  • The reaction of 1,1'-bis(dimethylsilyl)ferrocene with various aldehydes in the presence of a catalytic amount of Ni(PEt3)4 lead to the acyclic products by monohydrosilylation. The same reaction in the presence of a catalytic amount of (C2H4)Pt(PPh3)2 leads to the different cyclic six membered ring compound by double silylation. Platinum catalyzed double silylation of 4-cyanobenzaldehyde was generated 5,6-ferrocenylene-1,1,4,4,-tetramethyl-2-oxa-2- cyanophenyl-1,4-disylacyclehexane which was crystallized to have crystal structure.

Electrochemical Study of [Ni63-Se)2μ4-Se)3(dppf)3] Cluster and Its Catalytic Activity towards the Electrochemical Reduction of Carbon Dioxide

  • Park, Deog-Su;Jabbar, Md. Abdul;Park, Hyun;Lee, Hak-Myoung;Shin, Sung-Chul;Shim, Yoon-Bo
    • Bulletin of the Korean Chemical Society
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    • v.28 no.11
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    • pp.1996-2002
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    • 2007
  • The redox behavior of a [Ni6(μ3-Se)2(μ4-Se)3(Fe(η 5-C5H4P-Ph2)2)3] (= [Ni-Se-dppf], dppf = 1,1-bis(diphenylphosphino) ferrocene) cluster was studied using platinum (Pt) and glassy carbon electrodes (GCE) in nonaqueous media. The cluster showed electrochemical activity at the potential range between +1.6 and ?1.6 V. In the negative region (0 to ?1.6 V), the cluster exhibited two-step reductions. The first step was one-electron reversible, while the second step was a five-electron quasi-reversible process. On the other hand, in the positive region (0 to +1.6 V), the first step involved one-electron quasi-reversible process. The applicability of the cluster was found towards the electrocatalytic reduction of CO2 and was evaluated by experiments using rotating ring disc electrode (RRDE). RRDE experiments demonstrated that two electrons were involved in the electrocatalytic reduction of CO2 to CO at the Se-Ni-dppf-modified electrode.