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http://dx.doi.org/10.5012/jkcs.2007.51.3.232

Selective Silylation Reaction of Aldehydes with 1,1'-Bis(dimethylsilyl)ferrocene in the Presence of Ni/Pt Catalyst  

Kim, Jin-Sik (Department of Chemistry, Kyonggi University)
Choi, Sung-Keun (Department of Chemistry, Kyonggi University)
Lee, Jung-Hyun (Department of Chemistry, Kyonggi University)
Kong, Young-Kun (Department of Chemistry, Kyonggi University)
Publication Information
Journal of the Korean Chemical Society / v.51, no.3, 2007 , pp. 232-239 More about this Journal
Abstract
The reaction of 1,1'-bis(dimethylsilyl)ferrocene with various aldehydes in the presence of a catalytic amount of Ni(PEt3)4 lead to the acyclic products by monohydrosilylation. The same reaction in the presence of a catalytic amount of (C2H4)Pt(PPh3)2 leads to the different cyclic six membered ring compound by double silylation. Platinum catalyzed double silylation of 4-cyanobenzaldehyde was generated 5,6-ferrocenylene-1,1,4,4,-tetramethyl-2-oxa-2- cyanophenyl-1,4-disylacyclehexane which was crystallized to have crystal structure.
Keywords
1,1'-bis(dimethylsilyl)ferrocene; Hydrosilylation; Double Silylation; Aldehydes;
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1 Bortole-Scott, A.; Resendes, R.; Manners, I. Macromol. Chem. Phys. 2003, 204, 1259
2 Arsenault, A. C.; Miguez, H.; Kitaev, V.; Ozin, G. A.; Manners, I. Adv. Mater. 2003, 15, 503   DOI   ScienceOn
3 Moran, M.; Casado, C. M.; Cuadrado, I. Organometallics, 1993, 12, 4327   DOI   ScienceOn
4 Beletskaya,I.; Moberg, C.; Chem. Rev. 1999, 99, 3435   DOI   ScienceOn
5 Ishikawa, M.; Okizaki, S.; Naka, A.; Yachibana, A.; Kawauchi, S.; Yamabe, T. Organometallics, 1995, 14, 114   DOI
6 Sharma, H.K.; Yamamoto, K.; Kumada, M.J. Am. Chem. Soc., 1972, 94,9263   DOI
7 Rajsapan J.; Choi, H.; Lalancette. Roger A.; Sheridan, John B. Oraganometallics 2005, 24, 1468   DOI   ScienceOn
8 Hayward, P. J.; Blake, D. M.; Wilkinson, G.; Nyman, C.J. J. Am. Chem. Soc., 1970, 92,5873   DOI
9 Nyman, C.; Wymore, C. E.; Wilkinson, G. J. Chem. Soc. A, 1968,561
10 Kong, Y. K.; Lee, J. J. Korean Chem. Soc. 2002, 46, 139   DOI   ScienceOn
11 Kang, Y.; Kim, J.; Kong, Y. K.; Lee, J.; Lee, S. W.; Kang, S. O.; Ko, J. Organometallics, 2000, 19, 5026   DOI   ScienceOn
12 Sakurai, H.; Kamiyama, Y. Nakadaira, Y. J. Am. Chem. Soc., 1975, 97, 931   DOI
13 Naka, A.; Okazaki, S.; Hayashi, M.; Ishikawa, M. J. Organomet. Chem., 1995, 499, 35   DOI   ScienceOn
14 Carlson, C. W.; West, R. Organometallics, 1983, 2. 1081
15 Rajsapan J.; Lalancette, Roger A.; Sheridan, John B. Organometallics, 2005, 24, 1458   DOI   ScienceOn
16 Okinishima, H.; Yamamoto, K; Kumada, M. J. Am. Chem. Soc., 1972, 94, 9263   DOI
17 Uchimaru Yu, Lautenschager, Hans Juergen, Wynd Andrew J., Tanaka Masato, Goto Midori, Organometallics, 1992, 11, 2639   DOI
18 Eaborn, C.; Metham, T. N.; Pidcock, A. J. Organomet. Chem., 1973, 63, 107   DOI   ScienceOn
19 Ishikawa, M.; Naka, A.; Okizaki, S.; Sakamoto, H. Organometallics, 1993, 12, 87   DOI
20 Kim, J.; Kang, Y.; Lee, J.; Kong, Y. K.; Gong, M. S.; Kang, S. O.; Ko, J. Organometallics, 2001, 20, 937   DOI   ScienceOn
21 Nagashima, H.; Tanabe, K.; Sakakibara, J.; Ishibashi, T.; Itoh, K. Organometallics, 1989, 8, 2495   DOI
22 Cundy, C. S. J. Organomet. Chem., 1974, 69, 305   DOI   ScienceOn
23 a) Nyman, C. J.; Wymore, C. E. Wilkinson, G. Chem. Comm., 1967, 407