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http://dx.doi.org/10.5012/bkcs.2007.28.11.1996

Electrochemical Study of [Ni6(μ3-Se)2μ4-Se)3(dppf)3] Cluster and Its Catalytic Activity towards the Electrochemical Reduction of Carbon Dioxide  

Park, Deog-Su (Center for Innovative BioPhysio Sensor Technology, Pusan National University)
Jabbar, Md. Abdul (Department of Chemistry, Pusan National University)
Park, Hyun (Advanced Ship Engineering Research Center, Pusan National University)
Lee, Hak-Myoung (Department of Chemistry, Pusan National University)
Shin, Sung-Chul (Department of Chemistry, Gyeongsang National University)
Shim, Yoon-Bo (Department of Chemistry, Pusan National University)
Publication Information
Bulletin of the Korean Chemical Society / v.28, no.11, 2007 , pp. 1996-2002 More about this Journal
Abstract
The redox behavior of a [Ni6(μ3-Se)2(μ4-Se)3(Fe(η 5-C5H4P-Ph2)2)3] (= [Ni-Se-dppf], dppf = 1,1-bis(diphenylphosphino) ferrocene) cluster was studied using platinum (Pt) and glassy carbon electrodes (GCE) in nonaqueous media. The cluster showed electrochemical activity at the potential range between +1.6 and ?1.6 V. In the negative region (0 to ?1.6 V), the cluster exhibited two-step reductions. The first step was one-electron reversible, while the second step was a five-electron quasi-reversible process. On the other hand, in the positive region (0 to +1.6 V), the first step involved one-electron quasi-reversible process. The applicability of the cluster was found towards the electrocatalytic reduction of CO2 and was evaluated by experiments using rotating ring disc electrode (RRDE). RRDE experiments demonstrated that two electrons were involved in the electrocatalytic reduction of CO2 to CO at the Se-Ni-dppf-modified electrode.
Keywords
Redox behavior of metal cluster; Surface modification; Electrocatalysis; Electrochemical reduction of $CO_2$;
Citations & Related Records
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