• 한국산학기술학회논문지
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• 제20권3호
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• pp.483-490
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• 2019

화재 발생으로 인한 피해 및 영향에 관해 국내에서의 연구는 미비한 상태이다. 따라서 화재 발생에 따른 연기 농도를 측정하기 위한 기기를 개발함으로 연기가 주변 지역으로 확산될 경우의 농도를 측정하고자 한다. 본 논문에서 제안한 공기질 측정 시스템은 기존의 측정기와는 달리 CO, CO2, NOx VOCs, NH3 등 총 5가지의 가스를 동시에 측정할 수 있고, 센서보호 알고리즘을 통해 높은 내구 수명을 갖는다. 또한, 모니터링 프로그램을 통해 실시간 가스 변화량을 측정하는 시스템을 구성하였다. 상용 가스 분석기와의 비교를 통해 가스농도 측정의 신뢰성을 확보하였으며, 실내 및 실외 화재실험을 통해 발화점 주변에 존재하는 가스농도 평가를 실시하여 신뢰성이 높은 데이터를 얻을 수 있음을 확인하였다.

• 한국대기환경학회지
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• 제26권1호
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• pp.94-102
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• 2010

Water content of $PM_{2.5}$ (particles in the atmosphere with a diameter of less than or equal to a nominal $2.5{\mu}m$) was estimated by using a gas/aerosol equilibrium model, SCAPE2, for the particles collected at Seoul and Gosan, Korea. From measured and analyzed characteristics of the particles, the largest difference between Seoul and Gosan is the proportions of total ammonia (t-$NH_3$=gas phase $NH_3$+particle phase ${NH_4}^+$), total nitric acid (t-$HNO_3$=gas phase $HNO_3$+particle phase ${NO_3}^-$) and sulfuric acid ($H_2SO_4$). Even though both sites have sufficient t-$NH_3$ to neutralize acidic species such as $H_2SO_4$, t-$HNO_3$, and t-HCl (total chloric acid=gas phase HCl+particle phase $Cl^-$), equivalent fraction of t-$NH_3$ and t-$HNO_3$ are higher at Seoul and $H_2SO_4$ is higher at Gosan. Based on the modeling result, it is identified that the $PM_{2.5}$ at Seoul is more hygroscopic than Gosan if the meteorological conditions are the same. To reduce water content of $PM_{2.5}$, and thus, mass concentration, control measures for ammonia and nitrate reduction are needed for Seoul, and inter-governmental cooperation is required for Gosan.

• 한국환경과학회지
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• 제22권11호
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• pp.1481-1498
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• 2013

The SCR (selective catalytic reduction) system is highly-effective technique for NOx reduction from exhaust gases. In this study, the effects of the direction and size of nozzle and the ammonia injection concentration on the performance of SCR system are analyzed by using the computational fluid dynamics method. When the nozzle is arranged in zigzaged direction which is normal to exhausted gas flow, it is shown that the uniformity of gas flow and the NH3/NO molar ratio is improved remarkably. With the change of the ammonia injection concentration from 0.2 vol%(wet) to 1.0 vol%(wet), the uniformity of gas flow shows a good results. As the size of nozzle diameter changes from 6 mm to 12 mm, the uniformity of gas flow is maintained well. It is shown that the uniformity of the $NH_3/NO$ molar ratio becomes better with decreasing the ammonia injection concentration and the size of nozzle diameter.

• 전자공학회논문지SC
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• 제43권4호
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• pp.21-29
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• 2006

본 논문에서는 혼합가스의 종류를 구분하고 농도를 추정하기 위하여 퍼지 ARTMAP 신경회로망과 퍼지 ART 신경회로망을 각각 사용하였다. 온도변환 구동방식의 반도체식 가스센서를 이용하여 $NH_3,\;H_2S$, 그리고 그들의 혼합가스에 대해서 데이터를 획득하였고, 데이터들을 제안한 패턴인식방법의 입력으로 사용하기 위해서 전 처리 과정을 통해 데이터들의 차원을 줄여주었다. 실험을 통해서 본 논문에서 사용한 방법이 이전의 다른 방법들과 비교하여 학습시간을 줄이면서 좀더 안정된 농도 추정 성능을 보여줌을 확인하였다.

• Asian-Australasian Journal of Animal Sciences
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• 제27권7호
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• pp.937-945
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• 2014

Green and black tea by-products, obtained from ready-made tea industry, were ensiled at $10^{\circ}C$, $20^{\circ}C$, and $30^{\circ}C$. Green tea by-product silage (GTS) and black tea by-product silage (BTS) were opened at 5, 10, 45 days after ensiling. Fermentation characteristics and nutrient composition, including tannins, were monitored and the silages on day 45 were subjected to in vitro ruminal fermentation to assess anti-nutritive effects of tannins using polyethylene glycol (PEG) as a tannin-binding agent. Results showed that the GTS and BTS silages were stable and fermented slightly when ensiled at $10^{\circ}C$. The GTS stored at $20^{\circ}C$ and $30^{\circ}C$ showed rapid pH decline and high acetic acid concentration. The BTS was fermented gradually with moderate change of pH and acid concentration. Acetic acid was the main acid product of fermentation in both GTS and BTS. The contents of total extractable phenolics and total extractable tannins in both silages were unaffected by storage temperatures, but condensed tannins in GTS were less when stored at high temperature. The GTS showed no PEG response on in vitro gas production, and revealed only a small increase by PEG on $NH_3$-N concentration. Storage temperature of GTS did not affect the extent of PEG response to both gas production and $NH_3$-N concentration. On the other hand, addition of PEG on BTS markedly increased both the gas production and $NH_3$-N concentration at any ensiled temperature. It can be concluded that tannins in both GTS and BTS suppressed rumen fermentation, and tannins in GTS did more weakly than that in BTS. Ensiling temperature for both tea by-products did not affect the tannin's activity in the rumen.

• 한국재료학회지
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• 제33권5호
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• pp.195-204
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• 2023

Micro-electronic gas sensor devices were developed for the detection of carbon monoxide (CO), nitrogen oxides (NO_x), ammonia (NH₃), and formaldehyde (HCHO), as well as binary mixed-gas systems. Four gas sensing materials for different target gases, Pd-SnO₂ for CO, In₂O₃ for NO_x, Ru-WO₃ for NH₃, and SnO₂-ZnO for HCHO, were synthesized using a sol-gel method, and sensor devices were then fabricated using a micro sensor platform. The gas sensing behavior and sensor response to the gas mixture were examined for six mixed gas systems using the experimental data in MEMS gas sensor arrays in sole gases and their mixtures. The gas sensing behavior with the mixed gas system suggests that specific adsorption and selective activation of the adsorption sites might occur in gas mixtures, and allow selectivity for the adsorption of a particular gas. The careful pattern recognition of sensing data obtained by the sensor array made it possible to distinguish a gas species from a gas mixture and to measure its concentration.

• 한국가스학회지
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• 제23권3호
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• pp.20-26
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• 2019

석탄 화력발전소 등의 대형 연소기기에서 질소산화물을 저감하기 위해 선택적 촉매환원 방법(SCR)의 탈질설비가 널리 쓰이고 있다. 본 연구에서는 SCR 탈질설비에서 암모니아를 공급하는 암모니아 분사 그리드(AIG)에 있는 암모니아와 희석 공기 혼합기에서 암모니아와 희석 공기의 균일한 혼합에 적합한 최적의 혼합기 형상을 도출하는 것을 목적으로 전산유체해석을 통해 수행하였다. 이를 위해 기본 형상의 혼합기(Case 1)에서 유동 특성과 $NH_3$ 농도 분포 특성을 살펴보았다. 기본 형상의 혼합기에서는 희석 공기 주 배관에서 암모니아 주입 배관 입구 반대쪽의 벽면으로 $NH_3$ 분포가 치우치는 것을 확인하였다. 이를 개선하기 위해 암모니아 주입 배관의 상단 구멍 1 개와 측면 구멍 4개를 막은 경우(Case 2)와 암모니아 주입 배관의 상단에 수평 평판을 설치한 경우(Case 3), 수평 평판과 함께 원호 평판을 설치 한 경우(Case 4)의 혼합기 형상에 대하여 유동과 $NH_3$ 농도 분포 특성을 분석하였다. 암모니아 주입 배관 상단에 수평 평판과 원호 평판을 설치한 경우(Case 4)에 혼합기 출구에서 $NH_3$ 분포의 % RMS 값이 가장 작은 값인 4.92%이고 농도 비율($R_{NH3}$) 범위가 -10.82~8.34%로 가장 최적의 $NH_3$ 균일 분포임을 알 수 있었다.

• Asian-Australasian Journal of Animal Sciences
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• 제27권8호
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• pp.1211-1218
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• 2014

Higher concentrations of ammonia ($NH_3$) and carbon dioxide ($CO_2$) in animal barns can negatively affect production and health of animals and workers. This paper focuses on measurements of summer concentrations of ammonia ($NH_3$) and carbon dioxide ($CO_2$) in a naturally ventilated laying henhouse located at an egg production facility in Bursa region, western Turkey. Also, indoor and ambient environmental conditions such as temperature and relative humidity were measured simultaneously with pollutant gas concentrations. The average $NH_3$ concentrations during summer of 2013 was 8.05 ppm for exhaust and 5.42 ppm for inlet while average $CO_2$ concentration was 732 ppm for exhaust and 625 ppm for inlet throughout summer. The overall minimum, average and maximum values and humidity were obtained as $16.8^{\circ}C$, $24.72^{\circ}C$, and $34.71^{\circ}C$ for indoor temperature and 33.64%, 63.71%, and 86.18% for relative humidity. The lowest exhaust concentrations for $NH_3$ and $CO_2$ were 6.98 ppm and 609 ppm, respectively. They were measured in early morning at the maximum diurnal ventilation rate in July 2013 and August 2013. The highest concentrations were 10.58 ppm for $NH_3$ and 904 ppm for $CO_2$ recorded in the afternoon when the ventilation rate was the lowest in June 2013.

• Journal of Plant Biology
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• 제16권1_2호
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• pp.17-22
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• 1973

The experiments were conducted to examine the injuries of $SO_2$, $NH_3$, and $SO_2$ and NH3 mixed gas to the germination and the growth of plants. Six kinds of plants were used as the material. These plants seeds were treated with the gases for five days. Rate of the germination and the growth in height of varying plants were different according to the components of the gases. The critical concentration of the gases for both the germination and the growth were in 5ppm of $SO_2$, 50ppm of $NH_3$, and 50ppm $SO_2$ and 50ppm $NH_3$ mixed gases. When a low concentration of $SO_2$ was treated together with NH3, especially it was reduced to 60 percent of the damage in the germination and the growth. In the treatemnt with $SO_2$, the germination of the seeds which soaked in water for 24 hours reduced the injuries more 40 percent than those which for one hour. It was observed that the seeds with thick coasts or with originally intact coats were suffered but little damaged by the gases, and the external symptoms of an injury were shown, at first, in water pore, and then, in guard cell on the leaves.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 하계학술대회 논문집 E
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• pp.2007-2009
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• 1999

In this paper, discharge domain of wire-cylindrical plasma reactor was separated from a gas flow duct to avoid unstable discharge by aerosol particle deposited on discharge electrode and grounded electrode. The NOx, SOx removal was experimentally investigated by a reaction induced to ammonium nitrate, ammonium sulfate using a low price of aqueous NaOH solution and a small quantity of ammonia. Volume percentage of aqueous NaOH solution used was 20% and $N_2$ flow rate was 2.5[$\ell$/min] for bubbling aqueous NaOH solution. Ammonia gas(14.82%) balanced by argon was diluted by air and was introduced to a main simulated flue gas duct through $NH_3$ injection system which was in downstream of reactor. The $NH_3$ molecular ratio[MR] was determined based on $NH_3$ to [NO+$SO_2$]. MR is 1.5. The NOx removal rates increased in the order of DC, AC and pulse, but SOx removal rates was not significantly effected by source of electricity. The NOx removal rate slightly decreased with increasing initial concentration but SOx removal rate was not significantly effect by initial concentration, and NOx, SOx removal rates decreased with increasing gas flow rate.