• 폴리머
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• 제37권2호
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• pp.232-239
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• 2013

A series of novel imidazole-blocked diisocyanate bioadhesives (IBAs) were synthesized from reaction of toluene 2, 4-diisocyanate (TDI), isophorone diisocyanate (IPDI), hydroxyl-terminated polylactide (HO-PLA-OH), 1,1,1-trimethylolpropane (TMP), and imidazole. Synthesis of IBAs was confirmed by Fourier transform infrared spectroscopy (FTIR) and gel permeation chromatography (GPC). Differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA) revealed that the TDI-based IBA had lower thermal dissociation temperature and a faster deblocking rate than IBA based on IPDI. Hydroxyl-terminated polyurethane (HPU) was introduced to study the adhesive effect of the synthesized IBAs. Improvement on elastic modulus, tensile strength and water resistance of IBA-modified HPU in comparison with neat HPU suggested the good adhesive effect of IBA due to the strong chemical reaction between released NCO groups from IBA and hydroxyl groups from HPU.

• 한국응용과학기술학회지
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• 제18권3호
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• pp.241-247
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• 2001

Aqueous urethane dispersion resin begins to assume commercial importance due to increasing environmental awareness of VOC in coating industry. Moreover there have been strong industrial needs for the development of reactive-type polyurethane flame retardant coatings. In this study, chlorinated polyester polyols were synthesized by two step polycondensation reaction using mono chloroacetic acid, adipic acid, trimethylol propane, and 1,4-butanediol. In the next step polyurethane dispersion was prepared using these chlorinated polyester polyols and isophorone diisocyanate with dimethylol propionic acid(DMPA) and trimethylamine. The structure of chlorinated polyol was characterized by GPC, FT-IR and NMR. Particle size and its distribution were examined in terms of various dispersion parameters including molecular weight and composition of polyol, amount of DMPA, and NCO/OH ratio, etc. The effect of chlorinated polyols on flammability was also evaluated.

• 한국전자통신학회논문지
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• 제7권6호
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• pp.1499-1504
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• 2012

본 과제는 부대 이전을 할 때 장병들이 선호하는 것과 선호하지 않는 요인들이 무엇인지를 알아보고 원활한 이전사업이 될 수 있도록 해당부대에 제안하려고 한다. 과제 연구결과는 다음과 같다. 첫째로 부대 이전사업에 대한 장병들의 선호도의 평균은. 4.00이었다. 이중 책임성(4.11)과 노력성 적정성이 가장 중요하게 선호하는 것으로 분석하였다. 둘째는 남 여별 선호도는 남자 군인(3.96)은 노력성과 책임성을 중시한 반면 여자군인(4.12)은 적정성과 소통성에 관심이 많은 것으로 분석하였다. 셋째 직위별로는 부사관은 전문성과 책임성을 가장 중시한 반면 장교는 적정성을 가장 중시하였다.

• 전기전자학회논문지
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• 제15권4호
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• pp.281-286
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• 2011

차세대 DTV 표준인 DVB-T2는 다양한 전송 대역폭을 지원하며, 대역폭에 따라 심볼 주파수가 달라진다. 따라서 다양한 심볼 주파수로 수신 신호를 표본화해야 한다. 또한 수신부 발진기의 주파수 오차로 인한 표본화 주파수 오차의 보상을 위해 미세한 표본화 주파수 보정도 필요하다. 수신 신호를 고정된 표본화 주파수를 갖는 ADC로 표본화 하고, 재표본화기를 이용하여 표본화 주파수를 심볼 주파수에 맞출 수 있다. 본 논문에서는 DVB-T2 복조기를 위한 재표본화기의 구조를 제안한다. 또한 모의실험을 통해 DVB-T2 신호의 각각의 부반송파에 대한 재표본화 결과의 주파수 특성을 보인다.

• 안보군사학연구
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• 통권4호
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• pp.157-209
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• 2006

The kinds of traits and behaviors studied most frequently in the early leadership research included physical characteristics, personalities, abilities, skills, behaviors and so forth. Researchers who studied leadership emphasized the important role of cultural, counter-insurgent, stability operational and clinical leadership traits and behaviors to perform the special mission of Overseas Forces The purpose of this study was to examine effective leadership traits, behaviors and skills for special mission of ROK Overseas Forces and to find out the differences on leadership traits, skills and behaviors among officers, noncommissioned officers(NCO) and enlisted men of the army. In order to achieve this purpose, a number of literature reviews and survey researches were conducted. The data for the analysis were collected through the questionnaire which consisted of 94leadership traits, skills and behaviors items Subjects were composed of 43 officers, 144 NCOs and 109 enlisted men Although the ranking order of leadership traits, skills and behaviors items among the groups for each analysis did not show much difference, the results of one-way analysis of variance revealed that a few items had a significant statistical difference among the groups. Implications of comparative results were also discussed in this study. In conclusion, this study would be useful basis for further improvement on effective leadership traits, skills and behaviors of ROK Overseas Forces, and some further researches were recommended.

• Bulletin of the Korean Chemical Society
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• 제19권11호
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• pp.1211-1216
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• 1998

Bis(diethyldithiocarbamato)ioxomolybdenum(VI), cis-MoO2(S2CNEt2)2, 1, reacted with chlorotrimethylsilane (Me33SiCl) to give a seven-coordinate, pentagonal bipyramidal complex MoOC12(S2CN]Et2)2, 3, in which the oxo ligand is trans to the chloride ligand and the two chloride ligands are mutually cis. The monooxo molybdenum complex bis(diethyidithiocarbamato)oxomolybdenum(IV), MoO(S2CNEt2)2, 2, reacted with phenyl isocyanate (PhNCO) to give an Mo dimer MO2{μ-N(CONPh)Ph}(μ-NPh)(NPh)2(S2CNEt2)2, 4, which contains an Mo-Mo bond, two diethyldithiocarbamato ligands, two terminal imido (NPh) ligands, and two bridging hnido (NPh) ligands. One of the two bridging NPh ligands seemed to have been attacked by the electrophilic phenyl isocyanate carbon, which suggests that the bridging imido NPh ligand is more nucleophilic than the terminal one. Crystallographic data for 3: monoclinic space group P21/c, a=8.908(l) Å, b=17.509(3) Å, c=12.683(2) Å, β=110.15(1)°, Z=4, R(wR2)=0.0611(0.1385). Crystallographic data for 4-THF: orthorhombic space group P212121, a=17.932(4) Å, b=22.715(5) Å, c=11.802(3) Å, Z=4, R(wR2)=0.0585(0.1286).

• Bulletin of the Korean Chemical Society
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• 제20권5호
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• pp.535-538
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• 1999

Five coordinated water-soluble iridium(l) complex, IrH(CO)(TPPTS)3 (1) (TPPTS = P(m-C6H4SO3Na)3-xH2O) has been prepared from the reaction of IrCl3·3H2O with TPPTS and HCHO in H2O/EtOH solution. Complex 1 catalyzes the hydration of nitrites (RC ≡ N, R = CH3, CICH2, CH3(CH2)4, Ph) in aqueous solution to give the corresponding amides (RCONH2) at 100℃. The hydration of unsaturated nitrites (R'C ≡ N, R'=CH3CH=CH, CH3OCH=CH, trans-PhCH=CH, CH2=C(CH3)) takes place regioselectively on-C ≡ N group to give unsaturated amides (R'CONH2) leaving the olefinic group intact. The yields of the amides seem to be depending on the electrophilicity of the carbon of nitrile: The more the electron withdrawing ability of the substituents on nitrites, the more amides are obtained. The hydration of dinitriles (NC-R-CN, R=(CH2)4, (CH2)6) with complex 1 initially gives mono-hydration products (NC-R-CONH2) which are slowly hydrated further to give dihydration products (H2NCO-R-CONH2). The hydration of 1,4-dicyanobutane has been found to be somewhat faster than that of 1,6-dicyanohexane.

• BMB Reports
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• 제52권10호
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• pp.607-612
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• 2019

During meiosis, programmed double-strand breaks (DSBs) are repaired via recombination pathways that are required for faithful chromosomal segregation and genetic diversity. In meiotic progression, the non-homologous end joining (NHEJ) pathway is suppressed and instead meiotic recombination initiated by nucleolytic resection of DSB ends is the major pathway employed. This requires diverse recombinase proteins and regulatory factors involved in the formation of crossovers (COs) and non-crossovers (NCOs). In mitosis, spontaneous DSBs occurring at the G1 phase are predominantly repaired via NHEJ, mediating the joining of DNA ends. The Ku complex binds to these DSB ends, inhibiting additional DSB resection and mediating end joining with Dnl4, Lif1, and Nej1, which join the Ku complex and DSB ends. Here, we report the role of the Ku complex in DSB repair using a physical analysis of recombination in Saccharomyces cerevisiae during meiosis. We found that the Ku complex is not essential for meiotic progression, DSB formation, joint molecule formation, or CO/NCO formation during normal meiosis. Surprisingly, in the absence of the Ku complex and functional Mre11-Rad50-Xrs2 (MRX) complex, a large portion of meiotic DSBs was repaired via the recombination pathway to form COs and NCOs. Our data suggested that Ku complex prevents meiotic recombination in the elimination of MRX activity.

• Journal of the Korean Wood Science and Technology
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• 제47권2호
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• pp.200-209
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• 2019

To improve the water resistance of melamine-urea-formaldehyde (MUF) resins, different levels of blocked polymeric 4,4 diphenyl methane diisocyanate (B-pMDI) were blended with MUF resins to prepare B-pMDI/MUF hybrid adhesives, and their adhesion performances were evaluated for the surface lamination of fancy veneer on plywood. FT-IR spectra showed that the de-blocked -NCO groups reacted with the -OH of hydroxymethyl groups of the MUF resins to form urethane bonds at 2% B-pMDI/MUF, which was detected before and after their hydrolysis. The mass loss after the hydrolysis consistently decreased as the B-pMDI level increased, indicating an improvement in the water resistance. As the B-pMDI level increased, the activation energy of hybrid adhesives decreased, which improved the reactivity of the hybrid adhesives. Additionally, the water resistance improvement of the hybrid adhesives increased the tensile shear strength of the surface laminated plywood in semi-water proof and water-proof by 23 % and 8 %, respectively, at 2% B-pMDI level. This was likely due to the urethane linkages in the hybrid adhesives. However, the formaldehyde emission from plywood panels bonded with the hybrid adhesives increased in the dry state, indicating incomplete curing of the hybrid adhesives.

• Structural Engineering and Mechanics
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• 제86권6호
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• pp.765-778
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• 2023

This study investigates the free vibration and buckling analyses of isotropic curved plate structures fixed at all ends. The Kirchhoff-Love Plate Theory (KLPT) and Finite Element Method (FEM) are employed to model the curved structure. In order to perform the finite element analysis, a four-node quadrilateral element with 5 degrees of freedom (DOF) at each node is utilized. Additionally, the drilling effect (θ_z) is considered as minimal to satisfy the DOF of the structure. Lagrange's equation of motion is used in order to obtain the first ten natural frequencies and the critical buckling values of the structure. The effects of various radii of curvatures and aspect ratio on the natural frequency and critical buckling load values for the single-bay and two-bay curved frames are investigated within this scope. A computer code based on finite element analysis is developed to perform free vibration and buckling analysis of curved plate frames. The natural frequency and critical buckling load values of the present study are compared with ANSYS R18.2 results. It has been concluded that the results of the present study are in good agreement with ANSYS results for different radii of curvatures and aspect ratio values of both single-bay and two-bay structures.