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Syngas Production Based on Co-electrolysis of CO2 and H2O in Solid Oxide Electrolysis Cell (고체 산화물 CO2-H2O 공전해 기반 합성가스 생산 기술 )

  • NAMGI JEON;SANGHYEOK LEE;SANGKUK KIM;CHIKYU AHN;JIN SOO AHN
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.2
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    • pp.140-145
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    • 2024
  • High temperature co-electrolysis of H2O-CO2 mixtures using solid oxide cells has attracted attention as promising CO2 utilization technology for production of syngas (H2/CO), feedstock for E-fuel synthesis. For direct supply to E-fuel production such as hydrocarbon and methanol, the outlet gas ratio (H2/CO/CO2) of co-electrolysis should be controlled. In this work, current voltage characteristic test and product gas analysis were carried out under various reaction conditions which could attain proper syngas ratio.

A Study on Reverse-water Gas Shift Reaction in Solid Oxide Water Electrolysis Cell-stack for CO2 Reduction (CO2 저감을 위한 고체산화물 수전해 스택의 역수성가스 전환 반응 고찰)

  • SANGKUK KIM;NAMGI JEON;SANGHYEOK LEE;CHIKYU AHN;JIN SOO AHN
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.2
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    • pp.162-167
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    • 2024
  • Fossil fuels have been main energy source to people. However, enormous amount of CO2 was emitted over the world , resulting in global climate crisis today. Recently, solid oxide electrolyzer cell (SOEC) is getting attention as an effective way for producing H2, a clean energy resource for the future. Also, SOEC could be applicable to reverse water-gas shift reaction process due to its high-temperature operating condition. Here, SOEC system was utilized for both H2 production and CO2 reduction process, allowing product gas composition change by controlling operating conditions.

Definition of Triangle Cell and Effective Generating methodology of Generalized Reed-Holler Coefficients (삼각 셀의 정의와 효율적인 GRM 계수 생성 기법)

  • 나기수;윤병희;변기영
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.29 no.6C
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    • pp.751-762
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    • 2004
  • In this paper, we propose the method to derive new GRM(Generalized Reed-Muller) coefficients for each 2$^n$ polarities using Triangle cell. As the existing methods to generate GRM coefficients, there are Green's method to operate transform matrix with a given RM coefficient and Besslich's method to get other polarities using basic transfer matrices repeatedly. In this paper, Triangle cell is defined so as to obtain GRM coefficients efficiently. After arranging 2$^n$ given RM coefficients of a first row of Triangle cell, sequence modulo sum is peformed in parallel to low column by a fixed numerical formula. To prove the efficiency of proposed arithmetic method, it is compared with Besslich’s method. As the compared result, to calculate GRM coefficients of all polarities to n input variables, Besslich’s method needs 2$^n$$^{-1}$ ${\times}$(2$^n$-1) two-input Ex-ORs and the proposed method needs 2${\times}$(the number of Ex-ORs for n-1 variables)+3$^n$$^{-1}$ for the same system complexity - (lo $g_2$$^n$) $T_{X}$./.

Exchange Coupling Field and Thermal Stability of Ni80Fe20/[Ir22/Mn78-Mn]/Co75Fe25 Multilayer Depending on Mn Content (Ni80Fe20/[Ir22/Mn78-Mn]/Co75Fe25 다층박막에서 Mn 함유량에 의존하는 교환결합력과 열적안정성)

  • Kim, B.K.;Lee, J.Y.;Kim, S.S.;Hwang, D.G.;Lee, S.S.;Hwang, J.Y.;Kim, M.Y.;Rhee, J.R.
    • Journal of the Korean Magnetics Society
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    • v.13 no.5
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    • pp.187-192
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    • 2003
  • The magnetic and thermal properties of NiFe/[IrMn-Mn]/CoFe with Mn additions have been studied. As-deposited CoFe pinned layers with [IrMn-Mn]layer had dominantly larger exchange biasing field ( $H_{ex}$) and blocking temperature ( $T_{b}$) than those with pure I $r_{22}$M $n_{78}$ used. The $H_{ex}$ and $T_{b}$ improved with 76.8-78.1 vol% Mn, but those of the NiFe/IrMn/CoFe dropped considerably with more addition of 0.6 vol % Mn. The average x-ray diffraction peak ratios of fcc [(111)CoFe, NiFe]/(111)IrM $n_3$ textures for the Mn inserted total vol of 75.5, 77.5, and 79.3% were about 1.4, 0.8, and 0.6, respectively. For the sample without Mn inserted layer, the $H_{ex}$ between IrMn and CoFe layers was almost zero, but it increased to 100 Oe after annealing of 250 $^{\circ}C$. For as-grown two multilayers samples with ultra-thin Mn layers of 77.5 and 78.7 vol %, the $H_{ex}$s were 259 and 150 Oe, respectively. In case of IrMn with 77.5 vol% Mn, the $H_{ex}$ was increased up to 475 Oe at 350 $^{\circ}C$ but decreased to 200 Oe at 450 $^{\circ}C$, respectively. The magnetic properties and thermal stabilities of NiFe/[IrMn-Mn]/CoFe multilayer were enhanced with Mn additions. In applications where higher $H_{ex}$ and $T_{b}$ are required, proper contents of Mn can be used. be used. used.

The Effects of Organic Matter (BIO-COM) Application on the Soil Physico-Chemical Properties and Rice Yields (유기물(有機物)(BIO-COM) 시용(施用)이 답토양(畓土壤)의 이화학적(理化學的) 성질(性質)과 수도수량(水稻收量)에 미치는 영향(影響))

  • Lim, Soo-Kil;Kim, Sang-Don;Lee, Sang-Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.23 no.1
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    • pp.26-33
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    • 1990
  • The pot experiment was conducted to compare the effects of BIO-COM (Organic fertilizer made from industrial by-product) with the compost and humic acid on the physico-chemical properties of soils and the yield of paddy rice (CV. Chucheong-byeo). The results obtained were as follows: 1. All the fertilizer treatments, except humic acid, increased rice yield compare to no fertilizer treatment, and Bio-Com was the highest among the fertilizer treatments. 2. Rice yields were increased with increasing BIO-COM only up to 4% but 2% with N.P.K. fertilizers. 3. Rice yield showed highly positive correlation with number of panicle per hill but negative correlation with 1000 grain weight. 4. BIO-COM application induced the noticeable increase of pH, EC, OM, T-N, Av-P, Ex-Ca, Ex-Mg, Ex-Na, and $Av-SiO_2$, contents in the soils after experiments, and there were highly significant positive correlation among them. 5. BIO-COM application was positively affected on plant height, number of tiller, and fresh weight and dry weight of rice plant throughout entire growing stages and these are positively correlated with rice yield. 6. BIO-COM application also induced the increase of chlorophyll, N, P, Ca, and Mg contents in rice plant 7. It is revealed that there were highly positive correlations between rice yields and pH, EC, OM, T-N, Ex-Ca, and Ex-Mg in the soils. 8. It was also shown the highly significant positive correlations between rice yields, and N and P contents in the rice plant at heading stages, respectively.

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Exchange coupling field of NiFe/IrMn/CoFe trilayer depending on Mn composition (3중박막 NiFe/IrMn/CoFe에서 Mn 함유량에 의존하는 교환결합세기)

  • 김보경;이진용;함상희;김순섭;이상석;황도근;김선욱;이장로
    • Proceedings of the Korean Magnestics Society Conference
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    • 2003.06a
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    • pp.130-131
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    • 2003
  • The magnetic and thermal properties of NiFe/IrMn/CoFe with Mn additions have been studied. As grown CoFe pinned-layers with IrMn-Mn have dominantly larger exchange biasing field( $H_{ex}$) and blocking temperature( $T_{b}$) than when pure I $r_{22}$M $n_{78}$ is used. The magnetic properties improve, $H_{ex}$ and $T_{b}$ improve with 77-78 vol% Mn, but drop considerably with more Mn additions, losing magnetic properties of theb NiFe/IrMn/CoFe with addition 0.6 vol % Mn. The average x-ray diffraction peak ratios fcc (111)CoFe of (111)IrM $n_3$ textures for the Mn inserted total vol of 75, 77, and 79 vol% were about 1.4, 0.8, and 0.6, respectively. For the sample without Mn inserted layer, the $H_{ex}$ between I $r_{22}$M $n_{78}$ and CoFe layers is almost nothing. For two multilayer as-grown samples with ultra-thin Mn layers of 77 vol % and 79 vol %, the $H_{ex}$s are 250 Oe and 150 Oe, respectively. In case of IrMn with 77.5 vol% Mn, the $H_{ex}$ was 444 Oe up to 30$0^{\circ}C$ endured of 363 Oe at 40$0^{\circ}C$, respectively. Mn additions improve the magnetic properties and thermal stabilities of NiFe/IrMn/CoFe. Those increase the $H_{ex}$ and $T_{b}$. In applications where higher $H_{ex}$ and $T_{b}$ are accept, proper concentrations of Mn can be used.n can be used.be used.

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Randomized, Double-Blind Study of Efficacy and Safety of Gynostemma pentaphyllum Ethanol Extract in a Normal Population (정상인에서 스트레스와 불안에 대한 돌외추출물의 효과와 안전성에 관한 무작위 배정 이중 맹검 임상시험)

  • Jeong, Seong-Hae;Lee, Myung-Koo;Park, Mi-Sook;Kim, Jae-Moon
    • Korean Journal of Clinical Pharmacy
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    • v.21 no.2
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    • pp.131-137
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    • 2011
  • The purpose of this study was to evaluate the clinical efficacy of a standardized special ethanol extract from Gynostemma pentaphyllum as a management for anxiety and stress of normal population. This is a two-arm, parallelgroup, randomized, double blind clinical trial comparing Gynostemma pentaphyllum extract 200 mg bid (GP-EX, n=48) or placebo bid (n=54). The main outcome measures were the decrease in anxiety sensitivity index (ASI), the State version (S-STAI) of the Stait-Trait Anxiety Inventory (STAI) and the Trait version (T-STAT) of the STAI from baseline over a 6 weeks treatment period. In more anxious group (S-STAI50 or ASI19), the anxiety in group with GP-EX was decreased significantly than one in normal population with placebo [S-STAI50: T-STAI = from $57.7{\pm}6.5$ ($mean{\pm}S.D.$) to $46.8{\pm}11.2$ in normal population with GP-EX, p=0.002 vs. from $54.1{\pm}9.9$ to $49.0{\pm}9.6$ in normal population with placebo, p>0.05; ASI19: T-STAI = from $47.2{\pm}12.0$ to $42.4{\pm}11.1$ in normal population with GP-EX, p=0.022 vs. from $48.7{\pm}11.5$ to $46.0{\pm}10.4$ in normal population with placebo, p>0.05]. The most frequently reported adverse reactions considered possibly related to treatment were mild gastrointestinal events. GP-EX is more effective than placebo and is well tolerated as a therapy for anxiety and stress of normal population.

Chromosome numbers on the Korean species of Senecio L. and two related genera (Asteraceae) (한국산 금방망이속(Senecio L.)과 근연분류군(국화과)의 체세포 염색체수)

  • Chang, Chin;Chung, Gyu Young
    • Korean Journal of Plant Taxonomy
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    • v.41 no.2
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    • pp.113-118
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    • 2011
  • The somatic chromosome numbers of the Korean species of Senecio L. and two related genera are investigated here. Three different chromosome numbers were found: 2n = 40 in Senecio argunensis Turcz., S. nemorensis L., S. vulgaris L., Tephroseris flammea (DC.) Holub and 2n = 44 in T. phaeantha (Nakai) C. Jeffrey & Y.L. Chen. and 2n = 48 in Sinosenecio koreanus (Kom.) B. Nord., T. kirilowii (Turcz. ex DC.) Holub and T. pierotii (Miq.) Holub. The chromosome numbers of Sinosenecio koreanus (Kom.) B. Nord., Tephroseris flammea (DC.) Holub and T. phaeantha (Nakai) C. Jeffrey & Y.L. Chen. were different from those in previous reports.

Physicochemical Properties of Topsoil Used for River Improvement and Non-Improvement Areas

  • Kim, Won-Tae;Cho, Yong-Hyeon;Yoon, Yong-Han;Kang, Hee-Kyoung;Park, Bong-Ju;Shin, Kyung-Jun;Eo, Yang-Joon;Yoon, Taek-Seong;Jang, Kwang-Eun;Kwak, Moo-Young;Song, Hong-Seon
    • Journal of Environmental Science International
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    • v.22 no.10
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    • pp.1295-1304
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    • 2013
  • This study was carried out to evaluate the physicochemical properties and perform a feasibility analysis of planting material composed of topsoil from river improvement and non-improvement areas. The results showed that the physicochemical properties of topsoil from river improvement areas were on the average sandy loam~loamy sand in soil texture, 5.6~6.8 in pH, 0.01~0.06 dS/m in EC, 0.9~2.1% in OM, 0.02~0.12% in T-N, 8~14 $cmol^+/kg$ in CEC, 0.01~0.08 $cmol^+/kg$ in Ex. $K^+$, 2.55~11.11 $cmol^+/kg$ in Ex. $Ca^{2+}$, 0.34~2.06 $cmol^+/kg$ in Ex. $Mg^{2+}$, and 3~396 mg/kg in Av. $P_2O_5$. And non-improvement areas showed on average sandy clay loam~sand in soil texture, 5.7~6.7 in pH, 0.02~0.08 dS/m in EC, 0.9~4.4% in OM, 0.02~0.23% in T-N, 7~18 $cmol^+/kg$ in CEC, 0.01~0.08 $cmol^+/kg$ in Ex. $K^+$, 3.81~12.67 $cmol^+/kg$ in Ex. $Ca^{2+}$, 0.60~1.95 $cmol^+/kg$ in Ex. $Mg^{2+}$, and 3~171 mg/kg in Av. $P_2O_5$. Meanwhile, the results of an applied valuation of topsoil- based planting were as follows. Ex. $K^+$ levels were low grade in all survey areas. OM was low grade in 12 improvement areas and 11 non-improvement areas. Av. $P_2O_5$ levels were low grade in 10 improvement areas and 10 non-improvement areas. T-N was low grade in six improvement areas and four non-improvement areas. Ex. $Mg^{2+}$ levels were low grade in two improvement areas.

Data Build-up for the Construction of Korean Specific Greenhouse Gas Emission Inventory in Livestock Categories

  • Won, S.G.;Cho, W.S.;Lee, J.E.;Park, K.H.;Ra, C.S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.3
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    • pp.439-446
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    • 2014
  • Many studies on methane ($CH_4$) and nitrous oxide ($N_2O$) emissions from livestock industries have revealed that livestock production directly contributes to greenhouse gas (GHG) emissions through enteric fermentation and manure management, which causes negative impacts on animal environment sustainability. In the present study, three essential values for GHG emission were measured; i.e., i) maximum $CH_4$ producing capacity at mesophilic temperature ($37^{\circ}C$) from anaerobically stored manure in livestock category ($B_{0,KM}$, Korean livestock manure for $B_0$), ii) $EF_{3(s)}$ value representing an emission factor for direct $N_2O$ emissions from manure management system S in the country, kg $N_2O-N$ kg $N^{-1}$, at mesophilic ($37^{\circ}C$) and thermophilic ($55^{\circ}C$) temperatures, and iii) $N_{ex(T)}$ emissions showing annual N excretion for livestock category T, kg N $animal^{-1}$ $yr^{-1}$, from different livestock manure. Static incubation with and without aeration was performed to obtain the $N_2O$ and $CH_4$ emissions from each sample, respectively. Chemical compositions of pre- and post- incubated manure were analyzed. Contents of total solids (% TS) and volatile solid (% VS), and the ratio of carbon to nitrogen (C/N) decrease significantly in all the samples by C-containing biogas generation, whereas moisture content (%) and pH increased after incubation. A big difference of total nitrogen content was not observed in pre- and post-incubation during $CH_4$ and $N_2O$ emissions. $CH_4$ emissions (g $CH_4$ kg VS-1) from all the three manures (sows, layers and Korean cattle) were different and high C/N ratio resulted in high $CH_4$ emission. Similarly, $N_2O$ emission was found to be affected by % VS, pH, and temperature. The $B_{0,KM}$ values for sows, layers, and Korean cattle obtained at $37^{\circ}C$ are 0.0579, 0.0006, and 0.0828 $m^3$ $CH_4$ kg $VS^{-1}$, respectively, which are much less than the default values in IPCC guideline (GL) except the value from Korean cattle. For sows and Korean cattle, $N_{ex(T)}$ values of 7.67 and 28.19 kg N $yr^{-1}$, respectively, are 2.5 fold less than those values in IPCC GL as well. However, $N_{ex(T)}$ value of layers 0.63 kg N $yr^{-1}$ is very similar to the default value of 0.6 kg N $yr^{-1}$ in IPCC GLs for National greenhouse gas inventories for countries such as South Korea/Asia. The $EF_{3(s)}$ value obtained at $37^{\circ}C$ and $55^{\circ}C$ were found to be far less than the default value.