• Title/Summary/Keyword: N and P Removal

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Application of Ferrate (VI) for Selective Removal of Cyanide from Plated Wastewater (도금폐수 중 시안(CN)의 선택적 제거를 위한 Ferrate (VI) 적용)

  • Yang, Seung-Hyun;Kim, Younghee
    • Clean Technology
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    • v.27 no.2
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    • pp.168-173
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    • 2021
  • The treatment of plated wastewater is subject to various and complex processes depending on the pH, heavy metal, and cyanide content of the wastewater. Alkali chlorine treatment using NaOCl is commonly used for cyanide treatment. However, if ammonia and cyanide are present simultaneously, NaOCl is consumed excessively to treat ammonia. To solve this problem, this study investigated 1) the consumption of NaOCl according to ammonia concentration in the alkaline chlorine method and 2) whether ferrate (VI) could selectively treat the cyanide. Experiments using simulated wastewater showed that the higher the ammonia concentration, the lower the cyanide removal rate, and the linear increase in NaOCl consumption according to the ammonia concentration. Removal of cyanide using ferrate (VI) confirmed the removal of cyanide regardless of ammonia concentration. Moreover, the removal rate of ammonia was low, so it was confirmed that the ferrate (VI) selectively eliminated the cyanide. The cyanide removal efficiency of ferrate (VI) was higher with lower pH and showed more than 99% regardless of the ferrate (VI) injection amount. The actual application to plated wastewater showed a high removal ratio of over 99% when the input mole ratio of ferrate (VI) and cyanide was 1:1, consistent with the molarity of the stoichiometry reaction method, which selectively removes cyanide from actual wastewater containing ammonia and other pollutants like the result of simulated wastewater.

Removal of Nutrients and Heavy Metals from Swine Wastewater using Chlorella vulgaris (Chlorella vulgaris를 이용한 양돈폐수 내 영양염류 및 중금속 제거)

  • Oh, Eun-Ji;Hwang, In-Sung;Yoo, Jin;Chung, Keun-Yook
    • Journal of Environmental Science International
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    • v.27 no.11
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    • pp.1059-1072
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    • 2018
  • Bioremediation has been recognized as a suitable alternative to conventional methods of removing contaminants, and it uses fungi, bacteria and microalgae. In contrast to other organisms, microalgae are unique in that they have the ability to perform photosynthesis like plants and to utilize organic/inorganic carbon substrates, in a process called phytoremediation. Microalgae can populate a reaction site rapidly and enhance the bioremediation efficiency. In this study, Chlorella vulgaris was used to evaluate the removal potentials of the nutrients (N and P) and heavy metals (Cu and Zn) from swine wastewater. The optimum growth conditions for Chlorella vulgaris and the removal potentials of N, P, Cu, and Zn from synthetic wastewater using Chlorella vulgaris were investigated. Based on the results, the applicability of this microalga to on-site wastewater treatment was examined. Optimal growth conditions for Chlorella vulgaris were established to be $28^{\circ}C$, a pH of 7, and light and dark cycles of 14:10 h. As the concentrations of the nutrients were increased, the efficiencies of N and P removal efficiencies by Chlorella vulgaris were decreased in the single and binary mixed treatments of the nutrients, respectively. Further, the efficiencies of Cu and Zn removal also decreased as the heavy metals concentrations added were increased, both in the single and binary mixed treatments. In addition, the efficiency of Cu removal was higher than that of Zn removal. Our results indicate that Chlorella vulgaris could be used in treatment plants for the removal of nutrients and heavy metals from swine wastewater.

Municipal Wastewater Treatment by Submerged Membrane Process (침지형 membrane을 이용한 생활오수처리)

  • 김광남;정순형;정우영;윤용수
    • Journal of environmental and Sanitary engineering
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    • v.14 no.2
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    • pp.105-112
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    • 1999
  • The removal characteristic of BOD, COD,T-N, and T-P was investigated in municipal wastewater treatment with anoxic and membrane submerged aerobic reactor. It was found that BOD and COD removal rate were obtained 90% and 92%, respectively, for 90 days operation. BOD and COD loading rate did not affect to the removal efficiency because MLSS concentration in aerobic tank was highly maintained.In the case of first reactor operated with anoxic and second reactor operated as aerobic, T-N, T-P removal rate were obtained 93% and 99% respectively.It was shown that removal efficiency could be maintained stable due to the complete removal of SS and sludge production decreased with increasing of sludge retention time.

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Removal of N and P by Intermittented Aeration Activated Sludge Process (간헐폭기식 활성슬러지 공법에 의한 질소, 인 제거)

  • 김동밀;이영신
    • Journal of Environmental Health Sciences
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    • v.18 no.2
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    • pp.57-61
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    • 1992
  • This study was made for enhanced removal of N and P by intermittented aeration Activated Sludge Process. Experiment were conducted to find the effects of aeration interval and nutrient removal efficiency. When applied aeration interval were 30~60 min, 2~4 h, 4~8 h, organic matter was not affected while phosphorous removal was aeration interval 30~60 min. Also, when applied mixing intensity were 15, 30, 45 and 60 rpm, organic matter was not affected while removal was maximum at 15 rpm. Total nitrogen and phosphorous removal were in the range of 76 and 85%. Density and MLSS of Sludge were in the range of 2.3~2.6 and 7198~7810 mg/l. Release of phosphorous from activated sludge under unaerobic condition was increased as pass time.

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A Pilot-Scale Study of Multiple Stage of Constructed Wetland Treatment System and Modeling for Nutrient Removal (Pilot 규모 연속배열형 인공습지의 영양염류 제거효능 규명 및 평가모델 연구)

  • Choi, Seung Il;Iamchaturapatr, Janjit;Rhee, Jae Seong
    • Journal of Korean Society on Water Environment
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    • v.26 no.5
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    • pp.781-788
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    • 2010
  • A pilot study was performed to examine the feasibility of multiple stage of constructed wetland (CW) for nutrient removal. The system is composed of six wetland cells connected with water-ways. The hydraulic of wetland cells is designed as free water surface flow. The treatment capacity was $25m^3d^{-1}$ at HRT of about one day for each cell. The magnitude of nutrient removal was related with the length of wetlands and plant density. Total N and P removal rates were 1353 and $246mg\;m^{-2}d^{-1}$ respectively. The pilot-scale reactor was model as continuous flow system containing contribution of CSTR and PFR typed-reactors. The $k-C^*$ model equation was applied to predict N and P reduction. The result indicated the equation was well guided to estimate reduction of $NO_3-N$ and $PO_4-P$.

Performance Evaluation of Soil Media for Water Quality Purification at LID Application (분산형 빗물관리시설 적용을 위한 수질정화기능 여재 성능 평가)

  • Park, Chan Gi;Kim, Chun Soo;Kim, Hwang Hee;Yoo, Sung-Yeol;Jeon, Ji Hong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.56 no.6
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    • pp.85-91
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    • 2014
  • In this study, the water quality purification of new medias which were NPS media, hyugato, mineral stone, charcoal for applying soil media of Integrated Management Practices (IMPs) of Low Impact Development (LID) were evaluated. The influent concentrations of COD, T-N, and T-P were 117.8 mg/L, 17.1 mg/L, and 2.062 mg/L, respectively. The infiltration capacities of NPS media, hyugoto, mineral stone, charcoal, and gravel were $7.1{\times}10m/s$, $7.3{\times}10^{-5}m/s$, $7.9{\times}10^{-5}m/s$, $6.0{\times}10^{-5}m/s$, respectively. All media meet criteria of infiltration capacity as surface soil layer at IMPs which is over $1.0{\times}10^{-5}m/s$. Maximum removal rates of COD, T-N, and T-P occurred at Charcoal with 98 % of COD removal rate, NPS with 78 % of T-N removal rate, and hyugato with 75 % fo T-P removal rate, respectively. For more high removal efficiency of all water quality item, the mixed media which is 4.5(NPS media): 1(charcoal) : 4.5 (hyugato) as volume ratio was evaluated. The infiltration capacity of mixed media was $7.9{\times}10^{-5}m/s$ and met the criteria of infiltration as surface soil layer. The water quality removal efficiencies of mixed media were very high with showing 70 % for COD, 85 % for T-N, and 71 % for T-P. The mixed media could purify the water quality of surface runoff and was recommended to used at the LID site of ground water quality problem.

Advanced Treatment Efficiency of Biological String Media and Oenanthe javanica for Effluent Quality Improvement in the Sedimentation Model Plant (하수의 최종 유출수 수질 개선을 위한 침전조 모형실험에 적용한 끈상 미생물접촉재와 미나리의 고도처리효율에 관한 연구)

  • Bae Joon-Sam;Lee Sang-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.3
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    • pp.440-447
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    • 2006
  • This study was aimed at the improvement of the effluent quality of municipal wastewater treatment plant by Oenanthe javanica and Bio-string media. The results were compared with conventional sedimentation tank and pilot sedimentation plant. In this study BOD as organic pollutants, SS, Nitrogen and Phosphorus were tested to evaluate the removal efficiencies for the advanced treatment. The result were as follow: in the Pilot Plant experiment, Tank 2 was fairly high removal efficiency as compared with Tank 1. The removal efficiency of BOD and SS in Tank 2 were as a range of $7.9%{\sim}38.8%,\;14.3%{\sim}60.0%$ and the removal efficiency of T-N, T-P were a range of $9.6%{\sim}31.5%,\;33.0%{\sim}80.0%$ respectively. The removal efficiency of T-P and SS were much higher than BOB and T-N.

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Effect of Operational Parameters on the Ammonia Stripping (암모니아 스트리핑에 미치는 운전인자의 영향)

  • Seo, Jeong-Beom;An, Kwang-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.9
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    • pp.935-939
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    • 2006
  • The biological nutrient removal from domestic wastewater with low C/N ratio is difficult. Therefore, this study was performed to examine effect of operational parameters such as air supply, hydraulic retention time, pH on the nitrogen removal by ammonia stripping and to increase influent C/N ratio without required carbon source. The ammonia stripping system used for the bench-scale experiment in laboratory had a dimension of 15 cm diameter and 150 cm height. The ammonia stripping reactors were classified into two types, type AS I and type AS II, according to there using or not media. Results of the research showed that the T-N removal efficiency of AS I using plastic media is slightly higher than AS II without media. In experimental condition of air supply 30 L/min and pH 12.5, T-N removal efficiencies increased as HRT of ammonia stripping reactor became longer from 8 hr to 36 hr. In experimental condition of HRT 36 hr, it was also found that the T-N removal efficiencies improved through increase of air supply. On the other hand, C/N ratio of wastewater was increased from average 3.9 to 5.4 by ammonia stripping.

Evaluation of Treatment Efficencies of Pollutants in Bongsan Constructed Wetlands for Treating Non-point Source Pollution (비점오염원 저감을 위한 봉산 인공습지의 오염물질 정화효율 평가)

  • Choi, Ik-Won;Moon, Sung-Dong;Seo, Dong-Cheol;Kang, Se-Won;Lim, Byung-Jin;Park, Jong-Hwan;Kim, Kap-Soon;Lee, Jun-Bae;Heo, Jong-Soo;Cho, Ju-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1089-1094
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    • 2011
  • To treat non-point source pollution in Juam lake, removal efficiencies of pollutants were investigated in Bongsan constructed wetlands (CWs) at different treatment time, stages and wastewater loads. The constructed wetlands consisted of forebay, $1^{st}$ and $2^{nd}$ wetlands. The concentrations of BOD, SS, T-N, and T-P in inflow were $1.87mg\;L^{-1}$, $1.62mg\;L^{-1}$, $11.47mg\;L^{-1}$, and $4.40mg\;L^{-1}$, respectively. The removal rates of BOD, SS, T-N, and T-P in Bongsan CWs were 26, 18, 16 and 9%, respectively. The removal rates of BOD and T-N were higher than those for SS and T-P. The amounts of pollutant removal in Bongsan CWs were higher in the order of forebay > $1^{st}$ wetland > $2^{nd}$ wetland for BOD, forebay > $2^{nd}$ wetland > $1^{st}$ wetland for SS, $1^{st}$ wetland > forebay > $2^{nd}$ wetland for T-N and $2^{nd}$ wetland > forebay > $1^{st}$ wetland for T-P.

Effects of pH on the growth, total nitrogen, total phosphorus and organic compound removal in heterotrophic culture of Chlorella sorokiniana applied wastewater treatment (pH와 탄소원이 Chlorella sorokiniana의 heterotrophic 배양 및 하폐수고도처리능에 미치는 영향)

  • Park, Jeong-Eun;Cho, Yong-Beom;Zhang, Shan;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.6
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    • pp.703-709
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    • 2013
  • Among many microalgae cultivation types, heterotrophic culture with low cost carbon sources and energy saving culture method is crucial. A result of estimating the effects of pH on wastewater treatment using heterotrophic growing microalgae Chlorella sorokiniana shows that there was no difference in microalgae growth amount and nitrogen, phosphorus removal rate by wide range of pH(5 ~ 9). From pH 5 to 9, total nitrogen, phosphorous and glucose removal rates were 10.5 mg-N/L/d, 2 mg-P/L/d, 800 ~ 1000 mg/L respectively. This study reveals that C. sorokiniana cannot metabolite glycerol heterotrophically, however, glucose and acetate were proper carbon sources for growth and T-N, T-P and TOC removal. This research highlights the potential of heterotrophic microalgal growth with wastewater treatment plant with wide range of pH and carbon sources.