• Title/Summary/Keyword: Murdoch

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Rational design of rare-earth orthoferrite LnFeO3 via Ln variation towards high photo-Fenton degradation of organics

  • Thi T. N. Phan;Aleksandar N. Nikoloski;Parisa A. Bahri;Dan Li
    • Advances in nano research
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    • v.16 no.1
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    • pp.41-52
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    • 2024
  • In this study, rare-earth orthoferrites LnFeO3 were synthesized using a facile hydrothermal reaction and their visible-light-induced photo-Fenton degradation of organics was optimized through Ln variation (Ln = La, Pr, or Gd). The morphological, structural, and chemical characteristics of as-prepared samples were examined in detail by using different methods, including XRD, SEM, TEM, XPS, etc. On the other side, under visible light illumination, the photo-Fenton-like catalytic activities of LnFeO3 were assessed in terms of the removal of selected organic models, i.e., pharmaceuticals (ketoprofen and tetracycline) and dyes (rhodamine B and methyl orange). As compared with PrFeO3 or GdFeO3, the sample of LaFeO3 displayed more structural distortion, larger specific surface area, and narrower band gap, resulting in its higher photo-Fenton-like catalytic activity toward the degradation of organics. In organic-containing solution, in which the initial solution pH = 5, catalyst dosage = 1 g/L and H2O2 concentration = 10 mM, 98.2% of rhodamine B, 31.1% of methyl orange, 67.7% of ketoprofen, or 96.4% of tetracycline was removed after 90-min exposure to simulated visible light. Our findings revealed that variation of Ln site on rare-earth orthoferrites was an effective strategy for optimizing their organic removal via visible-light-induced photo-Fenton reaction.

Traumatic Repetition and Writing as Awakening in Iris Murdoch's The Black Prince

  • Kim, Il-Yeong;Ryu, In Sang
    • Journal of English Language & Literature
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    • v.57 no.3
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    • pp.495-513
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    • 2011
  • Murdoch's novel, The Black Prince, is not, as most critics have suggested, an autobiographical novel. It is about the inner life or rather trauma of Bradley Pearson, an artist who repeatedly dreams about a shabby paper shop which used to be run by his "unsuccessful" parents. In this respect, Freudian concept of trauma is helpful since it can explain Bradley's present repetition of his past traumatic experience, while allowing us to understand the nature of his trauma which reveals itself not only through his repeated nightmares but also through the women who are represented as diverse versions of his mother, the origin of Bradley's trauma. Caruth's concept of traumatic awakening and traumatic survival is also instrumental in understanding the nature of the traumatic experience which Bradley undergoes in this novel. Induced by Loxias's address, Bradley makes a confession of "the sins," which makes possible his traumatic survival as well as traumatic awakening, which is transmitted not only to Loxias but also to us the readers. In this sense, the significance of Bradley's awakening is not confined to his past only, but becomes a matter of a social dimension. The meaning of Bradley's writing lies in this fact.

Nonlinear and nonclassical vibration analysis of double walled piezoelectric cylindrical nanoshell

  • Kachapi, Sayyid H. Hashemi
    • Advances in nano research
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    • v.9 no.4
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    • pp.277-294
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    • 2020
  • In current paper, nonlocal (NLT), nonlocal strain gradient (NSGT) and Gurtin-Murdoch surface/interface (GMSIT) theories with classical theory (CT) are utilized to investigate vibration and stability analysis of Double Walled Piezoelectric Nanosensor (DWPENS) based on cylindrical nanoshell. DWPENS simultaneously subjected to direct electrostatic voltage DC and harmonic excitations, structural damping, two piezoelectric layers and also nonlinear van der Waals force. For this purpose, Hamilton's principle, Galerkin technique, complex averaging and with arc-length continuation methods are used to analyze nonlinear behavior of DWPENS. For this work, three nonclassical theories compared with classical theory CT to investigate Dimensionless Natural Frequency (DNF), pull-in voltage, nonlinear frequency response and stability analysis of the DWPENS considering the nonlocal, material length scale, surface/interface (S/I) effects, electrostatic and harmonic excitation.

Ionic Equilibria in Mixed Solutions of Cuprous and Cupric Chloride (염화 제1구리와 제2구리 혼합용액의 이온평형)

  • Lee, Man Seung;Nicol, M.J.
    • Korean Journal of Metals and Materials
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    • v.46 no.1
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    • pp.20-25
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    • 2008
  • The ionic equilibira in mixed solutions of cuprous and cupric chloride were analyzed by considering chemical equilibria, mass and charge balance equations. The activity coefficients of solutes were calculated by using Bromley equation. Required thermodynamic constants and interaction parameters were evaluated from the data reported in the literature. The effect of NaCl and CuCl concentrations on the pH and potential of the mixed solutions was explained in terms of the variation in the concentration of solutes and in the activity of hydrogen ion. The calculated pH values of the mixed solutions agreed well with the measured values. However, the calculated values for the potential of the mixed solutions were lower than the measured values, indicating the necessity of considering the complex formation between cuprous and chloride ion, such as $Cu^2Cl{_4}^{2-}$ and $Cu_3Cl{_6}^{3-}$.

Fluid-conveying piezoelectric nanosensor: Nonclassical effects on vibration-stability analysis

  • Kachapi, Sayyid H. Hashemi
    • Structural Engineering and Mechanics
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    • v.76 no.5
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    • pp.619-629
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    • 2020
  • In current study, surface/interface effects for pull-in voltage and viscous fluid velocity effects on dimensionless natural frequency (DNF) of fluid-conveying piezoelectric nanosensor (FCPENS) subjected to direct electrostatic voltage DC with nonlinear excitation, harmonic force and also viscoelastic foundation (visco-pasternak medium and structural damping) are investigated using Gurtin-Murdoch surface/interface (GMSIT) theory. For this analysis, Hamilton's principles, the assumed mode method combined with Lagrange-Euler's are used for the governing equations and boundary conditions. The effects of surface/interface parameters of FCPENS such as Lame's constants (λI,S, μI,S), residual stress (τ0I,S), piezoelectric constants (e31psk,e32psk) and mass density (ρI,S) are considered for analysis of dimensionless natural frequency respect to viscous fluid velocity u̅f and pull-in voltage V̅DC.

Dynamic analysis of nanoscale beams including surface stress effects

  • Youcef, Djamel Ould;Kaci, Abdelhakim;Benzair, Abdelnour;Bousahla, Abdelmoumen Anis;Tounsi, Abdelouahed
    • Smart Structures and Systems
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    • v.21 no.1
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    • pp.65-74
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    • 2018
  • In this article, an analytic non-classical model for the free vibrations of nanobeams accounting for surface stress effects is developed. The classical continuum mechanics fails to capture the surface energy effects and hence is not directly applicable at nanoscale. A general beam model based on Gurtin-Murdoch continuum surface elasticity theory is developed for the analysis of thin and thick beams. Thus, surface energy has a significant effect on the response of nanoscale structures, and is associated with their size-dependent behavior. To check the validity of the present analytic solution, the numerical results are compared with those obtained in the scientific literature. The influences of beam thickness, surface density, surface residual stress and surface elastic constants on the natural frequencies of nanobeams are also investigated. It is indicated that the effect of surface stress on the vibrational response of a nanobeam is dependent on its aspect ratio and thickness.

Intestinal Spirochaetes of the Genus Brachyspira: An Update on Recent Findings

  • Hampson, David J.
    • Proceedings of the Korean Society of Veterinary Pathology Conference
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    • 2003.10a
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    • pp.1-5
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    • 2003
  • A variety of different spirochaetal bacteria inhabit the large intestines of animals and man. This paper focuses on anaerobic intestinal spirochaetes of the genus Brachyspira (formerly Serpulina). Within the last few years, six new Brachyspira species have been officially name and/or renamed, and two other groups of these bacteria have been given provisional species names (Table 1). (omitted)

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