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Kinetic Analysis for the Pyrolysis of Solid Refues Fuel Using Livestock Manure (축분 고형연료의 열분해 동역학 연구)

  • Jang, Eun-Suk;Song, Eunhye;Yoon, Jonghyuk;Kim, Young-Min
    • Applied Chemistry for Engineering
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    • v.31 no.4
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    • pp.443-451
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    • 2020
  • In this study, the physico-chemical properties and pyrolysis kinetics of livestock mature solid fuel were investigated to know its feasibility as a fuel. Ultimate and proximate analysis results showed that livestock mature solid fuel has high contents of volatile matter (64.94%), carbon (44.35%), and hydrogen (5.54%). The low heating value of livestock mature solid fuel (3880 kcal/kg) was also higher than the standard requirement of solid fuel (3000 kcal/kg). Thermogravimetic analysis results indicated that livestock mature solid fuel has three decomposition temperature regions. The first temperature zone (130~330 ℃) was consisted with the vaporization of extracts and the decomposition of hemicellulose and cellulose. The second (330~480 ℃) and third (550~800 ℃) temperature regions were derived from the decomposition of lignin and additional decomposition of carbonaceous materials, respectively. The activation energy derived from model free kinetic analysis results including Friedman, Flynn-Wall-Ozawa (FWO), and Kissinger-Akahira-Sunose (KAS) methods for the pyrolysis of livestock mature solid fuel was in the range of 173.98 to 525.79 kJ/mol with a conversion rate of 0.1 to 0.9. In particular, the activation energy increased largely at the higher conversion than 0.6. The kinetic analysis using a curve-fitting method suggested that livestock mature solid fuel was decomposed via a multi-step reaction which can be divided into five decomposition steps.

Rapid Detection of Pathogens Associated with Dental Caries and Periodontitis by PCR Using a Modified DNA Extraction Method (PCR을 이용한 치아우식증 및 치주염 연관 병원체의 빠른 검출)

  • Kim, Jaehwan;Kim, Miah;Lee, Daewoo;Baik, Byeongju;Yang, Yeonmi;Kim, Jaegon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.41 no.4
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    • pp.292-297
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    • 2014
  • DNA extraction is a prerequisite for the identification of pathogens in clinical samples. Commercial DNA extraction kits generally involve time-consuming and laborious multi-step procedures. In the present study, our modified DNA isolation method for saliva samples allows for the quick detection of pathogens associated with dental caries or periodontitis by PCR within 1 h. To release DNA from the bacteria, 1 min of boiling was adequate, and the resulting isolated DNA can be used many times and is suitable for long term storage of at least 13 months at $4^{\circ}C$, and even longer at $-20^{\circ}C$. In conclusion, our modified DNA extraction method is simple, rapid, and cost-effective, and suitable for preparing DNA from clinical samples for PCR for the rapid detection of oral pathogens from saliva.

Geomechanical properties of synthesised clayey rocks in process of high-pressure compression and consolidation

  • Liu, Taogen;Li, Ling;Liu, Zaobao;Xie, Shouyi;Shao, Jianfu
    • Geomechanics and Engineering
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    • v.20 no.6
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    • pp.537-546
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    • 2020
  • Oil and natural gas reserves have been recognised abundantly in clayey rich rock formations in deep costal reservoirs. It is necessary to understand the sedimentary history of those reservoir rocks to well explore these natural resources. This work designs a group of laboratory experiments to mimic the physical process of the sedimentary clay-rich rock formation. It presents characterisation results of the physical properties of the artificial clayey rocks synthesized from illite clay, quartz sand and brine water by high-pressure consolidation tests. Special focus is given on the effects of illite clay content and high-stress consolidation on the physical properties. Multi-step loaded consolidation experiments were carried out with stress up to 35 MPa on mixtures constituting of the illite clay, quartz sand and brine water with five initial illite clay contents (w=85%, 70%, 55%, 40% and 25%). Compressibility and void ratio were characterised throughout the physical compaction process of the mixtures constituting of five illite clay contents and their water permeability was measured as well. Results show that the applied stress induces a great reduction of clayey rock void ratio. Illite clay contents has a significant influence on the compressibility, void ratio and the permeability of the physically synthesized clayey rocks. There is a critical illite clay content w=70% that induces the minimum void ratio in the physically synthesised clayey rocks. The SEM study indicates, in the high-pressure synthesised clayey rocks with high illite clay contents, the illite clay minerals are located in layers and serve as the material matrix, and the quartz minerals fill in the inter-mineral pores or are embedded in the illite clay matrix. The arrangements of the minerals in microscale originate the structural anisotropy of the high-pressure synthesised clayey rock. The test findings can give an intuitive physical understanding of the deep-buried clayey rock basins in energy reservoirs.

Oxidative Desulfurization of Marine Diesel Using WOx/SBA-15 Catalyst and Hydrogen Peroxide (WOx/SBA-15 촉매와 과산화수소를 이용한 선박용 경유의 산화 탈황 연구)

  • Oh, Hyeonwoo;Kim, Ji Man;Huh, Kwang-Sun;Woo, Hee Chul
    • Korean Chemical Engineering Research
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    • v.55 no.4
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    • pp.567-573
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    • 2017
  • In this work, tungsten oxide ($WO_x$) supported on SBA-15 (mesoporous silica) were prepared and applied for oxidative desulfurization of sulfur compounds in marine diesel containing about 230 ppmw of sulfur concentration. Prepared catalysts were examined by two steps; at first step, oxidation reaction carried out with hydrogen peroxide as oxidant and then the oxidized sulfur compounds were extracted by acetonitrile as solvent. Catalysts were characterized by using X-ray diffraction, X-ray fluorescence, X-ray photoelectron spectroscopy and $N_2$ adsorption-desorption isotherms. Tungsten oxide exists as monoclinic crystal system on SBA-15 and over about 10 wt% of the $WO_x$ loading took the form of multi-layers on SBA-15. The 13 wt% $WO_x$/SBA-15 catalyst exhibite highest activity, achieving about 76.3% sulfur removal in the reaction conditions, such as catalyst amount of 0.1 g, reaction temperature at $90^{\circ}C$, reaction time for 3 h and O/S molar ratio of 10. One time oxidation reaction is enough oxidize the sulfur compounds in marine diesel completely. The repetition experiment of extraction process indicated that sulfur removal could reach 94.4% after 5 times.

A 0.18-μm CMOS Baseband Circuits for the IEEE 802.15.4g MR-OFDM SUN Standard (IEEE 802.15.4g MR-OFDM SUN 표준을 지원하는 0.18-μm CMOS 기저대역 회로 설계에 관한 연구)

  • Bae, Jun-Woo;Kim, Chang-Wan
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.17 no.3
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    • pp.685-690
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    • 2013
  • This paper has proposed a multi-channel and wide gain-range baseband circuit blocks for the IEEE 802.15.4g MR-OFDM SUN systems. The proposed baseband circuit blocks consist of two negative-feedback VGAs, an active-RC 5th-order chebyshev low-pass-filter, and a DC-offset cancellation circuit. The proposed baseband circuit blocks provide 1 dB cut-off frequencies of 100 kHz, 200 kHz, 400 kHz, and 600 kHz respectively, and achieve a wide gain-range of +7 dB~+84 dB with 1 dB step. In addition, a DC-offset cancellation circuit has been adopted to mitigate DC-offset problems in direct-conversion receiver. Simulation results show a maximum input differential voltage of $1.5V_{pp}$ and noise figure of 42 dB and 37.6 dB at 5 kHz and 500 kHz, respectively. The proposed I-and Q-path baseband circuits have been implemented in $0.18-{\mu}m$ CMOS technology and consume 17 mW from a 1.8 V supply voltage.

A 65-nm CMOS Low-Power Baseband Circuit with 7-Channel Cutoff Frequency and 40-dB Gain Range for LTE-Advanced SAW-Less RF Transmitters (LTE-Advanced SAW-Less 송신기용 7개 채널 차단 주파수 및 40-dB 이득범위를 제공하는 65-nm CMOS 저전력 기저대역회로 설계에 관한 연구)

  • Kim, Sung-Hwan;Kim, Chang-Wan
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.17 no.3
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    • pp.678-684
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    • 2013
  • This paper describes a low-power baseband circuit for SAW-less LTE-Advanced transmitters. The proposed transmitter baseband circuit consists of a 2nd-order Tow-Thomas type active RC-LPF and a 1st-order passive RC LPF. It can provide a 7 multi-channel cut-off frequencies and wide gain control range of -41 dB ~ 0 dB with a 1-dB step. The proposed 2nd-order active RC-LPF adopts an op-amp in which three other sub-op amps are in parallel connected to reduce DC current for different cutoff frequency. In addition, each sub-op amp adopts both Miller and feed-forward phase compensation method to achieve an UGBW of more than 1-GHz with a small DC power consumption. The proposed baseband circuit is implemented in 65-nm CMOS technology, consuming DC power from 6.3 mW to 24.1 mW from a 1.2V supply voltage for each different cut-off frequency.

Analysis of RTM Process Using the Extended Finite Element Method (확장 유한 요소 법을 적용한 RTM 공정 해석)

  • Jung, Yeonhee;Kim, Seung Jo;Han, Woo-Suck
    • Composites Research
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    • v.26 no.6
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    • pp.363-372
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    • 2013
  • Numerical simulation for Resin Transfer Molding manufacturing process is attempted by using the eXtended Finite Element Method (XFEM) combined with the level set method. XFEM allows to obtaining a good numerical precision of the pressure near the resin flow front, where its gradient is discontinuous. The enriched shape functions of XFEM are derived by using the level set values so as to correctly describe the interpolation with the resin flow front. In addition, the level set method is used to transport the resin flow front at each time step during the mold filling. The level set values are calculated by an implicit characteristic Galerkin FEM. The multi-frontal solver of IPSAP is adopted to solve the system. This work is validated by comparing the obtained results with analytic solutions. Moreover, a localization method of XFEM and level set method is proposed to increase the computing efficiency. The computation domain is reduced to the small region near the resin flow front. Therefore, the total computing time is strongly reduced by it. The efficiency test is made with a simple channel flow model. Several application examples are analyzed to demonstrate ability of this method.

Efficiently Development Plan from the User's Need Analysis of the Army Tactical C4I(ATCIS) System (지상전술 C4I(ATCIS)체계 운용자 요구분석을 통한 효율적 발전 방안)

  • Park, Chang-Woon;Yang, Hae-Sool
    • The Journal of the Korea Contents Association
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    • v.8 no.5
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    • pp.246-259
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    • 2008
  • This study was to minimize the trial and error in the primary step of the C4I system(ATCIS) of the each army corps on the front line, and test the economy and efficiency was tested by reviewing related papers and the system characteristics of other countries. The relationship was researched by analyzing the collected survey data and survey data related to the user's requirement level such as the army standards, that is, commonality, timeliness, simplification, automaticity, field availability and viability, multi-stage security and interoperability, unification. The result showed that the C4I system was efficiently operated through the system reliability for the specification of the system and operation manual, maneuverability and security, adaptability of the war field and system support and management, and good education and training about system operation, and less system maintenance and supplementary element. As a result, the development plan confirmed that the continuous operator education and the construction of the maintenance, and the upgrade digitalization(C4ISR+D) with the korean characteristics based on IT of network systems, and system development of the measurement model of the operator performance must be continuously supplemented in the near future.

Thickness Evaluation of the Aluminum Using Pulsed Eddy Current (펄스 와전류를 이용한 알루미늄 두께 평가)

  • Lee, Jeong-Ki;Suh, Dong-Man;Lee, Seung-Seok
    • Journal of the Korean Society for Nondestructive Testing
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    • v.25 no.1
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    • pp.15-19
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    • 2005
  • Conventional eddy current testing has been used for the detection of the defect-like fatigue crack in the conductive materials, such as aluminum, which uses a sinusoidal signal with very narrow frequency bandwidth, Whereas, the pulsed eddy current method uses a pulse signal with a broad bandwidth. This can allow multi-frequency eddy current testing, and the penetration depth is greater than that of the conventional eddy current testing. In this work, a pulsed eddy current instrument was developed for evaluating the metal loss. The developed instrument was composed of the pulse generator generating the maximum square pulse voltage of 40V, an amplifier controlled up to 52dB, an A/D converter of 16 bit and the sampling frequency of 20 MHz, and an industrial personal computer operated by the Windows program. A pulsed eddy current probe was designed as a pancake type in which the sensing roil was located inside the driving roil. The output signals of the sensing roil increased rapidly wich the step pulse driving voltage かn off, and the latter part of the sensing coil output voltage decreased exponentially with time. The decrement value of the output signals increased as the thickness of the aluminum test piece increased.

A Bibliometric Study of Library and Information Science Research in Korea (한국 문헌정보학 연구의 계량적 분석 - 국내 문헌정보학과 교수 연구업적을 중심으로 -)

  • Lee, Jong-Wook;Yang, Ki-Duk
    • Journal of the Korean Society for Library and Information Science
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    • v.45 no.4
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    • pp.53-76
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    • 2011
  • This study assesses research patterns and trends of library and information science(LIS) in Korea by applying bibliometric analysis. For the study, 2,400 peer-reviewed publications from 2001 to 2010(including conference proceedings) published by 159 LIS professors in Korea were analyzed by year, author, affiliation and journal. The study findings showed an increasing trend in collaboration(52.75% of total publications with single authors and 47.25% with multiple authors) among LIS professors in Korea, robust publication patterns of Korean LIS faculty(average 1.51 publications per year), and an increasing number in foreign publications(170 publications). The study results also suggested an internationalization of LIS in Korea. Specifically, the study found a higher rate of Korean LIS faculty with foreign degrees than in previous years as well as a higher publication rate of professors with international degrees. The analysis of publication patterns conducted by the study, which is a first step in our aim to establish a multi-faceted approach for assessing the impact of scholarly work, will be followed up with analysis of references and citations to evaluate the quality of publications.