• 제목/요약/키워드: Multi-metals

검색결과 182건 처리시간 0.02초

Water treatment sludge for removal of heavy metals from electroplating wastewater

  • Ghorpade, Anujkumar;Ahammed, M. Mansoor
    • Environmental Engineering Research
    • /
    • 제23권1호
    • /
    • pp.92-98
    • /
    • 2018
  • Suitability of aluminium-based water treatment sludge (WTS), a waste product from water treatment facilities, was assessed for removal of heavy metals from an electroplating wastewater which had high concentrations of copper and chromium along with other heavy metals. Batch tests with simulated wastewater in single- and multi-metal solutions indicated the influence of initial pH and WTS dose on removal of six metals namely Cu(II), Co(II), Cr(VI), Hg(II), Pb(II) and Zn(II). In general, removal of cationic metals such as Pb(II), Cu(II) and Zn(II) increased with increase in pH while that of anionic Cr(VI) showed a reduction with increased pH values. Tests with multi-metal solution showed that the influence of competition was more pronounced at lower WTS dosages. Column test with diluted (100 times) real electroplating wastewater showed complete removal of copper up to 100 bed volumes while chromium removal ranged between 78-92%. Other metals which were present in lower concentrations were also effectively removed. Mass balance for copper and chromium showed that the WTS media had Cu(II) and Cr(VI) sorption capacities of about 1.7 and 3.5 mg/g of dried sludge, respectively. The study thus indicates that WTS has the potential to be used as a filtration/adsorption medium for removal of metals from metal-bearing wastewaters.

다이아몬드 배열 무전해 니켈 도금층/무산소동 기판의 열전도도 특성 (Thermal Properties of Diamond Aligned Electroless Ni Plating Layer/Oxygen Free Cu Substrates)

  • 정다운;김송이;박경태;서석준;김택수;김범성
    • 한국분말재료학회지
    • /
    • 제22권2호
    • /
    • pp.134-137
    • /
    • 2015
  • The monolayer engineering diamond particles are aligned on the oxygen free Cu plates with electroless Ni plating layer. The mean diamond particle sizes of 15, 23 and $50{\mu}m$ are used as thermal conductivity pathway for fabricating metal/carbon multi-layer composite material systems. Interconnected void structure of irregular shaped diamond particles allow dense electroless Ni plating layer on Cu plate and fixing them with 37-43% Ni thickness of their mean diameter. The thermal conductivity decrease with increasing measurement temperature up to $150^{\circ}C$ in all diamond size conditions. When the diamond particle size is increased from $15{\mu}m$ to $50{\mu}m$ (Max. 304 W/mK at room temperature) tended to increase thermal conductivity, because the volume fraction of diamond is increased inside plating layer.

사질식양토와 식토에서 중금속 이온의 다중 경쟁 흡착 (Competitive Adsorption of Multi-species of Heavy Metals onto Sandy Clay Loam and Clay Soils)

  • 정덕영;노현희
    • 한국토양비료학회지
    • /
    • 제38권5호
    • /
    • pp.238-246
    • /
    • 2005
  • 두 가지 이상의 중금속이온이 토양에 존재할 때 토양입자표면에 흡착되는 중금속 이온은 복합적인 경쟁이온치환과 특정결합기작에 따라 흡착량이 결정된다. 본 연구는 충남 논산과 대전시 유성에 소재하는 밭토양에서 채취한 사질식양토와 식토를 공시토양으로 하여 중금속의 다중경쟁흡착특성을 조사하였다. 경쟁흡착은 조사 대상 중금속인 Cr, Cd, 및 Pb를 토양용액에 처리 농도를 달리하여 단일, 이중, 삼중체계로 처리하였다. 등온흡착은 평형농도가 증가함에 따라 흡착이 증가하는 경향을 보여주었으며 이중과 삼중체계에서는 동일 평형농도에서 흡착량은 각각의 중금속이온의 농도와 중금속 전하에 의해 영향을 받는 것으로 조사되었다. 3가지 중금속이온의 이중경쟁 흡착특성은 전기음성도는 낮으나 이온포텐셜이 높은 Cr 이온이 경쟁이온 보다 선택적 흡착특성을 보여주고 있으며 Cd와 Pb가 Cr 흡착에 미치는 영향은 유사한 것으로 조사되었다. 따라서 본 연구 결과 3중 경쟁 흡착 시 중금속 이온의 흡착량이 단일과 이중 경쟁흡착보다 증가하는 특성을 구명하기 위해서는 다중 형태로 존재하는 중금속이온의 흡착기작과 다중 형태상의 중금속이온의 반응식, 그리고 반응식에 따른 가수분해상수를 구하여 흡착정도와 경쟁 상태에 대한 추가 연구가 필요하다. 결론적으로 다중 중금속이온이 존재하는 상태 하에서 흡착친화도는 토양 내 중금속이온의 이동성과 불용화 및 가용화 사이의 분배특성에 영향을 주는 것으로 판단되었다.

고에너지 물질 연소를 기반으로 한 Multi Physics Modeling (How to Prepare the Manuscript for Submission to the Proceedings of KSPE Conference)

  • 김기홍;여재익
    • 한국추진공학회:학술대회논문집
    • /
    • 한국추진공학회 2007년도 제28회 춘계학술대회논문집
    • /
    • pp.238-241
    • /
    • 2007
  • We present an innovative method of multi-physics application involving energetic materials. Energetic materials are related to reacting flows in extreme environments such as fires and explosions. They typically involve high pressure, hish temperature, strong non-linear shock waves, and high strain rate deformation of metals. We use an Eulerian methodology to address these problems. Our approach is naturally free from large deformation of materials that makes it suitable for high strain-rate multi-material interaction problems. Furthermore we eliminate the possible interface smearing by using the level sets. We have devised a new level set based tracking framework that can elegantly handle large gradients typically found in reacting gases and metals. We show several work-in-progress applications of our algorithm including the Taylor impact test, explosive venting and additional confined explosion problems of modem interest.

  • PDF

다중주물을 활용한 주얼리 제작에 관한 연구 (A study on jewelry-making using a multi-casting)

  • 이정수;김형성
    • 한국결정성장학회지
    • /
    • 제22권5호
    • /
    • pp.223-226
    • /
    • 2012
  • 이종(異種)금속을 접합 가공하는 모꾸메가네기법, 상감기법 등의 기존 제작 방식은 주얼리 대량생산에 있어 표현 및 제작 상 많은 제한이 따른다. 이를 극복하기 위하여 기존의 정밀주조기법과 CAD/CAM방식을 융합한 다중(多重)주물 제작기법을 제시하였다. 주얼리 원본제작에 있어 CAD/CAM을 활용하여 2차 원본은 1차 원본보다 5 % 작게 제작하였다. 1차 황동 주조물에 2차로 은을 주조하여 실험하였으며, 2차 주조 시 통상적 주조의 플라스크 온도 보다 약 $150{\sim}200^{\circ}C$ 높게 주조하였다. 다중주물 방식을 통하여 대량생산이 가능한 이종(異種)금속의 주얼리를 손쉽게 제작할 수 있었다.

다관절 로봇을 이용한 엔드밀 가공에 관한 연구 (A Study on the Endmilling using the Multi-Articulated Robot)

  • 최은환;정선환;최성대
    • 한국정밀공학회:학술대회논문집
    • /
    • 한국정밀공학회 2003년도 춘계학술대회 논문집
    • /
    • pp.1772-1775
    • /
    • 2003
  • The stiffness of multi-articulated industrial robots is very weak, because their structure is an articulated type with some links and joints. Thus it is known that cutting processes for metals are not accepted in machine shop well, but they have a lot of merits for cutting processes, for example. drilling, tapping. and engraving etc., because of the characteristics of their high degree of freedom. The temptation of cutting aluminium was carried out to investigate the feasibility and the limitations or constrains for cutting metals on them. First the mode shapes of 6-axes FANUC welding robot were taken and analysed, and next the cutting processes were practically carried out on it. The results of study were found out to show the feasibility of cutting processes at end-milling under 6mm of tool diameter. as well as to have some limitations and constrains, for examples, surface roughness and feed rate, depth of cut, cutting force etc..

  • PDF

Innovative Modeling and Simulation of Reacting Flow with Complex Confined Boundaries

  • Kim, Ki-Hong;Yoh, Jai-Ick
    • 한국추진공학회:학술대회논문집
    • /
    • 한국추진공학회 2008년 영문 학술대회
    • /
    • pp.311-319
    • /
    • 2008
  • We present an innovative method of multi physics application involving energetic materials. Energetic materials are related to reacting flows in extreme environments such as fires and explosions. They typically involve high pressure, high temperature, strong shock waves and high strain rate deformation of metals. We use an Eulerian methodology to address these problems. Our approach is naturally free from large deformation of materials that make it suitable for high strain rate multi-material interacting problems. Furthermore we eliminate the possible interface smearing by using the level sets. We heave devised a new level set based tracking framework that can elegantly handle large gradients typically found in reacting gases and metals. We show several work-in-progress application of our integrated framework.

  • PDF

다축 절삭가공용으로의 육관절 산업용 로봇의 적용평가 (Application Estimate of 6 Degree of Freedom Industrial Robot for Multi-Axes Cutting Machine)

  • 정선환;최성대;권현규;최은환
    • 한국기계가공학회지
    • /
    • 제2권4호
    • /
    • pp.33-39
    • /
    • 2003
  • The stiffness of multi-articulated industrial robots is very weak, because their structure is an articulated type with some links and joints. Thus it is known that cutting processes for metals are not accepted in machine shop well, but they have a lot of merits for cutting processes, for example, drilling, tapping, and engraving etc, because of the characteristics of their high degree of freedom. The temptation of cutting aluminium was carried out to investigate the feasibility and the limitations or constraints for cutting metals on them. First the mode shapes of 6 degree of freedom welding robot were taken and analysed, and next the cutting processes were practically carried out on it. The results of study were found out to show the feasibility of cutting processes at drilling under 6mm of tool diameter, as well as to have some limitations and constraints, for examples, feed rate, depth of cut and cutting force etc.

  • PDF

Biosorption of Cr, Cu and Al by Sargassum Biomass

  • Lee, Hak-Sung
    • Biotechnology and Bioprocess Engineering:BBE
    • /
    • 제2권2호
    • /
    • pp.126-131
    • /
    • 1997
  • The biosorption and desorption of Cr, Cu and Al were carried out using brown marine algae Sargassum fluitans biomass, known as the good biosorbent of heavy metals. The content of alginate bound to light metals could be changed by physical and chemical pretreatment. The maximum uptake of Cr, Cu and Al was independent of the alginate content. The maximum uptaker of Al was two times(mole basis) than those of Cu and Cr. The aluminum-alginate complex was found in the sorption solution of raw and protonated biomass. Most of Cu, Al and light metals sorbed in the biomass were eluted at pH 1.1. However, only 5 to 10% of Cr sorbed was eluted at pH 1.1. The stoiceometric ion exchange between Cu and Ca ion was observed on Cu biosorption with Ca-loaded biomass. A part of Cr ion was bound to biomass as Cr(OH)2+ or Cr(OH)2+. Al was also bound to biomass as multi-valence ion and interfered with the desorbed Ca ion. The behavior of raw S. fluitans in ten consecutive sorption-desorption cycles has been investigated in a packed bed flow-through-column during a continuous removal of copper from a 35 mg/L aqueous solution at pH 5. The eluant used was a 1%(w/v) CaCl2/HC solution at pH 3.

  • PDF

ITO/Ag/ITO 투명전도막의 전기적 특성 (Electrical Properties of ITO/Ag/ITO Conducting Transparent Thin Films)

  • 채홍철;백창현;홍주화
    • 대한금속재료학회지
    • /
    • 제49권2호
    • /
    • pp.192-196
    • /
    • 2011
  • The multi-layered thin film with an ITO/Ag/ITO structure was produced on PET by using magnetron reactive sputtering method. First, 30 nm of ITO thin film was coated on PET by using normal temperature process. Then 20-52 nm of the Ag thin film was coated. Lastly, 30 nm of ITO thin film was coated on Ag layer. The sample of the 20 nm Ag thin film showed more than 70% transmission and a $2.7{\Omega}/{\Box}$ sheet resistance. When compared to the existing single-layered transparent conducting thin film, multi-layered film was found to be superior with about $5{\Omega}/{\Box}$ less sheet resistance. However, since the Ag layer became thinner, the band gap energy needs to be increased to more than 3.5 eV.