• Title/Summary/Keyword: Multi-metals

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Water treatment sludge for removal of heavy metals from electroplating wastewater

  • Ghorpade, Anujkumar;Ahammed, M. Mansoor
    • Environmental Engineering Research
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    • v.23 no.1
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    • pp.92-98
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    • 2018
  • Suitability of aluminium-based water treatment sludge (WTS), a waste product from water treatment facilities, was assessed for removal of heavy metals from an electroplating wastewater which had high concentrations of copper and chromium along with other heavy metals. Batch tests with simulated wastewater in single- and multi-metal solutions indicated the influence of initial pH and WTS dose on removal of six metals namely Cu(II), Co(II), Cr(VI), Hg(II), Pb(II) and Zn(II). In general, removal of cationic metals such as Pb(II), Cu(II) and Zn(II) increased with increase in pH while that of anionic Cr(VI) showed a reduction with increased pH values. Tests with multi-metal solution showed that the influence of competition was more pronounced at lower WTS dosages. Column test with diluted (100 times) real electroplating wastewater showed complete removal of copper up to 100 bed volumes while chromium removal ranged between 78-92%. Other metals which were present in lower concentrations were also effectively removed. Mass balance for copper and chromium showed that the WTS media had Cu(II) and Cr(VI) sorption capacities of about 1.7 and 3.5 mg/g of dried sludge, respectively. The study thus indicates that WTS has the potential to be used as a filtration/adsorption medium for removal of metals from metal-bearing wastewaters.

Thermal Properties of Diamond Aligned Electroless Ni Plating Layer/Oxygen Free Cu Substrates (다이아몬드 배열 무전해 니켈 도금층/무산소동 기판의 열전도도 특성)

  • Jeong, Da-Woon;Kim, Song-Yi;Park, Kyoung-Tae;Seo, Seok-Jun;Kim, Taek Soo;Kim, Bum Sung
    • Journal of Powder Materials
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    • v.22 no.2
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    • pp.134-137
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    • 2015
  • The monolayer engineering diamond particles are aligned on the oxygen free Cu plates with electroless Ni plating layer. The mean diamond particle sizes of 15, 23 and $50{\mu}m$ are used as thermal conductivity pathway for fabricating metal/carbon multi-layer composite material systems. Interconnected void structure of irregular shaped diamond particles allow dense electroless Ni plating layer on Cu plate and fixing them with 37-43% Ni thickness of their mean diameter. The thermal conductivity decrease with increasing measurement temperature up to $150^{\circ}C$ in all diamond size conditions. When the diamond particle size is increased from $15{\mu}m$ to $50{\mu}m$ (Max. 304 W/mK at room temperature) tended to increase thermal conductivity, because the volume fraction of diamond is increased inside plating layer.

Competitive Adsorption of Multi-species of Heavy Metals onto Sandy Clay Loam and Clay Soils (사질식양토와 식토에서 중금속 이온의 다중 경쟁 흡착)

  • Chung, Doug Y.;Noh, Hyun-Hee
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.5
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    • pp.238-246
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    • 2005
  • We conducted this investigation to observe competitive adsorption phenomena among the heavy metals onto the available sorption sites of soil particle surfaces in sandy clay loam and clay soil collected from Nonsan city, Chungnam and Yoosung, Daejeon in Korea, respectively. Polluted and contaminated soils can often contain more than one heavy metal species, resulting in competition for available sorption sites among heavy metals in soils due to complex competitive ion exchange and specific sorption mechanism. And the adsorption characteristics of the heavy metals were reported that the selectivity for the sorption sites was closely related with electropotential and electro negativity carried by the heavy metals. The heavy metals were treated as single, binary and ternary systems as bulk solution phase. Adsorption in multi-element system was different from single-element system as Cr, Pb and Cd. The adsorption isotherms showed the adsorption was increased with increasing equilibrium concentrations. For binary and ternary systems, the amount of adsorption at the same equilibrium concentration was influenced by the concentration of individual ionic species and valence carried by the respective heavy metal. Also we found that the adsorption isotherms of Cd and Pb selected in this experiment were closely related with electronegativity and ionic potential regardless number of heavy metals in solution, while the adsorption of Cr carried higher valance and lower electro negativity than Cd and Pb was higher than those of Cd and Pb, indicating that adsorption of Cr was influenced by ionic potential than by electronegativity. Therefore adsorption in multi-element system could be influenced by electronegativity and ionic potential and valance for the same valance metals and different valance, respectively. But it still needs further investigation with respect to ionic strength and activity in multi-element system to verify sorption characteristics and reaction processes of Cr, especially for ternary system in soils.

How to Prepare the Manuscript for Submission to the Proceedings of KSPE Conference (고에너지 물질 연소를 기반으로 한 Multi Physics Modeling)

  • Kim, Ki-Hong;Yoh, Jai-Ick
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.04a
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    • pp.238-241
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    • 2007
  • We present an innovative method of multi-physics application involving energetic materials. Energetic materials are related to reacting flows in extreme environments such as fires and explosions. They typically involve high pressure, hish temperature, strong non-linear shock waves, and high strain rate deformation of metals. We use an Eulerian methodology to address these problems. Our approach is naturally free from large deformation of materials that makes it suitable for high strain-rate multi-material interaction problems. Furthermore we eliminate the possible interface smearing by using the level sets. We have devised a new level set based tracking framework that can elegantly handle large gradients typically found in reacting gases and metals. We show several work-in-progress applications of our algorithm including the Taylor impact test, explosive venting and additional confined explosion problems of modem interest.

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A study on jewelry-making using a multi-casting (다중주물을 활용한 주얼리 제작에 관한 연구)

  • Lee, Jung Soo;Kim, Hyeong Seong
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.5
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    • pp.223-226
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    • 2012
  • There are many restrictions in conventional ways of Jewelry mass production which are Mokume Gane, Inlaid Technology based on a joining work of dissimilar metals. To overcome this, Multi-Casting using both Jewelry-Casting and CAD/CAM has presented. In experiment on Muti-Casting, second original sample which was produced by CAD/CAM is 5 % smaller than first one. The first and second castings are brass and silver, respectively. When making second sample, the temperature of flask was about $150{\sim}200^{\circ}C$ higher than the standard temperature of flask when making castings. Through the Multi-Casting, it was found that there was no trouble making dissimilar metals Jewelry which can be mass produced.

A Study on the Endmilling using the Multi-Articulated Robot (다관절 로봇을 이용한 엔드밀 가공에 관한 연구)

  • 최은환;정선환;최성대
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.1772-1775
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    • 2003
  • The stiffness of multi-articulated industrial robots is very weak, because their structure is an articulated type with some links and joints. Thus it is known that cutting processes for metals are not accepted in machine shop well, but they have a lot of merits for cutting processes, for example. drilling, tapping. and engraving etc., because of the characteristics of their high degree of freedom. The temptation of cutting aluminium was carried out to investigate the feasibility and the limitations or constrains for cutting metals on them. First the mode shapes of 6-axes FANUC welding robot were taken and analysed, and next the cutting processes were practically carried out on it. The results of study were found out to show the feasibility of cutting processes at end-milling under 6mm of tool diameter. as well as to have some limitations and constrains, for examples, surface roughness and feed rate, depth of cut, cutting force etc..

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Innovative Modeling and Simulation of Reacting Flow with Complex Confined Boundaries

  • Kim, Ki-Hong;Yoh, Jai-Ick
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.311-319
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    • 2008
  • We present an innovative method of multi physics application involving energetic materials. Energetic materials are related to reacting flows in extreme environments such as fires and explosions. They typically involve high pressure, high temperature, strong shock waves and high strain rate deformation of metals. We use an Eulerian methodology to address these problems. Our approach is naturally free from large deformation of materials that make it suitable for high strain rate multi-material interacting problems. Furthermore we eliminate the possible interface smearing by using the level sets. We heave devised a new level set based tracking framework that can elegantly handle large gradients typically found in reacting gases and metals. We show several work-in-progress application of our integrated framework.

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Application Estimate of 6 Degree of Freedom Industrial Robot for Multi-Axes Cutting Machine (다축 절삭가공용으로의 육관절 산업용 로봇의 적용평가)

  • Cheong, Seon-Hwan;Choi, Seong-Dae;Kweon, Hyun-Kyu;Choi, Eun-Hwan
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.2 no.4
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    • pp.33-39
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    • 2003
  • The stiffness of multi-articulated industrial robots is very weak, because their structure is an articulated type with some links and joints. Thus it is known that cutting processes for metals are not accepted in machine shop well, but they have a lot of merits for cutting processes, for example, drilling, tapping, and engraving etc, because of the characteristics of their high degree of freedom. The temptation of cutting aluminium was carried out to investigate the feasibility and the limitations or constraints for cutting metals on them. First the mode shapes of 6 degree of freedom welding robot were taken and analysed, and next the cutting processes were practically carried out on it. The results of study were found out to show the feasibility of cutting processes at drilling under 6mm of tool diameter, as well as to have some limitations and constraints, for examples, feed rate, depth of cut and cutting force etc.

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Biosorption of Cr, Cu and Al by Sargassum Biomass

  • Lee, Hak-Sung
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.2 no.2
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    • pp.126-131
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    • 1997
  • The biosorption and desorption of Cr, Cu and Al were carried out using brown marine algae Sargassum fluitans biomass, known as the good biosorbent of heavy metals. The content of alginate bound to light metals could be changed by physical and chemical pretreatment. The maximum uptake of Cr, Cu and Al was independent of the alginate content. The maximum uptaker of Al was two times(mole basis) than those of Cu and Cr. The aluminum-alginate complex was found in the sorption solution of raw and protonated biomass. Most of Cu, Al and light metals sorbed in the biomass were eluted at pH 1.1. However, only 5 to 10% of Cr sorbed was eluted at pH 1.1. The stoiceometric ion exchange between Cu and Ca ion was observed on Cu biosorption with Ca-loaded biomass. A part of Cr ion was bound to biomass as Cr(OH)2+ or Cr(OH)2+. Al was also bound to biomass as multi-valence ion and interfered with the desorbed Ca ion. The behavior of raw S. fluitans in ten consecutive sorption-desorption cycles has been investigated in a packed bed flow-through-column during a continuous removal of copper from a 35 mg/L aqueous solution at pH 5. The eluant used was a 1%(w/v) CaCl2/HC solution at pH 3.

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Electrical Properties of ITO/Ag/ITO Conducting Transparent Thin Films (ITO/Ag/ITO 투명전도막의 전기적 특성)

  • Chae, Hong-Chol;Baeg, Chang-Hyun;Hong, Joo-Wha
    • Korean Journal of Metals and Materials
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    • v.49 no.2
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    • pp.192-196
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    • 2011
  • The multi-layered thin film with an ITO/Ag/ITO structure was produced on PET by using magnetron reactive sputtering method. First, 30 nm of ITO thin film was coated on PET by using normal temperature process. Then 20-52 nm of the Ag thin film was coated. Lastly, 30 nm of ITO thin film was coated on Ag layer. The sample of the 20 nm Ag thin film showed more than 70% transmission and a $2.7{\Omega}/{\Box}$ sheet resistance. When compared to the existing single-layered transparent conducting thin film, multi-layered film was found to be superior with about $5{\Omega}/{\Box}$ less sheet resistance. However, since the Ag layer became thinner, the band gap energy needs to be increased to more than 3.5 eV.