• Economic and Environmental Geology
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• v.53 no.1
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• pp.23-32
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• 2020

Geological CO₂ sequestration is a global warming response technology to limit atmospheric emissions by injecting CO₂ captured on a large scale into deep geological formations. The presented results concern mineralogical and hydrogeological investigations (FE-SEM, XRD, XRF, and MICP) of mudstone samples from drilling cores of the Pohang basin, which is the research area for the first demonstration-scale CO₂ storage project in Korea. They aim to identify the mineral properties of the mudstone constituting the caprock and to quantitatively evaluate the hydrogeologic sealing capacity that directly affects the stability and reliability of geological CO₂ storage. Mineralogical analysis showed that the mudstone samples are mainly composed of quartz, K-feldspar, plagioclase and a small amount of pyrite, calcite, clay minerals, etc. Mercury intrusion capillary pressure analysis also showed that the samples generally had uniform particle configurations and pore distribution and there was no distinct correlation between the estimated porosity and air permeability. The allowable CO₂ column heights based on the estimated pore-entry pressures and breakthrough pressures were found to be significantly higher than the thickness of the targeting CO₂ injection layer. These results showed that the mudstone layers in the Yeongil group, Pohang basin, Korea have sufficient sealing capacity to suppress the leakage of CO₂ injected during the demonstration-scale CO₂ storage project. It should be noticed, however, that the applicability of results and analyses in this study is limited by the lack of available samples. For rigorous assessment of the sealing efficiency for geological CO₂ storage operations, significant efforts on collection and multi-aspect evaluation for core samples over entire caprock formations should be accompanied.

• Economic and Environmental Geology
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• v.50 no.4
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• pp.303-311
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• 2017

The laboratory scale experiment was performed to evaluate the sealing capacity of the capping rock such as tuff and mudstone, measuring the intial supercritical $CO_2$ ($scCO_2$) injection pressure and the $scCO_2$-water-rock reaction for 90 days. The drilling cores sampled from 800 m in depth around the Janggi basin, Korea were used for the experiment. The mineralogical changes of mudstone and tuff were measured to evaluate the geochemical stability during the $scCO_2$-water-rock reaction at $CO_2$ storage condition (100 bar and $50^{\circ}C$). The rock core was fixed in the high pressurized stainless steel cell and was saturated with distilled water at 100 bar of pore water pressure. The effluent of the cell was connected to the large tank filled with 3 L of water and 2 L of $scCO_2$ at 100 bar, simulating the subsurface injection condition. The $scCO_2$ injection pressure, which was higher than 100 bar, was controlled at the influent port of the cell until the $scCO_2$ begin to penetrate into the rock and the initial injection pressure (> 100 bar) of $scCO_2$ into the rock was measured for each rock. The mineralogical compositions of mudstones after 90 days reaction were similar to those before the reaction, suggesting that the mudstone in the Janggi basin has remained relatively stable for the $scCO_2$ involved geochemical reaction. The initial $scCO_2$ injection pressure (${\Delta}P$) of a tuff in the Janggi basin was 15 bar and the continuous $scCO_2$ injection into the tuff core occurred at higher than 20 bar of injection pressure. For the mudstone in the Janggi basin, the initial $scCO_2$ injection pressure was higher than 150 bar (10 times higher than that of the tuff). From the results, the mudstone in Janggi basin was more suitable than the tuff to shield the $scCO_2$ leakage from the reservoir rock at subsurface.

• Geotechnical Engineering
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• v.10 no.4
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• pp.5-16
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• 1994

This paper is concerned with the engineering characteristics weathered mudstone soil in Pohang area. The crushability of weathered Boil can be described in terms of the ratio of surface area(Sw'/Sw). In this study, the characteristics of weathered mudstone soil was investigated by performing teat such as compaction. CBR, permeability, and grain size according to compaction energy. The results are found as follows : (1) In generally, the specific gravity of weathered mudstone soil is very small and optimum moisture content (OMC) is large and maximum dry density is small (2) The CBR value increases as the compaction energy increases, but this value decreses from D -2 compaction(26kg.cm/cm3). the swelling ratio increases the npaction energy to 20.6kg.cm/cm" and decreases in all compaction energy from 20.6kg.cm/cm3 (3) As the compaction energy is small, the change of permeability due to water content is large and the difference between minimum coefficient of permeability and coefficient of permeability at OMC is large, but the difference is small as the compaction energy increases (4) The decrease of permeability due to the decrease of void ratio and the increase of ratio of surface area is caused by the crush of particle due to the increase in compaction energy. Especially, the compaction energy is smaller, the change of the ratio of surface area to the coefficient of permeability is larger.rger.

• Journal of the Mineralogical Society of Korea
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• v.17 no.1
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• pp.49-59
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• 2004

Organic smectite was hydrothermally synthesized by treating the opal-rich siliceous mudstone from the Pohang area with TMAOH solutions and 1:1 solutions of TMAOH+NaOH at $80^{\circ}C$ and concentrations ranging 10∼15%. Smectite was solely formed without accompanying any mineral products in case of TMAOH, whereas NaP and hydroxysodalite was synthesized together with smectite under the blending solution of TMAOH+NaOH. The synthesized smectite is identified as an organic smectite intercalating $TMA^{+}$ within its interlayer site, specifically corresponding to monmorillonite species, through mineralogical characterization by XRD, DTA, and IR analyses. The experimental results indicate that main precursor of the synthesized smectite is undoubtedly opal-CT, and the original sedimentary smectite included as considerable amounts in the mudstone seems to play a major role as Al-sources necessary far the smectite formation. Original inert components such as quartz and mica do not affect mostly to the synthesis reaction, and thus, are resultantly found as impurities in the synthetic products. These experimental results may imply that a new effective method for the low-temperature (less than $100^{\circ}C$) hydrothermal synthesis of organic smectite will be established if some Al-sources adequate for this synthetic system are available.

• The Journal of the Petrological Society of Korea
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• v.25 no.4
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• pp.335-348
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• 2016

The fluvial Tamna Formation, consisting of conglomerate, sandstone and mudstone layers, is widely distributed in Jeiu Island. Various sizes of quartz crystals were identified from most of the Tamna Formation, including the mudstone layer. XRD analysis also shows that the mudstone layer is composed of various minerals, quartz, plagioclase, K-feldspar, mica, magnetite, hematite, olivine, amphibole, gibbsite, calcite, analcime and clay minerals such as illite, kaolinite, vermiculite, smectite, chlorite, $10{\AA}$-halloysite. There is a tendency showing that the more amount of kaolinite, vermiculite, and chlorite is present where the more amount of quartz crystals is present. It is likely that the main source materials contributing to the Tamna Formation were from the parental rocks containing abundant quartz grains, suggesting that the Tamna Formation could not be related to Jeju volcanic rocks, but possibly to pre-existing basement rocks. Thus, we propose that the Tamna Formation was formed from the materials derived from both pre-existing basement rocks and Jeju volcanic rocks, which were subsequently affected by diagenesis, hydrothermal alteration and weathering process.

• Journal of the Korean Geosynthetics Society
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• v.12 no.3
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• pp.31-41
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• 2013

In this study, the properties of mudstone weathered soils related to landslides were analyzed at the area of landslide induced by heavy rainfall in Pohang. The soil tests were carried out to the soils obtained from landslide and non landslide sites, and the soil properties were investigated. The correlation between soil properties and landslides were analyzed using statistical technique, and then the soil factors were extracted from the correlation analysis. The correlation equation which can calculate the coefficient of permeability influenced on landslides was proposed using the soil factors. As the result of analysis, the porosity and unit weight of soils from the landslide area is smaller than those of soils from the non landslide area. The soils with poor grain size distribution and loose unit weight are prone to landslides because the soils have a large void ratio and a low unit weight. The permeability of soils from the landslide area is larger than that of soils from the non landslide area. According to the result of correlation analysis, the effective grain size, the saturated unit weight and silt and clay contents are evaluated as the influence factors. These factors were considered to estimate the coefficient of permeability of mudstone weathered soils.

• Geotechnical Engineering
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• v.11 no.4
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• pp.63-74
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• 1995

Much of Taegu and Kyungpook areas are composed of sedimentary rocks. This paper is concerned with the engineering characteristi os of weathered shale soils and mudstone soils. In this study, the engineering characteristics of weathered shale soils and mudstone soils are investigated by performing tests such as compaction, gradation, CBR permeability and crushability according to compaction energy and water content. The experiments were carried out to obtain the relationships of the ratio of surface area(Sw'/Sw) and the indez of crushing(IC) The results are found as follows : (1) Weathered shale soils are larger than weathered mudstone soils in maximun dry den sixty, but weathered shale soils are smaller than weathered mudstone soils in OMC. (2) Minimum permeability is found in OMC's 1~2% wet side, and the more compaction energy is high, the more the change's range of permeability becomes narrow. (3) There is linear correlation between the ratio of surface area and the indez of crushing. IC : 14.286sw'/Sw -8.429(r=0.9937) (4) Soaked CBR value becomes maximum in OMC's dry side, and it decreases as the water content increases. Whereas the more compaction energy is high the more unsoaked and soaked CBR values are high in OMC's dry side, unsoaked and soaked CBR values are opposed to that in OMC's wet side.

• Proceedings of the Korea Concrete Institute Conference
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• 1996.04a
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• pp.52-56
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• 1996

In this study, when natural mineral with Silica components(Zeolite & Mudstone) abundant in Korea used as an admixture for concrete, it is investigated that the properties of strength increase and economic effect compared with Silica Fume, the general admixture of high strength concrete.

• Proceedings of the Korean Society for Rock Mechanics Conference
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• 2004.10a
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• pp.137-148
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• 2004

• 한국해양학회지
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• v.20 no.2
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• pp.40-48
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• 1985

The depositional conditions and paleo-oceanography of the Hoedongri Formation(Silurian) distributed in the Hoedongri, Jeongseon-Kun, Kangweon-Do, Korea were investigated. The major rock types and facies of the Hoedongri Formation consist of mudstone and wackestone facies in which the content of insoluble residues is relatively high (average. 17%). The sedimentary structures observed in the Hoedongri Formation being helpful to the interpretation of depositional conditions are; crypt-algalaminates, bird's eye structures, evaporite pseudomorphs, dolomite mottle structures, detrital quartz pockets and cross bedding. Based on the rock types, facies and sedimentary structures of the Hoedongri Formation, it seems that the Hoedongri Formation might be deposited in a saline supratidal and intertidal zone.