• Title/Summary/Keyword: Mono-ammonium phosphate

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A Study on Low Temperature Properties of Kaolin-Phosphate-Water Systems (카올린-인산염-물계의 저온 특성에 관한 연구)

  • 박금길;박근원
    • Journal of the Korean Ceramic Society
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    • v.18 no.3
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    • pp.192-200
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    • 1981
  • This study deals with the low temperature ($25^{\circ}C$-$600^{\circ}C$) properties of Kaolin-Phosphate-water systems. Phosphoric acid, mono aluminum phosphate, mono ammonium phosphate, the mixture of phosphoric acid and mono aluminum phosphate, and the mixture of phosphoric acid and mono ammonium phosphate were used to characterize the M.O.R. of the systems with to quantity of phosphates, curing time, and firing temperature. Firing shrinkage, viscosity, surface tension, DTA, TGA, and X-ray diffraction patterns were also measured in order to investigated the factors of strengthening. The results of this study were summarized as follows: 1. The M.O.R. of kaolin-phosphate systems were stronger than that of Kaolin-water system at room temperature or low temperature($25^{\circ}C$-$600^{\circ}C$). Though it was increased according to the longer curing time, the higher temperature, and the more addition of phosphate, the M.O.R. were decreased in the case of 10 wt% phosphate addition in the system of phosphoric acid, mono aluminum phosphate and phosphoric acid-mono aluminum phosphate. 2. When the concentration of Phosphate was at 4 wt%, the M.O.R. of specimen cured at $25^{\circ}C$ and added to the phosphoric acid was strongest among the specimens in added to the others phosphates. Whereas, when the concentration of phosphate was above 6wt%, the M.O.R. of specimen cured at $25^{\circ}C$ and added to the phosphoric acid mono ammonium phosphate system cured at $25^{\circ}C$ was the strongest. 3. The M.O.R. of the specimen heated, in the temperature range of 15$0^{\circ}C$-1$600^{\circ}C$, and added to the mixture of phosphoric acid-mono aluminum phosphate system or phosphoric acid-mono ammonium phosphate system was stronger than that of specimen added to Phosphoric acid, mono-aluminum Phosphate or mono-ammonium phosphate alone. 4. The bonding force of phosphate binders was more closely related to surface tension than viscosity and it tended to be inversely proportional to surface tension. The bonding force after heating treatment seemed to be caused by the change of structure of phosphate according to heating.

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A Study on High Temperature properties of Kaolin-Phosphate-Water Systems (카올린-인산염-물계의 고온특성에 관한 연구)

  • 박금길;장영재
    • Journal of the Korean Ceramic Society
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    • v.18 no.4
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    • pp.229-236
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    • 1981
  • This study deals with the high temperature (600-135$0^{\circ}C$) properties of Kaolin-Phosphate-Water systems. Phosphoric acid, mono aluminum phosphate, mono ammonium phosphate, the mixture of phosphoric acid and mono aluminum phosphate, and the mixture of phosphoric acid and mono ammonium phosphate were used to characterize the M.O.R of the systems with to quantity of phosphates and firing temperature. Firing shrinkage, creeptest, DTA, TGA, and X-ray diffraction patterns were also measured in order to investigate the factors of strengthening. The resules of the experiments are as follows: 1. Linear shrinkage of kaolin-phosphate systems become larger as the firing temperature rise, and generally in the firing temperature of $600^{\circ}C$ and 100$0^{\circ}C$ the test pieces with phosphate binder show larger then Kaolin-Water system in linear shrinkage and reversed trends were found at 120$0^{\circ}C$ and 135$0^{\circ}C$. 2. Cold M.O.R. of kaolin-phosphate systems show higher trends in strength as the firing temperature rise. Comparing M.O.R. of test pieces after firing at 135$0^{\circ}C$, the mixture of phosphoric acid-mono aluminum phosphate, and phosphoric acid mono ammonium phosphate systems show higher strength than kaolin-mono aluminum phosphate system which widely used, and it shows highest strength when the mole ratio of phosphoric acid and mono ammonium phosphate is 1:1 among the test pieces of kaolin-phosphate systems. 3. The refractoriness of kaolin-phosphate systems are more deteriorated than Kaolin-Water system, and generally, the more addition of phosphate, the lower the refractoriness, however in the range of 4-8% phosphate addition, the difference of the fusion temperature is about 7$0^{\circ}C$. 4. The test pieces of T1 and T2 in creep test were same or even higher than kaolin-water system when 6% of phosphoric acid-mono ammonium phosphate was added to kaolin. 5. In case where the phosphoric acid-mono ammonium phosphate was added to kaolin in mole ratio 1:1 the cold M.O.R., after firing at 135$0^{\circ}C$, refractoriness and $T_2$ in creep test show better results than kaolin-mono-aluminum phosphate system which is widely used. 6. Phosphoric acid and mono ammonium phosphate react with kaolin in temperature over 100$0^{\circ}C$, and it forms aluminum phosphate.

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An Experimental Study on the Properties of Ultra Rapid Hardening Mortar Using Magnesia-Phosphate Cement (마그네시아 인산염 시멘트를 사용한 보수용 초속경 모르타르의 특성에 관한 실험적 연구)

  • Ahn, Moo-Young;Jung, Sang-Jin
    • Journal of the Korea Institute of Building Construction
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    • v.7 no.4
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    • pp.109-116
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    • 2007
  • Building structures are generally large in size and have a long life, and the construction of such structures requires the investment of a huge amount of money and social infrastructure. Furthermore, building structures are closely related to people's life. Recently, however, the rapid development of society has been worsening air pollution, which is in turn accelerating the degradation of building structures. Thus, the safety of building structure is emerging as a critical issue. To cope with this problem, the government enacted "The Special Act on Safety Control for Infrastructure" but we need engineers' higher concern over the maintenance and reinforcement of existing structures. Recently researches are being made actively on repair mortar using ultra rapid hardening cement for recovering the performance of structures. The present study conducted an experiment on the basic physical properties of ultra rapid hardening mortar for repairing and reinforcing building structures using magnesia cement and mono-ammonium phosphate. In the experiment, we changed the water-cement ratio and carried out replacement at different ratio of MAP/MgO(%). We used retarder to have working life, and made comparative analysis through evaluating working life and fluidity and measuring strength by age.

The Anti-Microbial Activity of Modified Chitosan. (변형 키토산의 항균효과)

  • 정병옥;강성태;정석진
    • Microbiology and Biotechnology Letters
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    • v.26 no.4
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    • pp.338-344
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    • 1998
  • New type of chitosan derivatives, chitosan-g-MAP, were synthesized by graft copolymerization of mono (2-methacryloyl oxyethyl) acid phosphate (MAP) into chitosan, in order to solubilize chitosan in water. Ceric ammonium nitrate was used as an initiator for graft copolymerization. The optimal conditions for graft copolymerization were determined on the basis of reaction temperature, time, and the concentration of initiator and monomer. The reaction conditions for the highest percentage of grafting were as follows: an initiator concentration, 3.5${\times}$10$\^$-3/ M; monomer concentration, 0.19 M; and reaction temperature, 40$^{\circ}C$ The reaction rate reached the maximum value after 4 hrs of reaction. Antifungal activity was tested against Candida albicans, Trichophyton rubrum and Trichophyton violaceum by using chitosan-g-MAP and two other chitosan samples which have degree of deacetylation of 70% (DA-7) and 90% (DA-90). Their antifungal activities were investigated in weak acidic range. Maximum antifungal activity of them was observed at pH 5.75. Chitosan-g-MAP inhibited thoroughly the growth of Candida albicans and Trichophyton violaceum. Howerver, DA-70 and DA-90 showed higher antifungal activities on Trichophyton rubrum than that of chitosan-g-MAP.

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Studies on Fire-Retardant-Treatment and Press Drying of Plywood (합판(合板)의 내화처리(耐火處理)와 열판건조(熱板乾燥)에 관(關)한 연구(硏究))

  • Lee, Phil-Woo;Kim, Jong-Man
    • Journal of the Korean Wood Science and Technology
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    • v.10 no.1
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    • pp.5-37
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    • 1982
  • Plywood used for construction as a decorative inner material is inflammable to bring large fire accidents and burn out human life and their properties. To diminish the fire disaster, fire retardant plywood has been required indeed. In the methods of manufacturing the fire retardant plywood the soaking method is occasionally used. However after soaking plywood into fire retardant chemical solutions, redrying of soaked plywood is the most important. In this study, 3.5mm thin and 5.0mm thick plywoods were selected for fire retardant treatment. Treating solutions were prepared for 20% dilute solutions of ammonium sulfate, monoammonium phosphate, diammonium phosphate, borax-boric acid and minalith, and water solution. 1-, 3-, 6-, and 9 hour-soaking treatments were applied and after treatments hot plate drying was applied to those treated plywoods at $90^{\circ}C$, $120^{\circ}C$ and $150^{\circ}C$, of press temperature. Drying rates, drying curves, water absorption rates of fire retardant chemicals, weight per volume and fire retardant degree of plywood were investigated. The results may be summarized as follows: 1. The plywoods treated with ammonium sulfate, monoammonium phosphate and diammonium phosphate and diammonium phosphate showed increase of chemical absorption rate with proportion to increase of treating time, but not in case of the plywood treated with borax-boric acid and minalith. 2. In the treatment of definite time, the absorption rate per unit of volume of plywood showed higher in thin plywood (thickness of 3.5mm) than in thick plywood (thickness of 5.0mm). In both thin and thick plywoods, the highest absorption rate was observed in 9 hour-treatment of ammonium sulfate. The value was 1.353kg/$(30cm)^3$ in thin plywood and 1.356kg/$(30cm)^3$ in thick plywood. 3. The volume per weight of plywood after chemical treatment increased remarkably and. after hot plate drying, the values were to a little extent higher than before chemical treatment. 4. The swelling rates of thickness in chemical-treated plywoods increased similarly with that of water-treated plywood in 1- and 3 hour-treatment of both thin and thick plywoods. But in 6- and 9 hour-treatment, the greater increased value showed in water-treated ply wood than any other chemical, especially in thick plywood. 5. The shrinkage rates after hot plate drying showed the same tendency as the swelling rate, and the rate showed the increasing tendency with proportion to increase of treating time in thick plywood of both chemical and water treatments. 6. Among drying curves, the curves of water-treated plywood placed more highly than chemical-treated plywood without-relation to thickness in 6- and 9 hour-treatment except in 1- and 3 hour-treatment. 7. The drying rate related to thickness of treated plywood, was twice above in thin plywood compared with thick plywood. 8. The drying rate remarkably increased with proportion to increase of the plate temperature and, the values were respectively 1.226%/min., 6.540%/min., 25.752%/min. in hot plate temperature of $90^{\circ}C$, $120^{\circ}C$, $150^{\circ}C$ in thin plywood and 0.550%/min., 2.490%/min, 8.187%/min, in hot plate temperature of $90^{\circ}C$, $120^{\circ}C$, $150^{\circ}C$ in thick plywood. 9. In the treatment at $120^{\circ}C$ of hot plate temperature, the drying rates of chemical-treated plywood showed the highest value in monoammonium phosphate of thin plywood and in diammonium phosphate of thick plywood. But the drying rate of water-treated plywood was highest in 6- and 9 hour-treatment. 10. The fire retardant degree of chemical-treated plywood was higher than that of the untreated plywood as shown in loss of weight, burning time, flame-exhausted time and carbonized area. 11. The fire-retardant effect among fire retardant chemicals were the greatest in diammonium phosphate, the next were in monoammonium phosphate and ammonium sulfate, and the weakest were in borax-boric and minalith.

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Effect of Temperature, pH and Addition of Minerals in Lactic Acid Fermentation using Enterococcus faecalis RKY1. (Enterococcus faecalis RKYl을 이용한 젖산발효에서 온도, pH및 미량원소 첨가의 영향)

  • 윤종선;위영중;오후록;류화원
    • Microbiology and Biotechnology Letters
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    • v.30 no.3
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    • pp.258-263
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    • 2002
  • In this study the effects of temperature, pH, and addition of some minerals were investigated in lactic acid fermentation using Enterococcus faecalis RKYI . As a result, strain of RKYl had retained biological activity at the wide range of temperature($34-46^{\circ}C$) and pH(6.0-9.0), and the optimum temperature and pH were $42^{\circ}C$ and 7.0, respectively. When the effect of various phosphate sources added on lactic acid fermentation was studied, di-basic forms of phos-phate(especially, ammonium phosphate and potassium phosphate) had more stimulating effect rather than mono-basic phosphate sources. And there were no perceivable effect of manganese and magnecium salts addition on lactic acid fermentation.

Study on Phosphate Investment for High Temperature Precision Castings(I);The Effect of Particle size and Distribution of Silica Sand on the characteristics of the Investment (고온정밀주조용 인산염계 매몰재에 관한 연구(I);매몰재의 특성에 미치는 규사의 입도와 입도분포의 영향)

  • Ahn, Ji-Hong;Lee, Jong-Nam
    • Journal of Korea Foundry Society
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    • v.5 no.2
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    • pp.85-96
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    • 1985
  • In order to investigate the effect of particle size and distribution of silica sand on the characteristics of investment, W/P ratio, setting time, temperature change during setting, setting expansion, thermal expansion and compressive strength of the investments were measured. In this experiment, magnesia clinker and mono ammonium phosphate were used as binder, and particle size and distribution of silica sand were classified for convinence into 10 categories. The main results obtained from this investigation were summerized as follows. 1. W/P ratio decreased with increase of particle size and evenness in distribution of sand grain. 2. Setting time decreased with increase of evenness in distribution of sand grain, and temperature during setting increased with evenness in distribution of sand grain. 3. Setting expansion decreased with increase of particle size, while it increased with evenness in distribution of sand grain. 4. Thermal expansion decreased with increase of particle size. 5. Compressive strength increased with increase of particle size and evenness in distribution of sand grain. From above results, G.F.N. 250 sand which contains 30% of 50-100 mesh could be recommended for investment casting.

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Incorporating concepts of biodiversity into modern aquaculture: macroalgal species richness enhances bioremediation efficiency in a lumpfish hatchery

  • Knoop, Jessica;Barrento, Sara;Lewis, Robert;Walter, Bettina;Griffin, John N.
    • ALGAE
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    • v.37 no.3
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    • pp.213-226
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    • 2022
  • Aquaculture is one of the fastest growing food producing sectors; however, intensive farming techniques of finfish have raised environmental concerns, especially through the release of excessive nutrients into surrounding waters. Biodiversity has been widely shown to enhance ecosystem functions and services, but there has been limited testing or application of this key ecological relationship in aquaculture. This study tested the applicability of the biodiversity-function relationship to integrated multi-trophic aquaculture (IMTA), asking whether species richness can enhance the efficiency of macroalgal bioremediation of wastewater from finfish aquaculture. Five macroalgal species (Chondrus crispus, Fucus serratus, Palmaria palmata, Porphyra dioica, and Ulva sp.) were cultivated in mono- and polyculture in water originating from a lumpfish (Cyclopterus lumpus) hatchery. Total seaweed biomass production, specific growth rates (SGR), and the removal of ammonium (NH4+), total oxidised nitrogen (TON), and phosphate (PO43-) from the wastewater were measured. Species richness increased total seaweed biomass production by 11% above the average component monoculture, driven by an increase in up to 5% in SGR of fast-growing macroalgal species in polycultures. Macroalgal species richness further enhanced ammonium uptake by 25%, and TON uptake by nearly 10%. Phosphate uptake was not improved by increased species richness. The increased uptake of NH4+ and TON with increased macroalgal species richness suggests the complementary use of different nitrogen forms (NH4+ vs. TON) in macroalgal polycultures. The results demonstrate enhanced bioremediation efficiency by increased macroalgal species richness and show the potential of integrating biodiversity-function research to improve aquaculture sustainability.

The application of Phosphate Magnesia Cement for Solidification of Soil (토양 고형화를 위한 인산염 마그네시아 시멘트 적용 연구)

  • Choi, Hun;Choi, Jun-Ok;Song, Myong-Shin;Moon, Chang-Yeol
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.533-536
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    • 2008
  • This study is the application of phosphate magnesia cement for solidification of soils. The object of the study is the application of the pavment of the farm roads. The new pavement method must be environmental, ecologic and durable. So, for solidification of farm road's soil, we use magnesia cement as quick setting, high strength materials. At magnesia phosphate cement, mixing ratio of mono ammonium phosphate and magnesia is 4:6 and w/b is 50 wt%, it show 14 MPa of compressive strength, and high hydration heat. Solidified soils that mixing ratios of magnesia cement and soil are 4:6 and 5:5 have very high durability for freezing and thawing.

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Characteristics of a New Obligate Methanol-Oxidizing Bacterium (새로운 절대 메탄올 산화세균의 분리 및 특성)

  • Kim, Si-Wook;Park, Yong-Ha
    • Korean Journal of Microbiology
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    • v.31 no.4
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    • pp.261-266
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    • 1993
  • A new methyltrophic bacterium which utilizes methanol as a sole source of carbon and energy was isolated from soil. It was Gram-negative, nonmotile, nonspore-forming rod, and strictly aerobic bacterium. Catalase and oxidase activities were present. Nitrate was reduced to nitrite. Vitamins and other growth factors were not required. Generation time was 1.6 hr under the optimal condition. The isolate assimilated methanol via the ribulose mono-phosphate pathway (Enter-Doudoroff varient) and did not have .alpha.-ketoglutarate dehydrogenase. It assimilated ammonia through glutamate dehydrogenase. The guanine plus cytosine content of the DNA was 61.0 mol%. The celular fatty acid composition was primarily straight-chain saturated $C^{16 : 0}$ acids (palmitic acids) and unsaturated $C_{16 :1}$ acid (palmitoleic acids), and the isolate also contained two unidentified $C_{17}$ branched fatty acids. The major ubiquinone was Q-8, and Q-6 and Q-7 were present as minor components. Phosphatidylethanolamine and phosphatidylglycerol were predominantly present, and diphosphatidyglycerol was also detected. Based on the physiological and biochemical properties, the isolate was assigned to a novel species of the genus Methylobacillus, Methylobacillus methanolovorus sp. nov.

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