• Journal of the Korean Chemical Society
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• v.67 no.5
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• pp.393-397
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• 2023

• Bulletin of the Korean Chemical Society
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• v.25 no.4
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• pp.460-465
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• 2004

Hydrofluoric acid has been used as a novel stripping agent for molybdenum(VI) after its extraction with Cyanex 301. In the extraction step, the effects of parameters such as type and initial concentration of acid, type of diluent, extractant concentration, metal concentration and temperature have been studied. In the stripping step, the effects of various stripping agents on stripping efficiency have been investigated. Hydrofluoric acid has been chosen as an effective stripping agent, and the effects of concentration of hydrofluoric acid, stripping time, volume of hydrofluoric acid and the number of stages of stripping have been studied. Molybdenum(VI) has been effectively separated from a large number of elements in binary mixtures, with a very high tolerance limit. Finally, the optimized method has been extended for the analysis of Mo(VI) in spent molybdenum catalysts.

• Economic and Environmental Geology
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• v.13 no.2
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• pp.117-127
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• 1980

Molybdenum as by-products of Sangdong tungsten mine occurrs in the form of molybdenite in quartz vein. The molybdenum contents of scheelite in Sangdong ore bodies ranges from trace to 8%, therefore the scheelites show variable fluorescence colores under ultra-violet lamp (short wave). The fluorescence color are in order high content of molybdenum, yellow, white and blue. The yellow fluorescing scheelite is dominant in upper ore vein, otherwise the blue fluorescent variety is dominant in lower ore vein. The fluorescence color of scheelite in the main ore vein show zonal distribution becoming progressively more blue outerwards, contrary more yellow innerwards, and even in single scheelite crystal, simillar zonal pattern is observed, too. Molybdenite occurrs as flakes or elongated blades at the margins of the quartz vein only molybdenite bearing quartz veins but also other sulfides mineral bearing quartz veins have mainly blue flourescing scheelites. We suggest that the molybdenum contents of the early stage ore solution are progressively decreased by a subsequent crystallization of the yellow fluorescing scheelites.

• Journal of Powder Materials
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• v.15 no.3
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• pp.214-220
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• 2008

In this study, consolidation behavior and hardness of commercially available molybdenum powder were investigated. In order to analyze compaction response of the powders, the elastoplastic constitutive equation based on the yield function by Shima and Oyane was applied to predict the compact density under uniaxial pressure from 100MPa to 700MPa. The compacts were sintered at $1400-1600^{\circ}C$ for 20-60 min. The sintered density and grain size of molybdenum were increased with increasing the compacting pressure and processing temperature and time. The constitutive equation, proposed by Kwon and Kim, was applied to simulate the creep densification rate and grain growth of molybdenum powder compacts. The calculated results were compared with experimental data for the powders. The effects of the porosity and grain size on the hardness of the specimens were explained based on the modified plasticity theory of porous material and Hall-Petch type equation.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.17 no.6
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• pp.38-45
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• 2018

Molybdenum flame spray coatings are widely used in industrial fields to enhance the performance of mechanical component parts such as pistons, shafts and clutches. This study investigates the surface characteristics of high tensile brass with molybdenum flame spray treatment using the clutch material for small ship. The surface characteristics after molybdenum flame spray treatment in high tensile brass were quantitatively analyzed for surface composition, coating layer thickness, friction coefficient, abrasion width and phenomenon, micro-hardness, and surface roughness.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.182.1-182.1
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• 2015

Transparent conducting oxides (TCOs)는 높은 투과율과 낮은 전기전도도를 갖고 있어 광다이오드, 태양전지 등 광소자에 적용하기 위해 많은 연구가 진행되어 왔다. 특히 Indium oxide 계열의 박막은 TCO 물질 중 하나로서 3.6 eV 의 wide bandgap을 가지고 있고, 높은 투과율과 낮은 전기 전도도 (< $10-3{\Omega}cm$)를 보여 다양한 응용이 가능해 오랫동안 연구 되어 지고 있다. 게다가 Indium oxide 계열의 박막은 낮은 가격과 화학적 안정성, 공정과정의 편의성 등 다양한 이점을 가지고 있어서 현재는 더 낮은 가격으로 생성해 더 높은 효율을 만드는데 관심이 집중되고 있다. 이러한 박막은 태양광 흡수층에서 생성되는 캐리어의 이동 및 외부 전극과의 접촉에서 발생하는 손실을 줄이기 위한 전극용 소재로 연구되어지고 있다. 본 연구에서는 Indium Molybdenum Oxide 박막을 Indium oxide와 Molybdenum 타겟을 이용하여 co-sputtering 방법으로 증착하였다. Indium molybdenum oxide 박막은 일정한 Mo 도핑농도와 일정한 Ar 개스 분압에서 다양한 기판온도 변화를 통해 증착하였다. 제작된 Indium molybdenum oxide 박막은 Hall Effect Measurement, Ultraviolet-Visible spectroscopy 및 X-Ray Diffraction (XRD) 등을 분석해 기판의 온도변화에 따른 전기비저항 및 광 투과도의 특성변화를 조사하였다.

• Asian-Australasian Journal of Animal Sciences
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• v.15 no.4
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• pp.509-515
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• 2002

Copper deficiency was induced in eight male buffalo calves by adding molybdenum (30 ppm wet basis) to their diet. Copper status was monitored from the liver copper concentration and a level below 30 ppm (DM basis) was considered as deficient. Haemoglobin, haematocrit, total and differential leucocyte numbers were determined. The functions of peripheral neutrophils were assessed by in vitro phagocytosis and killing of Staphylococcus aureus. The effect of molybdenum induced copper deficiency on bone marrow was monitored. The mean total leucocyte count was unaffected whereas a significant fall in neutrophil count coincided with the fall in hepatic copper level to $23.9{\pm}2.69$ ppm. Reduced blood neutrophil numbers was not accompanied by any change in the proportion of different neutrophil precursor cells in bone marrow. It was hypothesised that buffalo calves were more tolerant to dietary molybdenum excess than cattle. It was concluded that neutropenia in molybdenum induced copper deficiency occurred without any effect on their synthesis and maturation process. Bone marrow studies in healthy calves revealed higher percentage of neutrophilic myelocytes and metamyelocytes as compared to cattle.

• Journal of Welding and Joining
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• v.32 no.5
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• pp.65-71
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• 2014

Atmospheric plasma spraying (APS) is world-widely used process in the automotive industry as a method to provide wear resistance coatings for engine cylinder bore, using various materials. The weight of engine blocks can be considerably decreased by removing cast iron liners, which can finally result in the improvement of fuel efficiency. In this study, five kinds of powder materials, 1.2C steel powder and 1.2C steel powder mixed with 5, 10, 15, 20 wt.%. molybdenum powder, were deposited by atmospheric plasma spraying in order to investigate the effect of molybdenum on the wear resistance of coatings. Microstructural analysis showed that molybdenum splats were well distributed in 1.2C steel matrix with intimate bonding. The molybdenum added coatings showed better tribological properties than 1.2C steel coating. However, above the 15 wt.%. blending fraction, wear resistance was somewhat degraded with poor roughness of worn surface due to the brittle fracture occurred in molybdenum splats. Consequently, compared to conventional liner material, gray cast iron, 10 wt. pct. molybdenum blended 1.2C steel coating showed much better tribological properties and therefore it looks very feasible to replace gray cast iron liner.

• Resources Recycling
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• v.7 no.2
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• pp.9-15
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• 1998

Recovery af molybdenum in spent desulfuriring catalyst of petrochemical industries was studied from MfGnatc solulion which is a resultant of firstly remvercd vanadium by wet processes. In order to separate and recover molybdenum from upper mentioned rafinatz solution containing several mctal ions, such as molybdenum (1,100 ppm), vanadium (150 ppm), aluminium (19 ppm), and nickel (33 ppm), either adsorption technique by chelate resin or solvent extr~ction by tertiary amine as extractant was applied. In case of adsorption method, palyamine type chelate resin showed the highest selectivily far molybdenum ion up lo 60 ddm' of ancentration aftcr eluting with 3.0 rnolld~n' of NH,OH. On the othcr hand. molybdenum ion wa cffectlvely cxtractcd in Ule whole ranges of equilibrilrm pR by solvent extraction method with 10 ~01%-alamine 336 which was pretreated with 2N-HCI

• Journal of the Korean Applied Science and Technology
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• v.22 no.4
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• pp.349-354
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• 2005

It is interesting to discover the reaction kinetics of the newly developed molybdenum containing catalysts. The dissociation/adsorption of nitrogen on molybdenum surface is known to be structure sensitive, which is similar to that of nitrogen on iron surface. The rates over molybdenum nitride catalysts are increased with the increase of total pressure. This tendency is the same as that for iron catalyst, but is quite different from that for ruthenium catalyst. The activation energies of the molybdenum nitride catalysts are almost on the same level, although the activity is changed by the addition of the second component. The reaction rate is expressed as a function of the concentration of reactants and products. The surface nature of $CO_3Mo_3N$ is drastically changed by the addition of alkali, changing the main adsorbed species from $NH_2$ to NH on the surface. The strength of $NH_x$ adsorption is found to be changed by alkali dopping.