• 제목/요약/키워드: Molten carbonate

검색결과 229건 처리시간 0.041초

용융탄산염 연료전지용 공기극과 연료극의 저항 모델링 (Modelling of the Resistance Model for Anode and Cathode for Molten Carbonate Fuel Cells)

  • 이창환;정정열
    • 한국수소및신에너지학회논문집
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    • 제29권3호
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    • pp.267-273
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    • 2018
  • From the experiments of various temperature and gas compositions, total resistance which is composed of ohmic resistance, anode resistance, cathode resistance and Nernst loss was calculated wit simple assumption. In this work, the anode and the cathode resistance was modelled with new equation which can account for the correlation between the operating temperature and the gas composition. The proposed model can predict the resistance with maximum error of 2.57% and employed in the simulation of molten carbonate fuel cells.

임피던스법을 적용한 연료전지 성능규명 (Fuel Cell Performance by the Impedance Method)

  • 김귀열;서장수;박용필;이준응
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.157-159
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    • 2001
  • The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at 650$^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti alloys has been done in (62+38)mol% (Li+K)CO$_3$ melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for SOFC, by the way, Ni-YSZ materials are used as anode of SOFC widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a result, the performance of Ni-YSZ anode(47vo1%) was bettor excellent than the others.

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임피던스법을 이용한 연료전지의 특성 연구 (Fuel Cell Performance by the Impedance Method)

  • 서장수;김귀열;명기환;이성일;김용주
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.927-933
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    • 2000
  • The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at 650$^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti alloys has been done in (62+38)mol% (Li+K)CO3 melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for SOFC, by the way , Ni-YSZ materials are used as anode of SOFC widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a results, the performance of Ni-YSZ anode(40vo1%) was better excellent than the others.

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250kW급 MCFC용 전력변환기 개발 및 성능평가 (Performance Evaluation and Development of the Power Conditioning System for 250kW Molten Carbonate Fuel Cell)

  • 이진희;손의권;서인영
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2010년도 추계학술대회
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    • pp.261-262
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    • 2010
  • This paper presents the design, development and performance of a power conditioning system (PCS) for application to a Molten Carbonate Fuel Cell (MCFC) for high power generation system. The controller must also supervise the total PCS operation while communicating with the fuel cell system controller. A control method for parallel operation of 250kW PCS was implemented and verified respectively. Experimental performances are compared to minimum target requirements of the PCS for MCFC respectively.

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BaZr0.85-xPdxY0.15O3-δ/ Carbonates 복합전도체 전기적 특성 연구 (Study of Electrical Conductivity of BaZr0.85-xPdxY0.15O3-δ/ Carbonates Composite Materials)

  • 박가영;백승석;박준영
    • 한국세라믹학회지
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    • 제51권4호
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    • pp.283-288
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    • 2014
  • PdO-doped $BaZr_{0.85}Y_{0.15}O_{3-\delta}$ (BZPY) proton conductors have been proposed as applicable for intermediate temperature electrolytes for protonic ceramic fuel cells (PCFCs) because the PdO doping is effective for improving the proton conductivity of $BaZr_{0.85}Y_{0.15}O_{3-\delta}$ (BZY) with high affinity for hydrogen. In order to further improve the conductivity of BZPY, two-phase composite electrolytes consisting of a BZPY and molten carbonate were designed. Dense BZPY-based composite electrolytes were fabricated after sintering at $670^{\circ}C$ for 4 h, since molten carbonates fill the grain boundary of the porous BZPY matrix. Furthermore, BZPY/$(Li-0.5Na)_2CO_3$ composites show a significantly enhanced protonic conductivity at intermediate temperatures. This may be because easy proton transport is possible through the interface of the carbonate and oxide phase.