• Title/Summary/Keyword: Molten Lead

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Distribution Behavior of Bi and Pb Between Molten PbO-SiO2 Slag and Bi (용융(熔融) PbO-SiO2계(系) 슬래그와 Bi 사이의 Bi와 Pb의 분배거동(分配擧動))

  • Kim, Se-Jong;Kim, Eung-Jin;Sohn, Ho-Sang
    • Resources Recycling
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    • v.21 no.5
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    • pp.65-71
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    • 2012
  • The equilibrium distribution of bismuth and lead between molten PbO-$SiO_2$ slag and bismuth phase was studied in the temperature range of $775^{\circ}C$ to $850^{\circ}C$ in a MgO crucible. The oxygen partial pressure of atmosphere was controlled by $P_{CO2}/P_{CO}$ ratio. The value of $(%PbO)_{slag}/[%Pb]_{metal}$ increased with increasing $SiO_2$ content of slag, and the value of $(%Bi_2O_3)_{slag}/[%Bi]_{metal}$ decreased with increasing $SiO_2$ content of slag. The concentration of Pb in metal increased with increasing temperature. These experimental results agreed well with the thermodynamic prediction.

Study on the solution for the overflow of molten solder during the soldering of fuse cap through CFD analysis (전산유체해석을 통한 퓨즈캡 솔더링 시의 용융솔더 넘침 문제 해결방안 연구)

  • Jeong, Nam-Gyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.10
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    • pp.31-36
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    • 2018
  • Fuses are used to protect electric circuits or devices from excess current. Glass-tube fuses are typically used, but problems have arisen due to the mandated switch from conventional solder to lead-free solder. This study used CFD to simulate the phenomenon of molten solder being poured out of a fuse during the soldering process for a fuse cap and fuse element. In addition, a method is proposed to prevent solder from overflowing, and its effectiveness was verified based on the analysis results. The results show that a sufficient increase of the temperature inside the glass tube before soldering and gravity can help to prevent the solder from overflowing.

Preparation of $Pb(Sc_{1/2}Nb_{1/2})O_3$ powders by the molten salt synthesis method (용융염 합성법에 의한 $Pb(Sc_{1/2}Nb_{1/2})O_3$ 분말의 제조)

  • 박경봉
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.3
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    • pp.400-405
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    • 1997
  • Lead scandium niobate powders were prepared by a molten salt synthesis method using KCl as a flux. Variations in phase formation and particle morphology were investigated for the temperature range $700^{\circ}C$ to $850^{\circ}C$. Pure $Pb(Sc_{1/2}Nb_{1/2})O_3$ perovskite phase was formed at $850^{\circ}C$ after 2hrs and the average particle size of powder was below 0.5 $\mu\textrm{m}$. The results are discussed with respect to DTA, X-ray diffraction, and microstructural characterization data.

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Interaction of Laser Beam with PZT - Target and Observation of Laser - Induced Plume and Particle Ejection (Laser와 PZT - Target간의 반응과 그에 따른 Plume 형성 및 입자 방출에 관한 연구)

  • Lee, Byeong-U
    • Journal of Advanced Marine Engineering and Technology
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    • v.20 no.5
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    • pp.93-102
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    • 1996
  • Laser-induced plume and laser-target interaction during pulsed laser deposition are demonstrated for a lead zirconate titanate (PZT). A KrF excimer laser (wavelength 248nm) was used and the laser was pulsed at 20Hz, with nominal pulse width of 20ns. The laser fluence was~$16J/cm^2,$ with 100mJ per pulse. The laser-induced plasma plume for nanosecond laser irradiation on PZT target has been investigated by optical emission spectra using an optical multichannel analyzer(OMA) and by direct observation of the plume using an ICCD high speed photography. OMA analysis showed two distinct ionic species with different expansion velocities of fast or slow according to their ionization states. The ion velocity of the front surface of the developing plume was about $10^7$cm/sec and corresponding kinetic energy was about 100eV. ICCD photograph showed another kind of even slower moving particles ejected from the target. These particles considered expelled molten parts of the target. SEM morphologies of the laser irradiated targets showed drastic melting and material removal by the laser pulse, and also showed the evidence of the molten particle ejection. The physics of the plasma(plume) formation and particle ejection has been discussed.

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Effect of Anode Thickness on the Overpotential in a Molten Carbonate Fuel Cell (용융탄산염형 연료전지에서 과전압에 미치는 전극두께의 영향)

  • Lee, Choong-Gon;Lee, Sung-Yoon;Ryu, Bo-Hyun;Kim, Do-Hyung;Lim, Hee-Chun
    • Journal of the Korean Electrochemical Society
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    • v.13 no.1
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    • pp.34-39
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    • 2010
  • This work investigated the effect of anode thickness on the anodic overpotential with $100\;cm^2$ class MCFC single cells. The hydrogen oxidation rate in the molten carbonate is sufficiently high, which may lead to weak relation of overpotential with anode geometrical area. The relation of anode surface area and overpotential was analysed in terms of anode thickness in this work. Steady state polarization, inert gas step addition (ISA), and reactant gas addition (RA) methods were employed to the two cells with 0.77 mm and 0.36 mm thickness of anode. The result represented that the anodic overpotential at the cells were identical. It implied that the anodic overpotential was independent on the electrode thickness within the tested range.

Steam Explosion Experiments using ZrO$_2$ (ZrO$_2$를 이용한 증기폭발 실험)

  • Song, Jin-Ho;Kim, Hui-Dong;Hong, Seong-Wan;Park, Ik-Gyu;Sin, Yong-Seung;Min, Byeong-Tae;Kim, Jong-Hwan;Jang, Yeong-Jo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.12
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    • pp.1887-1897
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    • 2001
  • Korea Atomic Energy Research Institute (KAERI) launched an intermediate scale steam explosion experiment named "Test for Real Corium Interaction with water (TROI)" using reactor material to investigate whether the molten reactor material would lead to energetic steam explosion when interacted wish cold water at low pressure. The melt-water interaction experiment is performed in a pressure vessel with the multi-dimensional fuel and water pool geometry. The novel concept of cold crucible technology, where powder of the reactor material in a water-cooled cafe is heated by high frequency induction, is firstly implemented for the generation of molten fuel. In this paper, the lest facility and cold crucible technology are introduced and the results or the first series of tests were discussed. The 5 kg of molten ZrO$_2$jet was poured into the 67cm deep water pool at 30 ∼ 95 $\^{C}$. Either spontaneous steam explosions or quenching was observed. The morphology of debris and pressure wave profiles clearly indicate the differences between the two cases.

Study on Solidification and Strength of Soft Soils by Using Waste Magnesia-Carbon Powder (폐 Magnesia-Carbon Powder를 이용한 연약지반 고형화 및 강도 증진에 대한연구)

  • Choi, Hun;Song, Myong Shin;Kang, Hyung Ju;Jung, Eui Dam;Kim, Ju Seng
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.1
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    • pp.35-40
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    • 2011
  • Magnesia-carbon brick is used to refractory material in Converter and/or Ladle furnace for molten steel manufacturing. The rapid growth of steel making industry, molten steel industry is increased. Therefore, growth of molten steel industry lead to make waste magnesia-carbon brick by repair of Converter and/or Ladle furnace. These waste magnesia-carbon brick is abandoned all. Besides, as it is loosely composed of silt and clay including sand falling according to the type of gangue, rainwater inflows and outflows relatively easily, but silt or clay particles absorb water for a long period, weakening ground. This study tried to show that when colluvial soil is solidified using waste magnesia-carbon brick powder as a way to solidify strengthen the rigidity of colluvial soil.

An Examination of the Characteristics and Manufacturing Techniques of Joseon-era Metal Bullets (조선시대 금속제 탄환의 특징과 제작기법 검토)

  • Choi, Bo Bae;Lee, Hye Jin;Kim, Myung Hoon;Jeong, Hyeon Jin
    • Conservation Science in Museum
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    • v.28
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    • pp.65-88
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    • 2022
  • The characteristics and behavior of bullets are important because they are directly related to the firearm performance. However, research related to bullets have been small. In this paper, scientific analysis was conducted to find out the materials and manufacturing process of metal bullets during the Joseon Dynasty, owned by Korea Army Museum, and the types of firearms available were classified and organized according to the bullet diameter. As a result, bullets were classified into iron bullets, lead bullets, and lead-coated iron bullets. Most of the iron bullets and lead bullets were made from casting. Some iron bullets were made from forging. And the lead-coated iron bullet was made by pouring molten lead after putting the iron bullet into the mold. Finally, the bullets could be used for Hand Cannon, Matchlock Musket, Frankish Cannon, Hyeon-ja Cannon, Dae-Wiwon Cannon, Small Cannon, and Hong-Yi Cannon.

Thermodynamic interaction parameter between Zn and Cu, Ag, In, Bi, Pb, Sn in Dilute cadmium alloy by Touch Instant electro-motive force method (순간접전기전력법에 의한 용융 Cd중의 Zn과 Cu, Ag, In, Bi, Pb 및 Sn와의 상위작용 파라미터)

  • 김대룡;윤겸하
    • Journal of the Korean institute of surface engineering
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    • v.15 no.4
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    • pp.192-207
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    • 1982
  • A study has been made of the interaction parameters of Zn other elements in dilute solutesd solution of molten cadmium alloys over the temperature range of 450 to 570$^{\circ}C$. The experi-mental measurementss were made in a touch instant cell using a fusedd Licl-KCl electrolyte. The activity of zinc in binary and ternary solutions sexhibiteds a strong positive deviation from Raoult's law. The addition of silver, indium or lead increased the activity of zinc whereas addition of copper, bismuth or tin decreased the zinc activity slightly. The results for all the metallic solutions showed a linear dependence of reciprocal of ab-solute temperature over the experimental range. The interaction parameters obtained are as follows.

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CORIUM COOLABILITY UNDER EX-VESSEL ACCIDENT CONDITIONS FOR LWRs

  • Farmer, Mitchell T.;Kilsdonk, Dennis J.;Aeschlimann, Robert W.
    • Nuclear Engineering and Technology
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    • v.41 no.5
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    • pp.575-602
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    • 2009
  • In the wake of the Three Mile Island accident, vigorous research efforts were initiated to acquire a basic knowledge of the progression and consequences of accidents that involve a substantial degree of core degradation and melting. The primary emphasis of this research was placed on containment integrity, with: i) hydrogen combustion-detonation, ii) steam explosion, iii) direct containment heating (DCH), and iv) melt attack on the BWR Mark-I containment shell identified as energetic processes that could lead to early containment failure (i.e., within the first 24 hours of the accident). Should the core melt fail the reactor vessel, then non-condensable gas production from Molten Core-Concrete Interaction (MCCI) was identified as a mechanism that could fail the containment by pressurization over the long term. One signification question that arose as part of this investigation was the effectiveness of water in terminating an MCCI by flooding the interacting masses from above, thereby quenching the molten core debris and rendering it permanently coolable. Successful quenching of the core melt would prevent basemat melt through, as well as continued containment pressurization by non-condensable gas production, and so the accident progression would be successfully terminated without release of radioactivity to the environment. Based on these potential merits, ex-vessel corium coolability has been the focus of extensive research over the last 20 years as a potential accident management strategy for current plants. In addition, outcomes from this research have impacted the accident management strategies for the Gen III+LWR plant designs that are currently being deployed around the world. This paper provides: i) an historical overview of corium coolability research, ii) summarizes the current status of research in this area, and iii) highlights trends in severe accident management strategies that have evolved based on the findings from this work.