• Title/Summary/Keyword: Molecular Flow

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Effects of Surface Roughness and Interface Wettability in a Nanochannel (나노 채널에서의 표면 거칠기와 경계 습윤의 효과)

  • Choo, Yun-Sik;Seo, In-Soo;Lee, Sang-Hwan
    • The KSFM Journal of Fluid Machinery
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    • v.13 no.2
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    • pp.5-11
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    • 2010
  • The nanofluidics is characterized by a large surface-to-volume ratio, so that the surface properties strongly affect the flow resistance. We present here the results showing that the effect of wetting properties and the surface roughness may considerably reduce the friction of fluid past the boundaries. For a simple fluid flowing over hydrophilic and hydrophobic surfaces, the influences of surface roughness are investigated by the nonequilibrium molecular dynamics (NEMD) simulations. The fluid slip at near a solid surface highly depends on the wall-fluid interaction. For hydrophobic surfaces, apparent fluid slips are observed on smooth and rough surfaces. The solid wall is modeled as a rough atomic sinusoidal wall. The effects on the boundary condition of the roughness characteristics are given by the period and amplitude of the sinusoidal wall. It was found that the slip velocity for wetting conditions at interface decreases with increasing effects of surface roughness. The results show the surface rougheness and wettability determines the slip or no-slip boundary conditions. The surface roughness geometry shows significant effects on the boundary conditions at the interface.

Different Susceptibilities to Low Temperature Photoinhibition in the Photosynthetic Apparatus Among three Cultivars of Cucumber (Cucumis sativus L.)

  • Oh, Kwang-Hoon;Lee, Woo-Sung;Lee, Choon-Hwan
    • Journal of Photoscience
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    • v.8 no.3_4
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    • pp.105-112
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    • 2001
  • Susceptibility to low temperature photoinhibition in photosynthetic apparatus was compared among three cucumber cultivars, Gahachungjang (GH), Banbaekjijeo (BB) and Gaeryangsymji (GR). By chilling in the light for 6 h, a sustained decrease in the potential quantum yield (Fv/Fm) and the oxidizable P700 contents was observed, and the decrease was less in GH than in BB and GR. Although the difference was small, some $\Phi_{PSII}$ remained in GH after light-chilling for 6 h indicating that a few electrons can flow around photosystem II(PSII). As a consequence, the primary electron acceptor of PSII, $Q_{A}$, was reduced slowly and was not fully reduced after light-chilling for 6 h in GH. Although the amplitude was small, the development of NPQ was also faster in GH, indicating a higher capacity for non-photochemical energy dissipation. The relative fraction of a fast relaxing component of NPQ (qf) was higher in GH. After light-chilling for 5 h, the values of qf in BB and GR became much smaller than that in GH, indicating BB and GR suffered more significant uncoupling of ATPase and/or irreversible damages in PSII. When fluorescence induction transients were recorded after chilling, significant differences in quenching coefficients (qQ and qN) were observed among the three cultivars.

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Multivariable Nonlinear Model Predictive Control of a Continuous Styrene Polymerization Reactor

  • Na, Sang-Seop;Rhee, Hyun-Ku
    • 제어로봇시스템학회:학술대회논문집
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    • 1999.10a
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    • pp.45-48
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    • 1999
  • Model predictive control algorithm requires a relevant model of the system to be controlled. Unfortunately, the first principle model describing a polymerization reaction system has a large number of parameters to be estimated. Thus there is a need for the identification and control of a polymerization reactor system by using available input-output data. In this work, the polynomial auto-regressive moving average (ARMA) models are employed as the input-output model and combined into the nonlinear model predictive control algorithm based on the successive linearization method. Simulations are conducted to identify the continuous styrene polymerization reactor system. The input variables are the jacket inlet temperature and the feed flow rate whereas the output variables are the monomer conversion and the weight-average molecular weight. The polynomial ARMA models obtained by the system identification are used to control the monomer conversion and the weight-average molecular weight in a continuous styrene polymerization reactor It is demonstrated that the nonlinear model predictive controller based on the polynomial ARMA model tracks the step changes in the setpoint satisfactorily. In conclusion, the polynomial ARMA model is proven effective in controlling the continuous styrene polymerization reactor.

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Optimization Study on the Open-Loop Rankine Cycle for Cold Heat Power Generation Using Liquefied Natural Gas (액화천연가스를 활용한 개방형 랭킨 사이클에 적용한 냉열 발전의 최적화에 대한 연구)

  • KIM, YOUNGWOO;LEE, JOONGSUNG;LEE, JONGJIP;KIM, DONG SUN;CHO, JUNGHO
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.3
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    • pp.295-299
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    • 2017
  • In this study, computer simulation and optimization works have been performed for an open-loop Rankine cycle to generate power using five cases of liquefied natural gas compositions. PRO/II with PROVISION V9.4 from Schneider electric company was used, and the Soave-Redlich-Kwong equation of the state model was utilized for the design of the power generation cycle. It was concluded that more power was obtained from less molecular weight liquefied natural gas since there was more volumetric flow rate with less molecular weight.

miR-181b as a Potential Molecular Target for Anticancer Therapy of Gastric Neoplasms

  • Guo, Jian-Xin;Tao, Qing-Song;Lou, Peng-Rong;Chen, Xiao-Chun;Chen, Jun;Yuan, Guang-Bo
    • Asian Pacific Journal of Cancer Prevention
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    • v.13 no.5
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    • pp.2263-2267
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    • 2012
  • Objective: MicroRNAs (miRNAs) play important roles in carcinogenesis. The aim of the present study was to explore the effects of miR-181b on gastric cancer. Methods: The expression level of miR-181b was quantified by qRT-PCR. MTT, flow cytometry and matrigel invasion assays were used to test proliferation, apoptosis and invasion of miR-181b stable transfected gastric cancer cells. Results: miR-181b was aberrantly overexpressed in gastric cancer cells and primary gastric cancer tissues. Further experiments demonstrated inducible expression of miR-181b by Helicobacter pylori treatment. Cell proliferation, migration and invasion in the gastric cancer cells were significantly increased after miR-181b transfection and apoptotic cells were also increased. Furthermore, overexpression of miR-181b downregulated the protein level of tissue inhibitor of metalloproteinase 3 (TIMP3). Conclusion: The upregulation of miR-181b may play an important role in the progress of gastric cancer and miR-181b maybe a potential molecular target for anticancer therapeutics of gastric cancer.

Identification of troglitazone responsive genes: induction of RTP801 during troglitazone-induced apoptosis in Hep 3B cells

  • Kim, Jin-Oh;Kim, Ji-Young;Kwack, Mi-Hee;Hong, Su-Hyung;Kim, Moon-Kyu;Kim, Jung-Chul;Sung, Young-Kwan
    • BMB Reports
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    • v.43 no.9
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    • pp.599-603
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    • 2010
  • Troglitazone is an anti-diabetic agent that improves hyperglycemia by reducing peripheral insulin resistance in type II diabetic patients. Troglitazone has been shown to cause growth inhibition of various normal and cancerous cells. However, the molecular mechanism by which troglitazone affects the growth of these cancer cells remains unclear. Here, we report that troglitazone treatment of Hep 3B human hepatocellular carcinoma cells resulted in dose-dependent growth inhibition. Analysis of cell cycle distribution by flow cytometry showed that the number of apoptotic cells was increased in a dose-dependent manner in response to troglitazone treatment. cDNA microarray analysis showed a number of differentially expressed genes in response to troglitazone. Among the upregulated genes, hypoxia-inducible factor 1 (HIF-1)-responsive RTP801 was induced in a dose-dependent manner. We also observed HIF-1 accumulation by immnocytochemistry after troglitazone treatment. These results strongly suggest that RTP801 might be involved in troglitazone-induced apoptosis in Hep 3B cells.

Molecular Diffusion of Water in Paper(II)-Water-diffusion theory on pore structure of paper- (종이내 수분확산(제2보)-종이의 공극구조에 의한 수분확산 이론-)

  • Yoon, Sung-Hoon;Jeon, Yang
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.3
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    • pp.46-56
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    • 1998
  • The objective of this study was to investigate the relationship between water vapor diffusion properties and the pore structure of paper. Gas-phase molecular diffusivity of water vapor through pores was determined based on the kinetic theory of gas. A mathematical model was derived to characterize the dimensional changes of the pore caused by the fiber-swelling mechanism. A modified-Fickean diffusion model was designed to simulate the water-vapor diffusion phenomena in porous paper web. Structural characterisocs of paper pores including the tortuosity and the shape factor was studied on a theoretical basis of Knudsen flow diffusion. Results are summarized as follows: 1. The theoretical water vapor diffusivity in gas-phase was 0.092$cm^2$ /min, 2. Porosity was inversely proportional to the degree of wet-swelling of paper, 3. Solid-phase water-diffusivity of fiber was 1.2 $ \times 10^{-5}cm^2/min$, 4. Modified diffusion model was fairly consistent to the experimental data (from part I), and 5. The Fickean pore tortuosity, ranging from 1,000 to 2,500, was in inverse proportion to the porosity of paper, and the Knudsen shape factor and length-angle factor for micro-pores in paper were 0.5~3.5 and about 340, respectively.

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Heteroepitaxial Structure of ZnO Films Deposited on Graphene, $SiO_2$ and Si Substrates

  • Pak, Sang-Woo;Cho, Seong-Gook;Kim, Eun-Kyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.309-309
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    • 2012
  • Heteroepitaxial growth remains as one of the continuously growing interests, because the heterogeneous crystallization on different substrates is a common feature in the fabrication processes of many semiconductor materials and devices, such as molecular beam epitaxy, pulsed laser deposition, sputtering, chemical bath deposition, chemical vapor deposition, hydrothermal synthesis, vapor phase transport and so on [1,2]. By using the R.F. sputtering system, ZnO thin films were deposited on graphene 4 and 6 mono layers, which is grown on 400 nm and 600 nm $SiO_2$ substrates, respectively. The ZnO thin layer was deposited at various temperatures by using a ZnO target. In this experimental, the working power and pressure were $3{\times}10^{-3}$ Torr and 50 W, respectively. The base pressure of the chamber was kept at a pressure around $10^{-6}$ Torr by using a turbo molecular pump. The oxygen and argon gas flows were controlled around 5 and 10 sccm by using a mass flow controller system, respectively. The structural properties of the samples were analyzed by XRD measurement. The film surface and carrier concentration were analyzed by an atomic force microscope and Hall measurement system. The surface morphologies were observed using field emission scanning electron microscope (FE-SEM).

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pH Effect on Relaxation Spectra of Poly(methyl acrylate)-Poly(acrylonitrile) Copolymers by REM Model (REM 모델에 의한 Poly(methyl acrylate)-Poly(acrylonitrile) 공중합체 완화스펙트럼의 pH 영향)

  • Kim, Nam Jeong
    • Polymer(Korea)
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    • v.37 no.2
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    • pp.135-140
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    • 2013
  • The stress relaxation of poly(methyl acrylate)-poly(acrylonitrile) copolymer samples was carried out in air, distilled water, pH 3, 7 and 11 solutions at various temperatures using a tensile tester equipped with a solvent chamber. The relaxation spectra of poly(methyl acrylate)-poly(acrylonitrile) copolymers were obtained by applying the experimental stress relaxation curves to the equation of relaxation spectrum derived from the Ree-Eyring and Maxwell model. The determination of relaxation spectra was performed from computer calculation using a Laplace transform method. It was observed that the relaxation spectra of these samples are directly related to the distribution of molecular weights and self-diffusions of flow segments.

Influence of Dilauroyl Peroxide on Mechanical and Thermal Properties of Different Polypropylene Matrices (Dilauroyl Peroxide의 PP에 대한 기계적, 열적 성질 변화)

  • Sirin, Kamil;Yavuz, Mesut;Canli, Murat
    • Polymer(Korea)
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    • v.39 no.2
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    • pp.200-209
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    • 2015
  • In this study, the influence of dilauroyl peroxide on mechanical and thermal properties of different polypropylene (PP) matrices was investigated. Polypropylene matrices, different molecular weight isotactic PP containing 0.01, 0.02, 0.04, 0.06, 0.08, and 0.1 wt% of dilauroyl peroxide (DLP) were prepared by using a single-screw extruder. The effect of the visbreaking agent (DLP) on mechanical, physical, thermal and morphological properties of different molecular weight PP had been studied. Mechanical properties (tensile strength at break point, at yield and elongation at break point), melt flow index (MFI), scanning electron microscope (SEM) and differential scanning calorimetric (DSC) analyses of these matrices were examined. Melting ($T_m$) and crystallization ($T_c$) temperatures, crystallinity ratio (%) and enthalpies were determined. The microstructure of isotactic polypropylene matrix was investigated by scanning electron microscopy (SEM). From SEM analysis, it was observed that the surface disorder increased by the increasing amount of DLP. As a result of DSC analyses, the crystallinity ratio of the PP matrices has varied between 1.64-7.27%. Mechanical properties of the matrices have been improved. Particularly, the mechanical tests of PP have given interesting results when compounded with 0.06-0.08 wt% dilauroyl peroxide (DLP). Mechanical properties and thermal decomposition processes were all changed by increasing the amount of DLP in the matrix structure.