• 제목/요약/키워드: Mole Fraction

검색결과 403건 처리시간 0.025초

Ge mole fraction에 따른 SGOI MOSFET의 아날로그 특성 (Analog performances of SGOI MOSFET with Ge mole fraction)

  • 이재기;김진영;조원주;박종태
    • 대한전자공학회논문지SD
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    • 제48권5호
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    • pp.12-17
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    • 2011
  • 본 연구에서는 $Si_xGe_{1-x}$ 버퍼층 위에 성장된 strained-Si에 Ge 농도에 따라 n-MOSFET를 제작하고 소자 제작 후의 열처리 온도에 따른 소자의 아날로그 성능을 측정 분석하였다. 전자의 유효 이동도는 Ge 농도가 증가함에 따라 증가하였으나 32%로 높을 때에는 열처리 온도에 상관없이 오히려 감소하는 것으로 측정되었다. 상온에서 Ge 농도가 증가함에 따라 증가 소자의 아날로그 성능 지수가 우수하였으나 32% 농도에서는 오히려 좋지 않았다. 고온에서 strained-Si의 전자 유효이동도 저하가 Si보다 심하기 때문 SGOI 소자의 아날로그 성능 저하가 SOI 소자보다 심한 것을 알 수 있었다.

치즈 및 된장에서의 쓴 맛 펩타이드 특성 (Characteristics of Bitter Peptides from a Cheese and a Soybean Paste)

  • 김수호;이형주
    • 한국식품과학회지
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    • 제17권4호
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    • pp.276-282
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    • 1985
  • 단백발효식품에서의 쓴맛 펩타이드의 특성을 규명하기 위하여 여러 시료로부터 소수성 펩타이드를 2 1(v/v) chloroform-methanol로 추출하였다 이 중 모짜렐라치즈와 된장으로부터 얻은 쓴맛 텝타이드 추출물을 다시 Sephadex C-25 겔 크로마토그라피한 결과 분획 I II, III을 얻었는데 이들 시료 자체와 각각의 크로마토그라피 분획을 구성하고 있는 펩타이드의 아미노산 조성을 분석하여 평균소수도를 계산하였다. 시료들 자체는 쓴 맛을 나타내지 않았으나 용매로 추출된 소수성 펩타이드 분획은 강한 쓴 맛을 나타내었다. 시료의 용매추출 수율은 총 질소 함량의 0.08내지 62.50%의 범위로 나타났다. 모짜렐라치즈 질소물의 평균 소수도는 1.376cal/mole, 용매추출 분획은 1.623cal/mole. 젤 크로마토그라피 분획 I은 1,797cal/mole, 분적 II 는 2,454cal/mole, 분획 III은 1,559cal/mole 이었다. 된장의 경우 된장 자체, 용매추출 분획, 겔 크로마토그라피 분획 I, II, III의 평균소수도는 각각 1,229. 1,654, 1900, 2016, 998cal/mole 이었다. 쓴맛 펩타이드에서 중요한 아미노산을 leucine, Phenylal anine. p-roline, valine으로 나타났다.

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Pb(Ni1/3Nb2/3)O3-PbTiO3-PbZrO3계의 유전 및 압전특성 (Dielectric and Piezoelectric Properties of Pb(Ni1/3Nb2/3)O3-PbTiO3-PbZrO3 Solid Solution Ceramics)

  • 손정호;남효덕;조상희
    • 한국세라믹학회지
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    • 제25권5호
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    • pp.523-531
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    • 1988
  • The dielectric and piezoelectric properties with compositions in Pb(Ni1/3Nb2/3)O3-PbTiO3-PbZrO3-(PNN-PT-PZ)solid solution ceramics were investigated. In this study, the compsition ranges were 30 PNN 45mole%, 20 PT 50mole% and 50 PZ5mole%. As PT fraction were increased the grain size was increased and the fired density was decreased, but the changes of PNN fraction had no effect on the grain size. The Curie temperature was increased when PT and PNN fraction were increased. The displacement was increased but had a great hysteresis loss when PT fraction was increased. In morphotropic phase boundary, the maximum piezoelectric and electromechanical coupling factor were indicated. Morphotropic phase boundary(MPB) was 34 PT 36mole% in chang of compositions.

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YSZ 박막의 성장속도와 특성에 미치는 전기화학증착의 조건의 영향(II) (Influences of Electrochemical Vapor Deposition Conditions on Growth Rate ad Characteristics of YSZ Thin films(II))

  • 박동원;전치훈;김대룡
    • 한국세라믹학회지
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    • 제33권3호
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    • pp.355-361
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    • 1996
  • Yttria stabilized zirconia (YSZ) thin films were prepared by the electrochemical vapor deposition (EVD) method on the porous Al2O3 substrates. Y2O3 mol% of thin film was linearly increased with yttrium mole fraction of vapor phase. As yttrium mole fraction(Zyc13=0.18) increased dense and faceted thin films were enhanced. However as the yttrium mole fraction (Zyc13=0.04) decreased porous thin films with monoclinnic phase prevailed. With increasing pressure difference of substrate sides penetration depth decreased porosity and amount of monoclinic phase in the films increased.

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UV-Curable Fluorinated Crosslinkable Polyurethane-Acrylates for Marine Antifouling Coatings

  • Park, Jin-Myung;Kim, Sung Yeol;An, Seung-Kook;Lee, Young-Hee;Kim, Han-Do
    • 청정기술
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    • 제23권2호
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    • pp.148-157
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    • 2017
  • To prepare UV-curable polyurethane-acrylate oligomer, NCO-terminated urethane prepolymers with trimethylolpropane, [TMP; 0 (0), 0.1 (0.021) and 0.2 (0.043) mole (mole fraction)] as crosslinkable tri-functional chain extender were end-capped with pentaerythritol triacrylate [PETA; 2.0 (0.400), 1.7 (0.354) and 1.4 (0.304) mole (mole fraction)] with one hydroxyl group/three vinyl functionalities. The stable as-formulated UV-curable polyurethane-acrylates [stable mixtures of PETA-capped oligomer/reactive acrylic monomer diluents without/with heptadecafluorodecyl methacrylate (PFA; 0, 6 and 9 wt%)] were formed up to 0.2 (0.043) mole (mole fraction) of TMP content in the prepolymer, while homogeneous-mixing failed at 0.3 (0.068) mole (mole fraction), in which the crosslink density in NCO-terminated urethane prepolymer was too high to enable the formation of stable mixture. This study examined the effect of TMP/PETA molar ratio and heptadecafluorodecyl methacrylate (PFA) content (wt%) on the properties of UV-cured polyurethane-acrylates as marine antifouling coating materials. The properties of UV-cured polyurethane-acrylate were found to be significantly dependent on the crosslinkable TMP/PETA ratio and PFA content. With the increasing of the TMP and PFA contents, the contact angles increased, and consequently the surface tension decreased. The adhesion of algae/barnacles to PFA contained film samples were found to be sufficiently weak to allow their easy removal. These results suggest that the UV-cured samples containing PFA have strong potential as coating materials for antifouling applications.

Experimental Study of the Phase Equilibria for $CO_2$ in Liquified Natural Gas Components at 77-219K

  • Yun, Sang-Kook
    • International Journal of Air-Conditioning and Refrigeration
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    • 제11권2호
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    • pp.61-66
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    • 2003
  • In order to prevent roll-over and a rapid boil-off of LNG in tanks, the phase equilibria of carbon dioxide in liquefied natural gas components as binary mixtures at cryogenic temperatures have been experimentally measured using Fourier transform infrared spectroscopy in conjunction with a specially designed variable pressure/temperature cryostat cell (pathlength 2 mm; pressures up to 30 bar). Solid carbon dioxide has been found to be comparatively soluble in liquid nitrogen (3.25$\times$${10}^{-6}$ mole fraction), liquid methane (1.04$\times$${10}^{-4}$ mole fraction), liquid ethane (3.1$\times$${10}^{-2}$ mole fraction) and liquid propane (6.11$\times$${10}^{-2}$ mole fraction) at their normal boiling temperatures. The solubilities of carbon dioxide in various cryogens, which increased with increasing temperature, are much lower than those obtained by others using gas chromatography. The differences are attributed to infrared spectroscopy selectively measuring dissolved solute in situ whereas gas chromatography measures microscopic particulate solid in addition to dissolved solute.

층상형 혼합광물의 상호작용계수의 계산 및 응용 (Calculation of Interaction Parameters in Mixed Layer Minerals and their Application)

  • 이성근;김수진
    • 한국광물학회지
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    • 제10권2호
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    • pp.97-104
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    • 1997
  • Based on the method of determination for relative stability of each phase from the difference among the interaction parameters of the phases consisting the mixed layer, the types of interactions between layers were specified and interaction parameter between layers in ordered domain was analytically derived as a function parameter between layers in ordered domain was analytically derived as a function of not only temperature and mole fraction of layers but also ordering parameter. Interaction parameter between the different layers in ordered phase, L is as follows:{{{{ {L }_{1 } (X,Q,T)= { C} over { Q} -4(1-2Q) { L}^{2 } - { RT} over {2} ln { 1} over {2 } - { 2RT} over { { X}_{ s} } ln { { 4QX}`_{s } ^{2 } } over {(1- { X}_{s }- { QX}_{s })( { X}_{s }- {QX }_{s } ) } }}}}L2 is the interaction parameter between ordered and disordered phase in domain and is the mole fraction of the domain which represent the infinite length of mixed layer mineral and Q and C are the reaction progress parameter and arbitrary constant, respectively. This equation was used for the I/S mixed layer clay minerals to infer the relative stability of R1 type I/S mixed layer in the temperature range from 373K to 450K. The result of calculation suggest that, owing to the decrease in interaction parameter with increasing temperature. The interaction parameter decreases more rapidly with decreasing mole fraction of smectite in domain, which is consistent with the fact that the probability of finding the series smectite layer is lo in the domain with small mole fraction of smectite layers in natural system.

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바이오가스로부터 온실가스 메탄 회수를 위한 3단 분리막 공정 모사 (Simulation on Recovery of Methane Greenhouse Gas from Biogas Using 3 Stage Membrane Modules)

  • 이용택
    • 멤브레인
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    • 제28권4호
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    • pp.243-251
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    • 2018
  • 메탄은 중요한 온실가스 중의 하나이며, 바이오가스의 주 성분이다. 이러한 바이오가스로부터 메탄의 몰분율 농도를 0.95 이상으로 회수하기 위하여 폴리설폰 중공사 분리막 모듈을 3단으로 연결하여 회수율을 99% 이상으로 얻을 수 있도록 공정을 설계하고 전산 모사하였다. 수치 해석 시 이산화탄소 투과도와 선택도를 이산화탄소의 부분증기압 함수로 나타내어 전산 모사를 수행하여 정확도를 높이고자 하였다. 공급 기체 압력, 공급 기체 내 메탄 농도, 그리고 분리막 모듈 내 분리막 면적이 클수록, 생성물 내 메탄 몰분율 농도가 증가함을 알 수 있었다. 그러나 생성물 내 메탄 몰분율 농도를 0.95 이상, 동시에 메탄 회수율을 99% 이상 얻기 위해서는 분리막 모듈의 분리막 면적을 적절히 선택하여야 하며, 선정된 분리막 모듈을 다단 공정으로 구성함에도 불구하고 공급 기체 압력, 공급 기체 유속, 그리고 공급 기체 메탄 농도를 제한적 범위 내에서 조절하여야 함을 알 수 있었다.

ZnO Nanorods Grown on CdxZn1-xO Seed Layers with Various Cd Mole Fractions

  • Kim, Min-Su;Kim, Do-Yeob;Yim, Kwang-Gug;Kim, Soaram;Nam, Gi-Woong;Kim, Sung-O;Lee, Dong-Yul;Leem, Jae-Young
    • Bulletin of the Korean Chemical Society
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    • 제33권1호
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    • pp.189-193
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    • 2012
  • ZnO nanorods were grown on the $Cd_xZn_{1-x}O$ seed layers with various Cd mole fractions by hydrothermal method. The effects of the Cd mole fraction for $Cd_xZn_{1-x}O$ seed layers on the structural and optical properties of the ZnO nanorods were investigated by scanning electron microscopy, X-ray diffraction, and photoluminescence. The narrowest full-width at half-maximum and largest grain size of the $Cd_xZn_{1-x}O$ seed layers, indicating improvement in crystal quality, were observed at the Cd mole fraction of 0.5. At the Cd mole fraction of 0.5, the largest enhancement in the density, the crystal quality, and the growth rate of the ZnO nanorods was observed while their appearance was not affected significantly by the incorporation of the Cd in the $Cd_xZn_{1-x}O$ seed layers. Consequently, the luminescent properties of the ZnO nanorods were enhanced. The largest improvement in the structural and optical properties of the ZnO nanorods was observed at the Cd mole fraction of 0.5.

Self-Consistent Subband Calculations of AlGaN/GaN Single Heterojunctions

  • Lee, Kyu-Seok;Yoon, Doo-Hyeb;Bae, Sung-Bum;Park, Mi-Ran;Kim, Gil-Ho
    • ETRI Journal
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    • 제24권4호
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    • pp.270-279
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    • 2002
  • We present a self-consistent numerical method for calculating the conduction-band profile and subband structure of AlGaN/GaN single heterojunctions. The subband calculations take into account the piezoelectric and spontaneous polarization effect and the Hartree and exchange-correlation interaction. We calculate the dependence of electron sheet concentration and subband energies on various structural parameters, such as the width and Al mole fraction of AlGaN, the density of donor impurities in AlGaN, and the density of acceptor impurities in GaN, as well as the electron temperature. The electron sheet concentration was sensitively dependent on the Al mole fraction and width of the AlGaN layer and the doping density of donor impurities in the AlGaN. The calculated results of electron sheet concentration as a function of the Al mole fraction are in excellent agreement with some experimental data available in the literature.

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