• Title/Summary/Keyword: Modified soil

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A Study about Development of Hydrogen Peroxide Stabilizer in Modified Fenton Reaction Using Anion Surfactant (음이온 계면활성제를 사용한 modified Fenton 반응의 과수안정제 개발에 관한 연구)

  • Kim, Han Ki;Park, Kang Su;Kim, Jeong Hwan;Park, Joo Yang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.4B
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    • pp.377-382
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    • 2011
  • In this study, hydrogen peroxide is stabilized in modified Fenton reaction to improve the soil remediation. Phenanthrene, which is the typical compound in PAHs, was spiked into soil samples to copy the original contaminated site. Anionic surfactant, SDS (Sodium dodecyl sulfate) was used for hydrogen peroxide stabilizer. 4 mM of Fe(II), 5~50 mM of SDS and 102.897 mM of $H_2O_2$ was injected into soil samples which is contaminated by 125 mg/kg of phenanthrene to analyze decomposition rate of phenanthrene in modified Fenton reaction. In condition which SDS was injected 30 mM, decomposition rate of phenanthrene has best efficiency as 95% and in condition which SDS was injected over 30 mM, decomposition rate is lower than SDS 30 mM because SDS enacted as scavenger in the system. Results which assess the change of hydrogen peroxide concentration after injecting hydrogen peroxide stabilizer showed that hydrogen peroxide concentration was 14.6995 mM so that is stabilized at Fe(II) 2 mM condition in 48 hours. On the other hand, hydrogen peroxide is not stable in Fe(III) condition. SDS concentration was fixed and iron concentration was changed 2~8 mM to find out optimize proportion between iron concentration and SDS concentration in modified Fenton reaction. Consequentially, in condition of which Fe(II) 4 mM and SDS 30 mM, reaction has the highest removal rate as 95%.

Characteristics of Shear Strength for an Unsaturated Soil with the Matric Suction (흡인력에 따른 불포화토의 전단강도 특성)

  • Song, Chang-Seob;Choi, Dook-Ho
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.10 no.1
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    • pp.82-90
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    • 2007
  • In order to analyse the strength problems for an unsaturated soil, it is required to examine closely the characteristics of the parameters of shear strength which was changed with the metric suction and void ratio. To this ends, a triaxial compression test was conducted on the three samples-granular soil, cohesive soil and silty soil. The specimen was made by pressing the static pressure on the mold filled soil and was controled the void ratio with the different compaction ratio. And the test was performed by using the modified apparatus of the triaxial compression tester. The range of matric suction was 0-90 kPa.The measured results for the deviator stress and parameters of shear strength were analysed with the void ratio and the compaction ratio, and they were examined closely the characteristics of the strength for an unsaturated soil.

Desorption Characteristics of Volatile Organics Compounds in Soil by Microwave Heating (마이크로파 가열에 의한 토양 유기오염물질 탈착특성)

  • 문경환;김덕찬
    • Journal of environmental and Sanitary engineering
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    • v.11 no.2
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    • pp.65-73
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    • 1996
  • The objective of this study is to investigate the removal efficiency of volitile organic compounds in soil, and the mechanism of desorption by bench scale microwave heating, Silt soil used for experiment and was impregnated with toluene, tetrachloroethylene, o-xylene and p-dichlorobenzene and the microwave treatment was conducted in a modified domestic microwave oven : 2450MHz, 700W. According to the results of the research the removal efficiency was improved with increasing water contents and the soil temperature appeared to plateau period extending to 2-3minutes corresponds to the temperature a which steam distillation was expected. The value of removal rate constant (k) were calculated on dry and moisty silt soil, respectively, which showed linear with increasing microwave heating time. Therefore, addition of a certain amount of water to the contaminated soil can efficiently enhance the ability of the soil to absorb microwave energy and promote the evaporation of the volitile contaminants.

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Irrigation Scheduling with Soil Moisture Simulation Model (토양수분이동모형을 이용한 관개계획)

  • 최진용;정하우
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.38 no.1
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    • pp.98-106
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    • 1996
  • An irrigation scheduling model, IRIS developed to evaluate irrigation demand and irrigation time for upland crops. For IRlS modeling the soil moisture simulation model, SWATRER was adopted and modified. The developed model, IRIS operated under 5 different soil moisture level that is 20%, 40%, 60%, 80% of available soil moisture and optimum soil moisture level, OSML, which is different about the growing stage and no rainfall condition during growing period. As a result for IRIS simulation, irrigation demand for 5 different soil moisture level was 332.3, 409.8, 569.3, 732.2, 539.3mm, irrigation number was 5, 8, 18, 54, 16 times and irrigation interval during peak time of consumptive use was 20, 13, 6, 2, 6 days respectively. It is appeared that the higher soil moisture level the more irrigation demand and irrigation number and the higher soil moisture level the less irrigation interval.

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Characteristics of Permeability for an Unsaturated Soil (불포화토의 투수특성)

  • Song, Chang-Seob;Shin, Chang-Seob
    • Journal of The Korean Society of Agricultural Engineers
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    • v.47 no.4
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    • pp.35-41
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    • 2005
  • In order to analyse the flow problems for an unsaturated soil, it is required to examine closely the characteristics of the coefficient of permeability which is changing with the matric suction. To this ends, a permeability test was conducted on the three samples;granular soil, cohesive soil and silty soil. The specimen was made by pressing the static pressure on the mold filled with soil and the void ratio was controled with the different compaction ratio. And the test was performed by using the modified apparatus of the steady state method which was proposed by flute (1972). The range of matric suction was 0-90 kPa. The measured results for the coefficients of permeability were analysed with the void ratio and the compaction ratio, and it was examined closely the characteristics of the permeability for an unsaturated soil.

Interface shear between different oil-contaminated sand and construction materials

  • Mohammadi, Amirhossein;Ebadi, Taghi;Boroomand, Mohammad Reza
    • Geomechanics and Engineering
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    • v.20 no.4
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    • pp.299-312
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    • 2020
  • The aim of this paper was to investigating the effects of soil relative density, construction materials roughness, oil type (gasoil, crude oil, and used motor oil), and oil content on the internal and interface shear behavior of sand with different construction materials by means of a modified large direct shear test apparatus. Tests conducted on the soil-soil (S-S), soil-rough concrete (S-RC), soil-smooth concrete (S-SC), and soil-steel (S-ST) interfaces and results showed that the shear strength of S-S interface is always higher than the soil-material interfaces. Internal and interface friction angles of sand beds increased by increase in relative density and decreased by increasing oil content. The oil properties (especially viscosity) played a major role in interface friction behavior. Despite the friction angles of contaminated sands with viscous fluids drastically decreased, it compensated by the apparent cohesion and adhesion developed between the soil grains and construction materials.

Development of Equation of the Soil-Water Characteristic Curve for an Unsaturated Soil (불포화의 흙-수분 특성곡선 방정식의 개발)

  • Song, Chang-Seob;Lim, Seong-Yoon;Kim, Myung-Hwan
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2003.10a
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    • pp.191-194
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    • 2003
  • The purpose of this paper was to derive soil-water characteristic curve equation for unsaturated soil. To this end, a series of suction measured test was conducted on the selected 4 kinds of soil which is located in Korea, used the modified pressure plate apparatus. From the test results, it was proved that characteristic curve changes according to grain size distribution, size of void and fine grained soil contents. Residual degree of saturation(Sr) was decreased with void ratio and changed with fine grained soil contents, parameter ${\lambda}$ and hr was increased with void ratio. Soil-water characteristic curve equation based on the test result was suggested by void ratio or grain size distribution.

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Microwave Remediation of Soils Contaminated by Volatile Organic Chemicals (마이크로파에 의한 휘발성 유기토양오염물질 제거에 관한 연구)

  • 문경환;김우현;이병철;김덕찬
    • Journal of Environmental Health Sciences
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    • v.22 no.3
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    • pp.116-122
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    • 1996
  • This study has been focused on the applicability of microwave treatment of soil contaminated by volitile organic chemicals. Substrates studied were sand and sandy soil. These substrates were impregnated with toluene, tetrachloroethylene, o-xylene and p-dichlorobenzene. The microwave treatment was conducted in a modified domestic microwave oven: 2450 MHz, 700 W. The sandy soil temperature added water went up rapidly to about 130$\circ$C for 4 minutes. And then, the temperature appeared to plateau out. A series of tests were performed to depict the effectiveness of microwave treatment technique to organic contaminants from soils. Removal efficiencies in sandy soil and sand were increased with increasing water content and exposure time. Microwave radiation penetrates the soil and heats water throughout the matrix. Therefore, addition of a certain amount of water to the contaminated soil can efficiently enhance the ability of the soil to absorb microwave energy and promote the evaporation of the volitile contaminants. And the vapour pressure of impregnated organic contaminants becomes lower. the removal efficiency becomes poor.

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Enhancement of the Technique for Analyzing a Pile Driven by Vibro Hammer (진동해머에 의해 시공되는 말뚝의 해석기법 제고)

  • Lee, Seung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.5
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    • pp.3596-3601
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    • 2015
  • Enhancement of the existing program for analyzing a pile driven by vibro hammer was tried. Damping effect of dynamic soil resistance and clutch friction were added to the existing governing equation which constitute vibrating system of vibro hammer-pile-soil. Parameters of the modified Ramberg-Osgood model which simulates dynamic load transfer curves for the developed program were recomputed. Comparing the results of the modified program with those of the field tests, pile displacement with time and load transfer behavior were more similar to those of the field test. The penetration rates obtained from the modified program were more close to those of the field test rather than those of the commertical program.