• Title/Summary/Keyword: Modified PP

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Optimization of Processing Conditions and Mechanical Properties in Polymer Nanocomposite (고분자 나노복합재료의 가공조건 및 물성 최적화)

  • Nam, Byeong-Uk;Hong, Chae-Hwan;Hwang, Tae-Won
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.6
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    • pp.73-80
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    • 2007
  • Nanocomposites are used as a new class of polymer system and many researchers have been interested in the clay nanocomposite because of its good mechanical properties, heat resistance, flame retardancy, and barrier property. Modified layered silicates as fillers are dispersed at a nanometer-level within a polymer matrix and then new extraordinary properties are observed. In this study, polypropylene/clay nanocomposites were prepared in a twin screw extruder by the melt compounding method. In order to increase the compatibility of PP with the clay, the MAPP was used as a compatibilizer. And organic modified clays were used as a nanometric filler during the melt extrusion. Through the analysis of SAXS, WAXS, the dispersion of clay was investigated. These nanocomposites compared with a neat polypropylene/talc composite have high modulus, low toughness, and reduced shrinkage at the stable dispersion.

Modeling of Existing BNR Process using ASM3 and Modified Bio-P Module (ASM3+Bio-P module을 이용한 기존 BNR공정 모사)

  • Rho, Hae-Yeon;Gil, Kyung-Ik
    • Journal of Korean Society on Water Environment
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    • v.23 no.3
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    • pp.309-313
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    • 2007
  • In Activated Sludge Model, COD fraction of primary settled municipal wastewater was a very important parameter. In this study, the COD fraction was determined using the oxygen utilization rate experiments. Readily biodegradable COD ($S_S$) fraction was observed about 29.7% of influent TCOD. $S_I$, $X_I$, and $X_S$ were analyzed to be 7.6%, 7.3%, and 55.4% of TCOD, respectively. The model used in this study was developed based on ASM3 and modified Bio-P module in order to simulate the existing BNR process. Parameter estimation results showed that $Y_{STO,O2}$, $Y_{STO,NO}$, $Y_{H,O2}$, $Y_{H,NO}$, $Y_{PO4}$, ${\mu}_H$, $b_H$, ${\mu}_A$, $q_{PHA}$, $q_{PP}$ and ${\mu}_{PAO}$ were 0.7, 0.64, 0.61, 0.48, 0.31, 3.9, 0.1, 1.35, 4.98, 1.8 and 0.59, respectively. Using the presented model and the estimated parameters, the simulation of the existing BNR process was successfully conducted.

Multi-objective path planning for mobile robot in nuclear accident environment based on improved ant colony optimization with modified A*

  • De Zhang;Run Luo;Ye-bo Yin;Shu-liang Zou
    • Nuclear Engineering and Technology
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    • v.55 no.5
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    • pp.1838-1854
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    • 2023
  • This paper presents a hybrid algorithm to solve the multi-objective path planning (MOPP) problem for mobile robots in a static nuclear accident environment. The proposed algorithm mimics a real nuclear accident site by modeling the environment with a two-layer cost grid map based on geometric modeling and Monte Carlo calculations. The proposed algorithm consists of two steps. The first step optimizes a path by the hybridization of improved ant colony optimization algorithm-modified A* (IACO-A*) that minimizes path length, cumulative radiation dose and energy consumption. The second module is the high radiation dose rate avoidance strategy integrated with the IACO-A* algorithm, which will work when the mobile robots sense the lethal radiation dose rate, avoiding radioactive sources with high dose levels. Simulations have been performed under environments of different complexity to evaluate the efficiency of the proposed algorithm, and the results show that IACO-A* has better path quality than ACO and IACO. In addition, a study comparing the proposed IACO-A* algorithm and recent path planning (PP) methods in three scenarios has been performed. The simulation results show that the proposed IACO-A* IACO-A* algorithm is obviously superior in terms of stability and minimization the total cost of MOPP.

Preparation and Properties of Eco-friendly Waterborne Polyurethane-urea Primer for Thermoplastic Polypropylene Applied to Automobile Interiors (자동차 내장재용 열가소성 폴리프로필렌에 적용되는 선처리제용 친환경 수분산 폴리우레탄-우레아의 제조 및 성질)

  • Shin, Jong Sub;Park, Jin Myeong;Lee, Young Hee;Kim, Han Do
    • Clean Technology
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    • v.20 no.3
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    • pp.232-240
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    • 2014
  • The significance of thermoplastic polyolefin polypropylene (PP) lies in its potential to replace polyvinyl chloride (PVC), the most widely used material for automobile interiors (door trim, dash board), which discharges harmful compounds in certain conditions. Another benefit of PP (0.855 amorphous - 0.946 crystalline $g/cm^3$) is its low density compared to that of PVC ($1.1-1.45g/cm^3$), which reduces vehicle weight. Market demand for eco-friendly water-based adhesive/coating material is rising significantly as a substitute for solvent-based adhesive/coating material which emits VOC and causes harmful working conditions. Under such context, in this study, a series of eco-friendly waterborne polyurethane-urea primer (a paint product that allows finishing paint to adhere much better than if it were used alone) for hydrophobic PP were prepared from different mix of DMPA content, NCO/OH molar ratio, various wt% of silicone diol and various soft segment content, among which DMPA of 21 mole %, NCO/OH molar ratio of 1.2, modified silicone diol of 5 wt% and soft segment content of 73 wt% led to good adhesion strength. Additionally, the incorporation of optimum content of additives (0.5 wt% dispersing agent, 0.5 wt% levelling agent, 1.5 wt% antifoaming agent, 3.0 wt% matting agent) into the optimum waterborne polyurethane-urea also enabled good stability, levelling, antifoaming and non-glossy.

Numerical Errors in Digital Holographic Reconstruction of Interior Sound Fields (홀로그래피를 이용한 실내 음장의 재구성에서 발생하는 수치 오차)

  • 김영기;김양한
    • Journal of KSNVE
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    • v.9 no.4
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    • pp.687-692
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    • 1999
  • Digital holographic reconstruction method [W. A. Veronesi, et al, 1989, JASA, Vol. 85, pp. 588∼598] reconstructs a whole sound field by using measured sound pressure. This paper reports numerical errors of the method that occur at specific frequencies. The errors occur due to the truncation errors included in the calculation of transfer matrixes. The frequencies of the errors depend on the size of boundary element surfaces. Moreover, a modified calculation technique is proposed in the paper. The technique prevents the truncation errors by employing an indirect calculation procedure.

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A 4-Channel 6.25-Gb/s/ch VCSEL Driver for HDMI 2.0 Active Optical Cables

  • Hong, Chaerin;Park, Sung Min
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.17 no.4
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    • pp.561-567
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    • 2017
  • This paper presents a 4-channel common-cathode VCSEL driver array operating up to 6.25 Gb/s per channel for the applications of HDMI 2.0 active optical cables. The proposed VCSEL driver consists of an input buffer, a modified Cherry-Hooper amplifier as a pre-driver, and a main driver with pre-emphasis to drive a common-cathode VCSEL diode at high-speed full switching operations. Particularly, the input buffer merges a linear equalizer not only to broaden the bandwidth, but to reduce power consumption simultaneously. Measured results of the proposed 4-channel VCSEL driver array implemented in a $0.13-{\mu}m$ CMOS process demonstrate wide and clean eye-diagrams for up to 6.25-Gb/s operation speed with the bias current 2.0 mA and the modulation currents of $3.1mA_{PP}$. Chip core occupies the area of $0.15{\times}0.1{\mu}m^2$ and dissipate 22.8 mW per channel.

Rheological Characterization of Polypropylene/Layered Silicate Nanocomposites Using Integral Constitutive Equations (적분형 구성방정식을 이용한 폴리프로필렌/층상 실리케이트 나노복합재료의 유변학적 특성 분석)

  • Lee, Seung-Hwan;Youn, Jae-Ryoun
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.137-140
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    • 2005
  • Exfoliated nanocomposites of polypropylene/layered silicate were prepared by a melt compounding process using maleic anhydride modified polypropylene (PP-g-MAH) and organoclay. It was found that polypropylene/layered silicate nanocomposites exhibited remarkable reinforcement compared with the pure polypropylene or conventional composite filled with agglomerated organoclay. The polypropylene /layered silicate nanocomposites showed stronger and earlier shear thinning behaviors and outstanding strain hardening behavior than pure polypropylene or other conventional composites in shear and uniaxial elongational flows, respectively. We simulated rheological modeling for the pure polymer matrix and polypropylene/layered silicate nanocomposite in shear and elongational flows using K-BKZ integral constitutive equation. The two types of K-BKZequations have been examined to describe experimental results of shear and uniaxial elongational viscosities of pure polypropylene and polypropylene/layered silicate nanocomposite.

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A Partial Response Maximum Likelihood Detection Using Modified Viterbi Decoder for Asymmetric Optical Storage Channels

  • Lee, Kyu-Suk;Lee, Joo-Hyun;Lee, Jae-Jin
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.30 no.7C
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    • pp.642-646
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    • 2005
  • We propose an improved partial response maximum likelihood (PRML) detector with the branch value compensation of Viterbi decoder for asymmetric high-density optical channel. Since the compensation value calculated by a survival path is applied to each branch metric, it reduces the detection errors by the asymmetric channel. The proposed PRML detection scheme improves the detection performance on the $2^{nd},\;3^{rd}\;and\;4^{th}$ order PR targets for asymmetric optical recording channel.

Comparative Studies on Morphology of Low Temperature Ar-Plasma-treated Polymer Surfaces (알곤저온플라즈마처리된 고분자표면의 모폴로지에 대한 비교연구)

  • Seo Eun-Deock
    • Textile Coloration and Finishing
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    • v.16 no.5
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    • pp.35-41
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    • 2004
  • Poly(ethylene terephthalate), polyimide(Kapton), and polypropylene surfaces were modified with argon low temperature plasma by RF glow discharge at 240m Torr, 40W to investigate the surface morphological changes due to the plasma treatment using atomic force microscopy(AFM). Analysis of the AFM images and Ra(average roughness) revealed that the plasma treatment resulted in significant ablation on the surfaces. The morphological changes and surface roughness, however, were different depending on material characteristics such as heat stability, presence of amorphous region, swelling phenomenon, and molecular structure of repeating unit. It was assumed that polypropylene due to its tertiary hydrogen was ablated easily compared to poly(ethylene terephthalate), and that polyimide was more resistant to the ablation than PET due to rigid skeleton of imide and stable phenyl ring structure.

The Estimation of Rail Current Distribution According to Feeding Scheme (급전방식에 따른 레일전류 분포 예측)

  • Lee, C.M.;Han, M.S.;Jung, H.S.;Kim, J.R.;Kim, H.J.
    • Proceedings of the KIEE Conference
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    • 2005.07b
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    • pp.1619-1621
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    • 2005
  • AC electric railway feeding system classifies into three groups such as normal, TIE and PP feeding method. If the feeding scheme of ac electric railway is changed, current distribution flowing through the line is also modified. And if the current distribution is altered according to the feeding scheme, returned tendency through rail load current or fault current of the train is changed. So the investigation about error correcting method of protective relay is needed considering feeding scheme. In this paper prior to error correcting of protective relay, through interpreting feeding circuit, changes in current distribution of the rail in accordance with feeding would be predicted and analyzed.

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