• Journal of the Korean Ceramic Society
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• v.32 no.9
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• pp.1047-1055
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• 1995

Mn-Zn ferrite granules were formed by a spray-drying method of the slurry containing different kinds and concentrations of binders at various temperatures. The slurry was made by conventional ceramic processing method, that is, by mixing Fe2O3, MnO, ZnO powders (52 : 24 : 24 mol%), calcining and milling. Typical shape of the spray dried granules was spherical. The compaction behavior of these granules was dependent on the spray-drying temperature and the kind and concentration of binders. At lower pressure the granules were displaced and at higher pressure the granules were deformed and fractured to fill pores among the granules. The optimum concentration of the binder was 0.5wt%. The granules containing 0.5wt% PVA 205 were deformed and fractured well and the green density was higher than others. At higher concentrations of the binder the granules were deformed rather than fractured, therefore the green density was lowered because of the remaining unfilled pores. The decomposition temperature and the heat released were increased with increasing the concentration of the binders. The compaction response of the granules containing PVA 205 was more efficient than those containing PVA 217 and PVA 117. Green density was not dependent on the degree of hydrolysis of the binders. The compaction response of the granules spray-dried at 15$0^{\circ}C$ was most efficient.

• Journal of the Korean Ceramic Society
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• v.40 no.1
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• pp.1-4
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• 2003

To study the effect of aggregates on the microstructure of sintered bodies, Mn-Zn ferrite powders were prepared by an alcoholic dehydration method. Aggregate powders and reground powders were used as seeds and matrices, respectively. The mixing ratios for the aggregate and reground powders were varied with the sintering temperatures. Green densities were measured with changes in forming pressure and they were related to the microstructures of the sintered bodies. The aggregates proved to be capable of acting as seeds for abnormal grain growth. When the green density difference between the aggregate and the matrix was large, the aggregate could become the seed of abnormal grain growth. As the forming pressure increased, the more aggregates became seeds of abnormal grain growth.

• Electrical & Electronic Materials
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• v.3 no.3
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• pp.205-214
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• 1990

본 논문은 저손실 Mn-Zn-Fe 페라이트 제조에 관하여 연구한 것이다. Mn-Zn-Fe 페라이트는 16mol% Xno, 31mol% MnO 및 53mol% Fe$_{2}$O$_{3}$로 조성하였으며 0.1wt% $Na_{2}$SiO$_{3}$ 0.05wt% $Na_{2}$SiO$_{3}$ 0.1%wt% CaO 0.05% SiO$_{2}$ 및 0.05wt% SiO$_{2}$ 및 0.05wt% $Na_{2}$SiO$_{3}$ 0.1% CaO 0.05wt% $Al_{2}$O$_{3}$를 미량 첨가하였다. 그리고 하소와 분쇄과정을 거친 분말은 충진성을 높이기 위하여 과립화하였다. 소결 1250, 1300 및 1350.deg.C에서 이루어졌고, 평형 산소분압은 소오킹 시 PO$_{2}$는 6%부터 시작하여 점차 감소시켰으며 900.deg.C에서 순수한 질소 분위기로 냉각시켰다. 초투자율, 손실계수 및 고유저항 등의 자기적인 특성은 1300.deg.C에서 소결했을 경우의 것이 가장 우수하였다. 즉, 초투자율은 2*$10^{3}$~$10^{3}$의 높은 값을 얻을 수 있었으며 tan.delta./.mu.i값은 100KHz~ 400KHz의 고파수대에서 9*10$_{-6}$~21*10$_{-6}$이었으며 고유저항 값은 485~680 .OMEGA.-cm의 높은 값을 나타내어 중간주파수대의 자심재료에 적합한 페라이트임을 확인하였다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.05a
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• pp.96-100
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• 2003

평면형 자심재료용으로 응용하기 위한 Mn-Zn 페라이트에서 저손실 조성의 전자기적 특성과 분위기 조건에 따른 특성변화를 관찰하였다. $Fe_{2}O_{3}$ : MnO : ZnO 의 물비가 53 : 36 : 11 일 때, 가장 우수한 특성을 나타내었으며, $SiO_{2}$와 CaO는 입계 저항층 형성을 통한 손실은 감소시키고, 이로 인해 성능지수는 증가하여 100kHz ~ 200kHz 범위에서 최대값을 나타내어 전자기적 효율이 극대화되었다. 산소분압의 제어는 승온과정부터 산소분압을 제어시켜주어야만 Zn-loss 현상의 증가와 $Fe^{2+}$이온 농도의 감소 및 $Fe^{2+}-Fe^{3+}$ 이온간의 호핑(hoping)현상 등에 의한 손실을 최소화 할 수 있으며, 높은 투자율을 얻을 수 있었다. 그리고 소결 또는 냉각 중 평형 산소분압이 유지되지 못하면 다량의 결함이 출현하게 되고, 특히 $600^{\circ}C$이하에서 스피넬 상의 분해-산화반응이 일어나면서 미세구조 상에 결함으로 남게 되어 전자기적 특성이 저하되었다.

• Korean Journal of Materials Research
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• v.7 no.9
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• pp.758-762
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• 1997

52mol% Fe$_{2}$O$_{3}$, 26mol% MnO의 조성에서 calcium과 vanadium의 동시첨가에 의한 투자율의 변화원인을 살펴보았다. 초투자율은 첨가물의 농도가 커짐에 따라 감사하였으나 소결체의 밀도나 입자크기는 증가하였으므로 초투자율의 변화는 미세구조의 변화로는 설명되지 않았다. 전기비저항은 첨가물의 농도가 증가함에 따라 증가하였으며 이는 입계의 고저항층의 생성과 vanadium ion에 의한 Fe$^{2+}$이온의 산화로 설명되었다. 첨가물의 농도가 증가함에 따라, 초투자율의 제 2차 최대치가 나타나지 않는 것과 초투자율이 감소하는 것으로부터, 결정자기이방성 상수의 값은 음으로 커짐을 알 수 있었다. 투자육의 온도의존성과 비저항의 변화로부터, 첨가물의 농도에 따른 상온 초투자율의 감소는 Fe$^{2+}$ 이온 농도의 감소에 따른 결정자기이방성 상수의 증가에 의한 효과와 입계에 유리질이 생겨 자벽이 쉽게 이동하지 못하는 효과 때문인 것으로 판단되었다.

• Journal of the Korean Ceramic Society
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• v.30 no.5
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• pp.357-364
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• 1993

Chemical reaction occurred in the interface of Mn-Zn ferrite and glass after bonding. Effects of the formation of reaction layer on the magnetic properties were investigated. The composition of glass was 23PbO-61SiO2-6ZnO-8Na2O-2K2O and the ferrite was chosen to have a high permeability. Toroid samples of ferrites bonded with glasses, were heat-treated at $700^{\circ}C$, 80$0^{\circ}C$ and 90$0^{\circ}C$ for 1h. The reaction was observed to increase with bonding temperature, resulting in the development of reaction layer. Subsequently the initial permeability was found to be decreased. The permeabilities decreased by 25% with increasing bonding temperature from $700^{\circ}C$ to 80$0^{\circ}C$. At the bonding temperature of 90$0^{\circ}C$, the permeability was decreased by 45%, compared to that of 80$0^{\circ}C$.

• Resources Recycling
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• v.13 no.6
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• pp.37-42
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• 2004

The power loss analysis was carried out for Ni-Cu-Zn ferrite sample with different content of NiO and ZnO. The power loss, Pcv decreases monotonically with increasing temperature and attains to a certain value at around 100~120 degrees Celsius. The frequency dependence of Pcv can be explained by Pcv~f$^n$, and n is independent of the frequency, f up to 1 MHz. The Pcv decreases with an increase in ZnO/NiO. The Pcv was separated to hysteresis loss(Ph) and residual loss(Pcv-Ph). The temperature characteristics and compositional dependence of Pcv can be attributed to the Ph, while Pcv-Ph is not affected by both temperature and ZnO/NiO. By analyzing temperature and composition dependence of Ph and initial permeability, ${\mu}_i$ like following equations could be formularized. ${\mu}_i{\mu}_0=I_s^2/(K_I+b{\sigma}_0{\lambda}_s)$ Wh=13.5(I$_s^2/{\mu}_i{\mu}_0)$ Where ${\mu}_0$ is permeability of vacuum, I$_s$ is saturation magnetization, K$_I$ is anisotropy constant, $s_0$ is internal heterogeneous stress, ${\lambda}_s$ is magnetostriction constant, b is unknown constant, and Wh is hysteresis loss per one cycle of excitation (Ph=Wh${\times}$f). Steinmetz constant of Ni-Cu-Zn ferrite, m=1.64~2.2 is smaller than that of Mn-Zn ferrites, which suggests the difference of loss mechanisms between these materials.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2003.11a
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• pp.165-167
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• 2003

무전극 형광 램프에서 플라즈마 생성이 용이한 유도 결합형 플라즈마가 많이 사용되는데, 코일의 권선수나 주파수에 의해 전기적 특성의 변화가 크다. 따라서, 기존의 환형 무전극 형광 램프에 사용되는 ferrite core나 coil을 새롭게 적용하기 위하여 투자율이 2000인 Mn-Zn ferrite를 사용하여 주파수와 coil의 권선수를 변화시켜 전기적 특성을 측정하여 기존의 환형 무전극 형광램프와 비교·검토하였다.

• Proceedings of the Korean Vacuum Society Conference
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• 1994.02a
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• pp.85-86
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• 1994

• Journal of the Korean Ceramic Society
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• v.28 no.6
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• pp.483-487
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• 1991

Ferrite electromagnetic wave absorber whose attenuation ability are mainly relied on their magnetic loss, has been used in relatively narrow wave frequency ranges. In this study, we tried to produce a wide-range electromagnetic wave absorber by laminating sintered ferrite (Mn0.07Ni0.28Zn0.65Fe2O4) and dielectrics (Cordierite). We also investigated effects of dielectric constant and thickness on the attenuation behavior of the absorber. Applicable band width, in which the attenuation is greater than 20 dB can be widened from 100∼700 MHz of ferrite alone to 100∼900MHz by employing the laminated structure. Thickness of dielectrics to achieve wide-range application decreased as the dielectric constant increased.