• Title/Summary/Keyword: MnS

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Etching characteristics of ZnS:Mn thin films using $BCl_3/Ar$ high density plasma ($BCl_3/Ar$ 고밀도 플라즈마를 이용한 ZnS:Mn 박막의 식각 특성)

  • Kim, Gwan-Ha;Kim, Chang-Il;Lee, Cheol-In;Kim, Tae-Hyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.124-125
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    • 2005
  • ZnS:Mn thin films have attracted great interest as electroluminescence devices. In this study, inductively coupled BCl$_3$/Ar plasma was used to etch ZnS:Mn thin films. We obtained the maximum etch rate of ZnS:Mn thin films was 2209 ${\AA}$/min at a BCl$_3$(20%)/Ar(80%) gas mixing ratio, an RF power of 700 W, a DC bias voltage of-250 V, a total gas flow of 20 sccm, and a chamber pressure of 1 Pa. It was proposed that sputter etching is dominant etching mechanism while the contribution of chemical reaction is relatively low due to low volatility of etching products.

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MnO2 Nanowires Electrodeposited in a Porous Network of Agarose Gel as a Pseudocapacitor Electrode

  • Jin, Sohyun;Ryu, Ilhwan;Lim, Geo;Yim, Sanggyu
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.406-410
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    • 2020
  • Despite a simple preparation of manganese oxide (MnO2) nanowires by electrodeposition, the improvement in specific capacitance (Csp) and voltammetric response of the MnO2 nanowire-based electrodes has been quite limited. This is attributed to the poor electrical conductivity of MnO2 and its dense bulk morphology due to the aggregation of the nanowires. This study investigated the capacitive performance of MnO2 nanowires electrodeposited on agarose thin films. The good ionic conductivity and porous network of the agarose film provided favorable growth conditions for the MnO2 nanowires with suppressed aggregation. A maximum Csp value of 686 F/g measured at a scan rate of 10 mV/s was obtained, which was significantly larger than that of 314 F/g for the agarose-free MnO2 electrode at the same scan rate. The rate capability was also improved. The Csp measured at a high scan rate of 100 mV/s retained 74.0% of the value measured at 10 mV/s, superior to the retention of 71.1% for the agarose-free MnO2 electrode.

The study of the c($2{\times}2$) ordered Mn surface alloy Pd(001)

  • Jung, J.W.;Kim, S.H.;Park, C.Y.;Seo, J.K.;Min, H.G.;Byun, D.H.;Kim, J.S.
    • Journal of Korean Vacuum Science & Technology
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    • v.4 no.3
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    • pp.68-72
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    • 2000
  • We have deposited Mn on Pd(oon) at RT up to 30 ML. LEED pattern changed from p($1{\times}1$) to c($2{\times}2$) order below 0.5 ML Mn deposition. During Mn deposition, we have not found any changes in the peak position and the intensity of LEED I/V curve. Using LEED I/V curve analysis for each coverage, we found atomic structure and surface composition of c($2{\times}2$) ordered Mn alloy on Pd(001) surface. Above 1 Ml Mn, in the first layer the Mn subplane lies above the Pd subplane by 0.32 ${\AA}$. This result is very different from the earlier result of Jona et al., who contended that after annealing at 200 for 2 min, a buckled first layer with the Mn subplane lower than the Pd subplane by 0.2 ${\AA}$.

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Design and Simulation of a Flow Mobility Scheme Based on Proxy Mobile IPv6

  • Choi, Hyon-Young;Min, Sung-Gi;Han, Youn-Hee;Koodli, Rajeev
    • Journal of Information Processing Systems
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    • v.8 no.4
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    • pp.603-620
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    • 2012
  • Proxy Mobile IPv6 (PMIPv6) is a network-based mobility support protocol and it does not require Mobile Nodes (MNs) to be involved in the mobility support signaling. In the case when multiple interfaces are active in an MN simultaneously, each data flow can be dynamically allocated to and redirected between different access networks to adapt to the dynamically changing network status and to balance the workload. Such a flow redistribution control is called "flow mobility". In the existing PMIPv6-based flow mobility support, although the MN's logical interface can solve the well-known problems of flow mobility in a heterogeneous network, some missing procedures, such as an MN-derived flow handover, make PMIPv6-based flow mobility incomplete. In this paper, an enhanced flow mobility support is proposed for actualizing the flow mobility support in PMIPv6. The proposed scheme is also based on the MN's logical interface, which hides the physical interfaces from the network layer and above. As new functional modules, the flow interface manager is placed at the MN's logical interface and the flow binding manager in the Local Mobility Anchor (LMA) is paired with the MN's flow interface manager. They manage the flow bindings, and select the proper access technology to send packets. In this paper, we provide the complete flow mobility procedures which begin with the following three different triggering cases: the MN's new connection/disconnection, the LMA's decision, and the MN's request. Simulation using the ns-3 network simulator is performed to verify the proposed procedures and we show the network throughput variation caused by the network offload using the proposed procedures.

Damping Capacities of Nonthermoelastic BCC and HCP Martensites of Fe-Mn Binary System (Fe-Mn 이원계에서 비열탄성형 BCC 마르텐사이트와 HCP 마르텐사이트의 진동감쇠능)

  • Choi, C.S.;Kim, J.D.;Moon, I.G.;Baik, S.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.4 no.4
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    • pp.15-23
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    • 1991
  • The damping capacities of the nonthermoelastic bcc type lath martensite and of the nonthermoelastic hcp type thin plate martensite in Fe-Mn alloys were studied. Fe-17%Mn alloy showing the hcp type thin plate martensite was superior to Fe-4%Mn alloy having the bcc type lath martensite in damping capacity. The damping capacity of the Fe-17%Mn alloy became greater with increasing the hcp martensite volume fraction. The damping mechanism of the Fe-4%Mn alloy was well explained by the dislocation model. However, the damping mechanism of the Fe-17%Mn alloy was explained on the basis of austenite/martensite interface moving model. The two alloys showed almost same levels of tensile strength. However, the elongation was greater in the Fe-17%Mn alloy than in the Fe-4%Mn alloy, showing lower yield strength in the former than in the latter. This result was considered to be attributed to formation of stress-induced martensite during tension test.

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Effect of the Cu Composition Ratio on the Phase Transformation in Low Ni Austenite Cast Iron, Fe-3%C-16%(Ni+Mn+Cu) (Fe-3%C-16%(Ni+Mn+Cu) 주철에서 상변태에 미치는 Cu 조성비의 영향)

  • Park, Gi-Deok;Heo, Hoe-Jun;Na, He-Sung;Kang, Chung-Yun
    • Korean Journal of Metals and Materials
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    • v.50 no.6
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    • pp.419-425
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    • 2012
  • The purpose of this research was to develop a low Ni austenitic cast iron through replacing Ni by Cu and Mn because they are cheaper than Ni. The effect of the Cu content (6-12 wt%) on the microstructure characteristics was investigated in Fe-3%C-16%(Ni+Cu+Mn) cast iron. Contrary to general effect of the Cu on cast iron, the result of the microstructure analysis indicated that bainite and cementite were formed in high Cu content (>8 wt%Cu). A crystallized Cu-solution (Cu-Mn) phase and MnS in the Cu-solution were formed. The quantity of those phases increased as the Cu content increased. Consequently, the high Cu content in the composition ratio (Ni+Cu+Mn=16%) caused the formation of Cu-Mn/MnS and those phases decreased the effect of Cu and Mn on austenite formation. For this reason, bainite and cementite were formed in high Cu content.

A simple one Step Thermochemical Approach for Synthesis of ZnS:Mn Nanocrystals (NCs)

  • Molaei, Mehdi;Lotfiani, Ahmad;Karimimaskon, Fatemeh;Karimipour, Masoud;Khanzadeh, Mohammd
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.14 no.1
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    • pp.92-95
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    • 2014
  • In this work we have synthesized ZnS:Mn nanocrystals (NCs) using a simple one step thermochemical method. $Zn(NO_3)_2$ and $Na_2S_2O_3$ were used as the precursors and $Mn(NO_3)_2$ was the source of impurity. Thioglycolic acid (TGA) was used as the capping agent and the catalyst of the reaction. The structure and optical property of the NCs were characterized by means of X- ray diffraction (XRD), HRTEM, UV-visible optical spectroscopy and photoluminescence (PL). X-ray diffraction (XRD) and transmission electron microscopy (TEM) analyses demonstrated cubic phase ZnS:Mn NCs with an average size around 3 nm. Synthesized NCs exhibited band gap of about 4 eV. Photoluminescence spectra showed a yellow-orange emission with a peak located at 585 nm, demonstrating the Mn incorporation inside the ZnS particles.

Absolute $^{56}Mn$ Activity Measurement by $4{\pi}{\beta}-{\gamma}$ Conincidence Counting Technique ($4{\pi}{\beta}-{\gamma}$ 동시계수기술에 의한 $^{56}Mn$방사능 절대측정)

  • Hwang, Sun-Tae;Choi, Kil-Oung;Oh, Pil-Jae;Lee, Kyung-Ju;Lee, Kun-Jai
    • Journal of Radiation Protection and Research
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    • v.12 no.2
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    • pp.19-27
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    • 1987
  • In order to determine the $^{56}Mn\;{\gamma}$-detection efficiency of a $MnSO_4$ bath system, it is essential to do the absolute activity measurement of $^{56}Mn$ solution. For the fabrication of $^{56}Mn$ samples, a 13.718 mg of $^{56}Mn$ metal flake with 99.99% purity was irradiated for 12 minutes at the thermal neutron field of about $10^{13}n/cm^2s$ of flux density. The neutron activated $^{56}Mn$ metal sample was dissolved in 50 ml of 0.1 N-HCl solution. The $^{56}Mn$ samples were fabricated by using the dissolved stock solution and the activity of each of them was measured by the $4{\pi}{\beta}-{\gamma}$ coincidence counting technique. The obtained result was 408.070 kBq/mg with total uncertainty of 0.366% at reference date, 0 h on October 15, 1987.

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Microstructure and Machinability with Alloying Elements in the 304 Stainless Steel (304 스테인레스강에서 첨가원소에 따른 미세조직 및 절삭성 연구)

  • Kang, S.S.;Kim, H.C.;Lee, J.H.;Cho, J.R.;Jung, Y.G.;Jang, C.H.;Hwang, H.S.
    • Korean Journal of Materials Research
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    • v.16 no.9
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    • pp.584-591
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    • 2006
  • To enhance the machinability of the austenite stainless alloys, Mn and S were added to form MnS in the austenite matrix. Recently, Ca is also added to increase machinability. The alloying elements, such as C, Mn, S, Ca, and Al, are known to affect machinability, but those roles are not well understood. In this study, the ingots, controlled of alloying elements, C, Mn, S, Ca, Al, were prepared in the 304 stainless steel. The relationship between microstructure and machinability was compared to understand the role of alloying elements. It was proved that Mn and S enhanced machinability but C reduced it by analyzing cutting force on machining in the lathe. The alloying elements, Ca and Al, made a complex oxide compound of Mn-S-Ca-Al-Si-O, which results in increasing tool life. The ferrite volume fraction was changed with alloying elements and the effect of the ferrite fraction on machining was also discussed.

XMCD and PES study of a compensated-ferrimagnetic half-metal Mn3Ga

  • Seong, Seungho;Lee, Eunsook;Kim, Hee Yeon;Kim, Younghak;Baik, Jaeyoon;Kang, J.S.
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1190-1195
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    • 2018
  • By employing soft X-ray magnetic circular dichroism (XMCD), soft X-ray absorption spectroscopy (XAS), and photoemission spectroscopy (PES), we have investigated the electronic structure of the candidate zero-moment half-metallic $Mn_3Ga$. We have studied the ball-milled and annealed $Mn_3Ga$ powder samples that exhibit nearly zero magnetization. Mn 2p XAS revealed that Mn ions in $Mn_3Ga$ are nearly divalent for both of the Mn ions having the locally octahedral symmetry and those having the locally tetrahedral symmetry. The measured Mn 2p XMCD spectrum of $Mn_3Ga$ is very similar to that of ferrimagnetic $MnFe_2O_4$ having divalent Mn ions. The sum-rule analysis of the Mn 2p XMCD spectrum shows that both the spin and orbital magnetic moments of Mn ions in $Mn_3Ga$ are negligibly small, in agreement with the nearly compensated-ferrimagnetic ground state of $Mn_3Ga$. The valence-band PES spectrum of $Mn_3Ga$ agrees well with the calculated density of states, supporting the half-metallic electronic structure of $Mn_3Ga$.