• 제목/요약/키워드: MnS

검색결과 2,057건 처리시간 0.032초

$MnO_2$치환된 PMN계 세라믹스의 유전특성 (A study on Dielectric Properties usig PMN Ceramics with $MnO_2$ substitution)

  • 지승한;유도현;이은학;김영일;박광현;이덕출
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1997년도 하계학술대회 논문집 C
    • /
    • pp.1537-1539
    • /
    • 1997
  • In this study, the dielectric properties of $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3$ Ceramics have been investigated as a addition of the amount of $MnO_2(0{\leq}x{\leq}0.9wt%)$. The Temperature-dependant dielectric characteristics of 0.9PMN-0.1PT relaxor ferroelectric system were improved by enhencing the extent of the diffuse phase transition(DPT). The maximum dielectric permittivity decreased by substitution $MnO_2$ and the dielectric loss decreased with increasing $MnO_2$ substitution amount. It is expected decreasing in inner heat energy for temperature with increasing $MnO_2$ substitution.

  • PDF

Electronic Structures and Physical Properties of the Ordered and Disordered $Ni_2$MnGa Alloy Films

  • Kim, K. W.;Lee, N. N.;Y. Y. Kudryavtsev;Lee, Y. P.
    • 한국진공학회지
    • /
    • 제12권S1호
    • /
    • pp.104-106
    • /
    • 2003
  • In this study, the electronic structures and physical properties of Ni$_2$MnGa alloy films and their dependence on the order-disorder structural transitions were investigated. The results show that the ordered films behave nearly the same as the bulk $Ni_2$MnGa alloy, including the martensitic transformation at 200 K. Unexpectedly, the disordering in $Ni_2$MnGa alloy films does not lead to any appreciable magnetic ordering down to 4 K. An annealing of the disordered films restores the ordered structure with an almost full recovery of the magnetic and the transport properties of the ordered $Ni_2$MnGa alloy films. A possible explanation of the disappearance of magnetic moment in the disordered film is given by using the ab initio first-principles electronic-structure calculations.

$Ca_{2-X}-Ln_{x}MnO_{4}$상의 합성과 결정구조 정밀화 {Ln=Gd, Nd, Pr, Sm} (Syntheses and structure refinement of $Ln_{x}MnO_{4}$ {Ln=Gd, Nd, Pr, Sm})

  • 서상일;이재열
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
    • /
    • pp.726-729
    • /
    • 2000
  • Though L $a_{1+x}$S $r_{2-x}$M $n_2$ $O_{7}$ n=2 R-P phases have been well known to have CMR effect, it was generally believed that n=1 phase was insulating. But recently monolayered perovskite $Ca_{2-x}$L $n_{x}$Mn $O_4$phase has been reported to show magnetoresistance. In this study, layered perovskite $Ca_{2-x}$L $n_{x}$Mn $O_4$ (x=0, 0.5, Ln=Pr, Nd, Sm, Gd) phases were synthesized by solid state reaction and their structures were refined by Rietveld method. The space groups of $Ca_2$Mn $O_4$, N $d_{0.5}$C $a_{1.5}$Mn $O_4$phases were refined as C2cb and Fmmm, respectively.y.ely.y.y.y.y.y.y.

  • PDF

Evaluation of Manganese Ion on Controlling Harmful Microorganisms In vitro and In vivo for the Early-Weaned Pig

  • Kim, I.H.;Kang, D.H.;Kim, C.S.;Seok, H.B.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • 제11권1호
    • /
    • pp.8-12
    • /
    • 1998
  • Two experiments were conducted to determine the effects of $MnSO_4$ on controlling harmful microorganisms in vitro and in vivo. The in vitro experiment was conducted to examine the effects of manganese sulfate $(MnSO_4)$ on the reduction of Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) by growth stimulation of Pediococcus acidilactici (P. acidilactici; lactic acid bacteria). Manganese ion (0.003 %) was found to stimulate the growth of P. acidilactici in the In Vitro system. When E. coli and S. aureus were grown in a mixture with P. acidilactici, their numbers were reduced. This may be the result of a reduction of pH in the medium as a result of better growth of P. acidilactici due to stimulation by the Mn ion. The in vivo experiment was conducted to determine the effects of $MnSO_4$ in diets on controlling harmful microorganisms in fecal samples of pigs. There were no significant differences for the microbial numbers (i.e., total microorganisms, E. coli, lactic acid bacteria and S. aureus) in feces of pigs fed $MnSO_4$ compared to feces of pigs fed the control diet through 7 days. However, on day 7 of experiment, the pH of feces in pigs fed $MnSO_4$ (0.1%) decreased faster than pigs fed the control diet.

리튬 전지용 $MnO_2$ Cathode의 제조 및 전기화학적 특성 (The Preparation and Electrochemical Properties of $MnO_2$ Cathode for Lithium Rechargeable Battery)

  • 유영한;김영재;박준기;서부완;정인성;김주승;박복기;구할본;문성인
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1996년도 하계학술대회 논문집 C
    • /
    • pp.1682-1684
    • /
    • 1996
  • Recently, because diffusion of cordless machine and smart card and so on, and concern of unpolluted materials, one are concerned with Li secondary batteries. Li secondary batteries have high voltage, high energy density and high power density, and heavy metal pollution problems are little. Mn is low price and is distributed much quantity. Therefore, we investigated $MnO_2$. In this study, we worked the electrochemical properties and charge/discharge characteristics of $MnO_2/Li$ cells. In results, the more heating temperature is high, the more ${\gamma}-phase$ varied ${\beta}-phase$, and when $MnO_2$ is heated at $320^{\circ}C$ and super-s-black 20wt% is mixed, characteristics are the best.

  • PDF

비정질 $MnO_2$ 전극의 전극두께에 따른 고출력 특성 변화 (High Power Characteristics of Amorphous $MnO_2$ Electrode by Variation of Electrode Thickness)

  • 성우경;김은실;이하영;김선욱
    • 전기화학회지
    • /
    • 제3권4호
    • /
    • pp.235-240
    • /
    • 2000
  • 고출력 전기화학 캐패시터를 위한 전극제조공정으로 screen printing과 doctor blade법이 연구되었다. Screen printing에 의해서 제작된 비정질 $MnO_2$전극으로 측정된 CV (cyclic voltammogram)는 이상적인 캐패시터에 가까운 특성을 보여주었다. 50mV/s의 scan rate에서의 CV로부터 계산된 비용량은 $140{\mu}m,\;24{\mu}m,\; 3{\mu}m$의 전극두께에 대해서 각각 5.8F/g과, 81.8F/g, 172.0F/g의 값을 나타내었다. Screen printing전극에서의 $MnO_2$활물질의 이용율을 $100\%$로 하였을 때, paste와 doctor blade법의 이용율은 각각 $3.4\%$$47.6\%$이었다. Screen printing은 고출력 응용을 위한 얇은 전극의 코팅 방법으로 우수한 특성을 보였다.

난소절제 쥐에서 칼슘섭취수준에 따른 망간의 보충이 골격상태 및 칼슘평형에 미치는 영향 (The Effects of Manganese Supplementation on Bone Status and Calcium Balance in Ovariectomized Rats according to the Calcium Intake Levels)

  • 배윤정;손은화;김병철;서동완;김미현
    • Journal of Nutrition and Health
    • /
    • 제41권3호
    • /
    • pp.206-215
    • /
    • 2008
  • The purpose of this study was to investigate the effect of manganese (Mn) supplementation on bone status and calcium balance in ovariectomized rats according to the calcium intake levels. Total of 50 Sprague Dawley female rats (6 weeks) were divided into 5 groups and bred for 12 weeks: sham operated control group (SACa), OVX Ca deficiency group (OLCa) with Ca deficiency diet (0.1% Ca modified AIN-93N diet), OVX Ca deficiency & Mn supplement group (OLCaMn), OVX adequate Ca group (OACa; 0.5% Ca AIN-93N diet) and OVX adequate Ca & Mn supplement group (OACaMn). BMD (bone mineral density) of the femur was increased by Mn supplementation in OVX adequate Ca group. However, BMDs of spine, femur and tibia were lowered in OLCa compared to the OLCaMn group. Bone strength of tibia in OLCaMn group was significantly lower than OLCa group. Serum ALP (alkaline phosphatase) and CTx (C-telopeptide of collagen cross-links) levels were significantly higher in ovariectomized rats than those in the sham group, but they were not changed by Mn supplementation. Ca retention rate and Ca absorption rate did not differ among the experimental groups. Urinary Ca excretion was increased by Mn supplementation in Ca deficiency rats. In summary, Mn supplementation resulted in positive effects on bone mineral density ovariectomized rats with which intake adequate Ca. However, Mn supplementation on Ca deficiency ovariectomized rats resulted in decrement of BMO and bone strength by increasing Ca excretion. Therefore, it is encouraged to consider calcium intake levels in supplementation of manganese in order to prevent postmenopausal osteoporosis and to keep bone healthy. (KoreanJNutr2008; 41(3): 206~215)

Mg-Zn-Mn-(Ca)합금의 크리이프 소성변형 및 파단거동에 관한 연구 (A Study on the Plastic Deformation and Fracture Behavior of Mg-Zn-Mn-(Ca) Alloys)

  • 강대민;박수찬;강경일
    • 동력기계공학회지
    • /
    • 제10권3호
    • /
    • pp.45-50
    • /
    • 2006
  • In this paper, creep tests of Mg-Zn-Mn and Mg-Zn-Mn-Ca alloy casted by mold under the temperature range of 473.00-573.00K, and the stress range of 23.42-87.00Mpa were done with the equipment of automatic controlled temperature and computer for data acquisition. The activation energies were obtained by relationship between creep rate and temperature, and the stress exponents were obtained by relationship between creep rate and stress. From the experiment results, the activation energies of Mg-Zn-Mn and Mg-Zn-Mn-Ca alloy were 149.87kJ/mol, 147.97kJ/mol, respectively, and the stress exponents of those alloy were 5.13, 5.59, respectively, under the temperature of 473.00-493.00K and the stress range of 62.43-78.00Mpa. And the activation energies of those alloy were 134.41kJ/mol, 129.22kJ/mol, respectively, and the stress exponent of those alloy were 3.48, 3.77, respectively, under the temperature of 553-573Mpa and the stress range of 23.42-39.00Mpa. Also the lifes of Mg-Zn-Mn-Ca alloy were higher than those of Mg-Zn-Mn alloy, and the results of SEM showed fracture surfaces under low temperature had smaller dimples than those under high temperature.

  • PDF

ZnGa$_{2}$O$_{4}$:Mn,O 형광체의 휘도 및 색도 특성 (Brightness and chromaticity characteristics of ZnGa$_{2}$O$_{4}$:Mn,O phosphors)

  • 박용구;한정인;곽민기;한종근;주성후
    • E2M - 전기 전자와 첨단 소재
    • /
    • 제10권3호
    • /
    • pp.262-267
    • /
    • 1997
  • In order to improve the brightness and chromaticity of green emitting low voltage phosphor for FED, we examine PL, PLE and CL emission characteristics of ZnGa$_{2}$O$_{4}$:Mn,O prepared in Ar and vacuum. ZnGa$_{2}$O$_{4}$:Mn,O sintered in vacuum shows about 16 times as bright as the one fabricated in Ar and excellent chromaticity. In PL emission spectra of ZnGa$_{2}$O$_{4}$:Mn,O at low temperature of 9 K, two peaks are observed at 504 nm and 513 nm. At room temperature, the two peaks are superimposed due to the lattice thermal vibrational energy, and only one peak is observed at 509 nm. From PLE measurements, it is believed that the energy levels of the host lattice and Mn ions are coexisted. The energy transfer from the host lattice to the emission center of Mn$^{2+}$ ions occurs.s.

  • PDF

GaMnAs 자성반도체의 박막 특성 및 후처리에 따른 특성 변화 연구 (A Study on the Properties of the Magnetic Semiconductor GaMnAs Depending on Thin Film Deposition and the Treatment Conditions)

  • 김동식
    • 전자공학회논문지 IE
    • /
    • 제45권3호
    • /
    • pp.1-4
    • /
    • 2008
  • 본 연구에서는 비약적으로 발전하고 있는 반도체 소자가 요구하는 새로운 특성을 가진 신소재의 개발에 부응하여, 최근 세계적으로 많은 연구가 되고 있는 spintronics에 사용되는 화합물 자성반도체 박막에 관한 연구를 수행하였다. 본 연구에서 사용되는 GaMnAs 자성반도체 박막은 기존의 III-V족 화합물 반도체 소자에 적용이 쉽고, 그 응용범위가 넓어 앞으로의 전망이 매우 밝은 새로운 화합물 반도체라고 할 수 있다. 그러나 이런 GaMnAs 자성반도체 박막의 경우 현재까지 자성 특성을 나타내는 Curie 온도가 매우 저온에서만 나타나며, 또한 성장 조건에 따라 그 특성이 매우 달라지는 문제점을 가지고 있다. 따라서 본 논문에서는 GaMnAs 자성반도체 박막을 성장시키기 위한 최적조건과 자성특성을 향상시키기 위한 실험을 수행하였다.