• Transactions of the Korean hydrogen and new energy society
• /
• v.18 no.2
• /
• pp.140-150
• /
• 2007

Thermochemical 2-step methane reforming, involving the reduction of metal oxide with methane to produce syngas and the oxidation of the reduced metal oxide with water to produce pure hydrogen, was investigated on ferrite-based metal oxide mediums. The mediums, CoFZ, CuFZ, or MnFZ, were composed of the mixture of M(M=Co, Cu or Mn)-substituted ferrite as an active component and $ZrO_2$ as a binder, respectively. The WZ medium, composed of the mixture of $WO_3$ and $ZrO_2$, was also prepared to compare. With an addition of $ZrO_2$, the surface area of the mediums was slightly increased and the sintering of active components was greatly suppressed during the reduction. The higher reactivity of the reduced mediums for water splitting was confirmed by the temperature programmed reaction. From the results of the thermochemical 2-step methane reforming, the reactivity of $CH_4$ reduction and water splitting with ferrite-based metal oxide mediums was relatively higher than that with WZ, and the order of reactivity of the mediums was MnFZ>CoFZ>CuFZ>WZ.

• Journal of the Korean Ceramic Society
• /
• v.37 no.12
• /
• pp.1204-1211
• /
• 2000

Mn-Zn 페라이트 소결체와 SiO$_2$-PbO-ZnO 삼성분계 유리와의 계면반응에서 페라이트와 유리에 각각 첨가된 ZnO가 계면반응에 미치는 영향을 조사하였다. SiO$_2$-PbO-ZnO 삼성분계 유리에 첨가된 ZnO 함량이 낮은 경우 페라이트와의 접합계면에서 생성되는 중간상은 Pb$_2$(Mn,Fe)$_2$Si$_2$O$_{9}$와 Pb$_{8}$(Mn,Fe)Si$_{6}$O$_{21}$의 고용체였으며, ZnO 농도가 증가함에 따라 중간상은 사라졌다. 유리속의 ZnO 성분이 증가함에 따라 페라이트 소결체 쪽의 계면부근에 Zn의 농도가 증가하는 특이한 분포가 나타났다. 이는 유리 속에 첨가된 Zn 이온의 높은 활동도로 인해 페라이트에 포함된 Zn 이온의 용해반응이 선택적으로 억제되어 나타난 것으로 생각된다. 페라이트에 첨가된 ZnO 함량이 낮은 경우 SiO$_2$-PbO 이성분계 유리와의 접합계면에서 페라이트의 용해에 따른 침식과 입계를 통한 유리의 침투가 심하게 일어났으며, ZnO 함량이 증가함에 따라 계면을 통한 상호확산과 반응이 억제되었다.

• Journal of Power System Engineering
• /
• v.16 no.5
• /
• pp.76-82
• /
• 2012

Duplex stainless steels have the dual microstructure of austenite and ferrite phases. This steel exhibits generally a high corrosion resistance and higher mechanical strength compared with austenitic stainless steels. The steels used in the investigation have the chemical composition of Fe-22Cr-xNi-yMn-0.2N in which the contents of Ni and Mn were varied with maintaining the equal [Ni/Cr] equivalent. The fraction of ferrite phase was increased with the increase of annealing temperature. The impact factor of Mn element on the [Ni] equivalent was amended on the basis of the results of the investigation. 4Mn-2Ni alloy showed the highest pitting corrosion resistance. The fraction ratio, grain size and misorientation angle between grains were measured, and the correlation with pitting potential was investigated.

• Proceedings of the KIEE Conference
• /
• 2001.07e
• /
• pp.86-89
• /
• 2001

In this paper, the composite damping sheet with electromagnetic wave absorption was developed and studied. The damping sheets with Ni-Zn ferrite, Mn-Zn ferrite and PZT were prepared by mixing, molding and drying. From the characterizing results, the optimal portion of the composite is 1:1:0.1 of Mn-Zn ferrite:Rubber:PZT. The maximum absorption was -30 dB at 860 MHz in the single structure and over -15 dB at 180 MHz and 860 MHz in the two or three layers.

• Journal of electromagnetic engineering and science
• /
• v.8 no.2
• /
• pp.70-75
• /
• 2008

In this paper, the EM wave absorber was designed and fabricated for countermeasure against EMI from a ceiling of a tollgate in ETC system. We fabricated several samples in different composition ratios of MnZn-ferrite, Carbon, and CPE(Chlorinated Polyethylene). Absorption abilities were simulated in accordance with different thicknesses of the prepared absorbers and changed complex relative permittivity and permeability according to composition ratio. The optimized mixing ratio of MnZn-ferrite, Carbon, and CPE was found as 40:15:45 wt.% by experiments and simulation. Then the EM wave absorber was fabricated and tested using the simulated data. As a result, the developed EM wave absorber has the thickness of 3.3 mm and absorption ability was more than 20 dB in the case of normal incidence and more than 11 dB for the incident angle from 15 to 45 degrees at 5.8 GHz. Therefore, it was confirmed that the newly developed absorber can be used for ETC system.

• Journal of Welding and Joining
• /
• v.14 no.6
• /
• pp.93-100
• /
• 1996

Effect of a flux composition on weld metal toughness in submerged arc welding with 60kgf/$\textrm{mm}^2$ grade C-Mo type wires was investigated and interpreted in terms of weld metal microstructure and hardenability. Flux workability was also studied by characterizing a weld bead profile. Compared to other weld metals, .weld metal used alumina basic flux with nickel showed lowest oxygen content, highest hardenability and the most acicular ferrite. The highest impact toughness of that weld metal, however, was attributed to the tough matrix due to the nickel rather than to the larger amount of acicular ferrite. Manganese silicate flux had better workability than alumina basic flux, showing broader welding conditions resulting in a depth-to-width ratio of 0.5. The composition of oxides in the weld metal was dependent on the flux composition, showing MnO-SiO$_2$-TiO in manganese silicate flux and MnO-SiO$_2$-Al$_2$O$_3$-TiO in alumina basic flux. MnO-SiO$_2$composition in both oxides was similar to a tephroite.

• Journal of Korea Foundry Society
• /
• v.34 no.1
• /
• pp.1-5
• /
• 2014

The austempering transformation behavior in Fe-0.7wt.%C-2.3wt.%Si-0.3wt.%Mn steel is investigated. Each specimen was austenitized for 60 min at $900^{\circ}C$, and austempered at $380^{\circ}C$ for different time periods varying from 2 min to 256 min. After the austempering heat treatment, the Stage I and II evolutions are performed using optical metallography, X-ray diffraction and image analyses. Variations in the X-ray diffraction patterns and lattice parameters of the ferrite and austenite demonstrate that the residual austenite decomposes into ferrite and carbide during the Stage II evolution; moreover the amount of ferrite increases during the Stage I evolution. While the amount of austenite increases during Stage I, it dicreases during Stage II. Overall, the variations in the volume fractions of the microstructure and carbide formation in stages I and II meet high temperature austempering reaction of the ausferrite microstructure.

• Journal of the Korean Society for Heat Treatment
• /
• v.21 no.6
• /
• pp.281-286
• /
• 2008

In the 1.1 Mn steel containing boron, effects of the 0.1 V addition and processing condition were studied. In the $550^{\circ}C$ interrupted cooling where the main structure is (ferrite + pearlite), the impact toughness decreased as the tensile strength increased by the 0.1 V addition. The $800^{\circ}C$ rolling including two step rolling of $800-770^{\circ}C$, exhibited better strength-toughness balance, as compared to the $770^{\circ}C$ rolling. This seems to be kind of conditioning effect at higher temperature, e.g., more uniform deformation effect. In the accelerated cooling after the $750^{\circ}C$ rolling in a dual phase range, the impact toughness was enhanced, despite a large increase in tensile strength. This is believed to be related to the change of main structure from (ferrite + pearlite) to (ferrite + bainite).

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2004.05b
• /
• pp.69-72
• /
• 2004

In recent, there have been several developments in lamp technology that promise savings in electrical power consumption and improved quality of the lighting space. Above all, the advantage of ring-shaped electrodeless fluorescent lamp is the removal of internal electrodes and heating filaments that are a light-limiting factor of conventional fluorescent lamps. The ring-shaped electrodeless lamp is intended as a high efficacy replacement for the incandescent reflector lamp in many applications. Therefore, the life time of ring-shaped electrodeless fluorescent lamps is substantially higher than that of conventional fluorescent lamps and last up to 60,000 hours. In this paper, we present measurement results of electrical characteristics of a ring-shaped electrodeless fluorescent lamp as a function of frequency and number of coil turns using a highly permeable Mn-Zn ferrite. It is found that the impedance are increased while the quality factor decreases as frequency increases.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1999.11a
• /
• pp.265-268
• /
• 1999

In this study, we investigated the electromagnetic Properties of M $n_{Y}$Z $n_{1-x}$ F $e_{x}$ $O_4$(X=0.67~0.69, Y=0.13~0.19) doped with and without H $o_2$ $O_3$(each of 0.05~ 0.2wt%, step 0.05wt%). The greatest initial permeability of composition is M $n_{0.17}$Z $n_{0.16}$F $e_{0.67}$ $O_4$. As X and Y components, increased. generally resistivity slightly change by the various X and Y components. The initial permeability of M $n_{0.17}$Z $n_{0.16}$F $e_{0.67}$ $O_4$ doped with H $o_2$ $O_3$ showed the about 2.5 times higher than that of M $n_{0.17}$Z $n_{0.16}$F $e_{0.67}$ $O_4$ doped without H $o_2$ $O_3$EX>EX>EX>X>>EX>EX>EX>X>