• 제목/요약/키워드: Mn/S ratio

검색결과 212건 처리시간 0.023초

Pyritization of heavy metals in Lake Shihwa sediments, Korea

  • Shim, Moo-Joon;Kim, Eun-Soo;Kim, Kyung-Tae;Lee, Kwang-Woo
    • Journal of the korean society of oceanography
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    • 제35권2호
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    • pp.89-97
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    • 2000
  • The pyritization of heavy metals in Lake Shihwa sediments was investigated to determine sedimentary Pyrite-heavy metal associations influenced by various metal fractions, organic carbon, and total reduced sulfur. Parameters indicating the degree of heavy metal pyritization (DTMP) and degree of pyritization (DOP) were used to study the incorporation of heavy metals into the pyrite phase. The DOP levels ranged from 3.28-39.45%, showing wide differences among sampling stations. The levels were greater near the water gate and the center of the lake than near the industrial complex. The spatial pattern of the DOP levels was similar to the S/C ratio and also to the salinity. Based on the measured relationships between DOP and DTMP, heavy metals can be divided into three groups. In the first group was As, which showed a high affinity for pyrite. In the second group were Ni, Co and Cu, which showed a gradual increase in DTMP with increasing DOP. In the final group were Pb, Zn, Mn and Cr, which all showed a low DTMP with constant values with respect to DOP.

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열간가스성형용 알루미늄 개발 합금 공정 조건에 관한 연구 (Study on an Aluminum Modified Alloy and Manufacturing Conditions for Hot Metal Gas Forming)

  • 이경민;고건영;이현철;김동옥;이윤교;김정섭;송종호
    • 소성∙가공
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    • 제26권4호
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    • pp.222-227
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    • 2017
  • In order to respond to environmental regulations and increased demand for fuel economy, the demand for lightweight car bodies has grown. Hydroforming of aluminum is one possible solution as it eliminates the need for additional welding to develop closed cross-sectional parts. However, the low formability of aluminum is a limitation of its application. On the other hand, the ductility of materials can be improved at higher temperatures, and hot metal gas forming has been widely applied in the production of lightweight vehicle parts. In this study, aluminum alloy for pipe extrusion was developed by controlling the Mg:Cr:Mn ratio based on AA5083. Mechanical properties of the developed material were examined by tensile test and were applied to a forming simulation. Cold forming simulation for preforming and non-isothermal hot forming simulation for hot metal gas forming were carried out to validate process conditions. A prototype of the sidemember was manufactured under the given process condition. Finally, thickness distribution was compared with finite element analysis results.

초음파 진동자 응용을 위한 압전 세라믹의 유전 및 전기적 특성 (The Dielectric and Electrical Characteristics of Piezoelectric Ceramic for Ultrasonic Oscillator Application)

  • 이수호;민석규;윤광희;류주현;사공건
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.200-203
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    • 2000
  • The application of the ultrasonic nozzle has been extended because it is possible atomization of liquid material. In this study, the characteristics of the ultrasonic nozzle and ceramic oscillator were investigated. The oscillator for the ultrasonic nozzle were made piezoelectric ceramic of Pb[($Sb_{1/2}$ $Nb_{1/2}$)$_{0.035}$-($Mn_{1/3}$$Nb_{2/3}$)$_{0.065}$-($Zr_{0.49}$$Ti_{0.51}$)$_{0.90}$]$O_3$. The electromechanical coupling factor($k_p$) and mechanical quality factor(Qm) showed the values of 0.555, 1, 214 respectively when the Zr/Ti ratio was 49/51. Moreover, this oscillator will have the temperature stability because it's curie temperature is 322[$^{\circ}C$]. The driving current of ultrasonic nozzle showed the value of 80[mA] when the driving time was lO[min.]. Also, The surface temperature of ceramic oscillator showed 80[$^{\circ}C$] at driving time lO[min.] We knew that the ultrasonic nozzle had stabile driving above 10[min.].

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황토, 갯벌 및 머드의 중금속 흡착율에 관한 실험적 연구 (An Experimental Study on the Adsorption rates of Heavy Metals by Yellow Loess, Tidal Plat Sediment and Mud)

  • 이인숙;이미영;이택중;김현정;이병창;정명상;방은옥;송현실;황혜경;이중호;조영채
    • 환경위생공학
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    • 제19권2호
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    • pp.15-22
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    • 2004
  • Yellow loess, Tidal plat sediment, and mud are blown to be high in adsorption though they have great distinction according to the ratio of clay minerals content and their kinds. Thus one of the samples for this study can be obtained by drying of Yellow loess, Tidal plat sediment, and the mud which is semifinished products that are from the progress of heat treatment and making homogeneity which can be found everywhere in our county. Another sample can be prepared by reducing pollutants with the adsorbent and by homing heavy metals of their on. With the samples, noxious heavy metals such as Pb, Cd, and essential trace elements such as Cu, Fe, Mn by each concentration is tested for adsorption according to pH, the kinds of adsorbents and the amount of injection. With the help of these steps, this study shows that the adsorbents, which are green, reducing the additional pollution and low in price, can be found. It also shows that the optimal condition for removing pollutants can be found and the basic materials for treating water can be offered. The results were as follows ; Yellow loess shows the rates of adsorption by more than 50% and Tidal plat sediment and Mud show it by more than 90%. Thus Tidal plat sediment and Mud are higher than Yellow loess the rates of adsorption. The pH should be treated in natural condition because the rates of adsorption of Pb, Cd, Cu, Mn excepting Fe in mud is higher in pH 7 than in pH 3 of Yellow loess, Tidal plat sediment, and Mud. The drying adsorbents are good to use because the rates of adsorption of heavy metals has tendency to be higher in the drying method than in the burning method. It is considered that the more the mont of the injection of the adsorbent is , the higher the rates of adsorption is, and one gram is reasonable for the amount of the injection of Tidal plat sediment and mud. Yellow loess is suitable for the treatment of the water that includes low concentration of heavy metals because it has the lower rate of adsorption as the concentration of noxious heavy metals is higher. It is thought that Tidal plat sediment and Mud is proper for the treatment of the water that includes high concentration of heavy metals because the rates of adsorption has not been changed as the concentration of heavy metals increases.

CoFe/NiFeSiB/CoFe 자유층을 갖는 이중장벽 자기터널접합의 바이어스전압 의존특성 (Bias Voltage Dependence of Magnetic Tunnel Junctions Comprising Double Barriers and CoFe/NiFeSiB/CoFe Free Layer)

  • 이선영;이장로
    • 한국자기학회지
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    • 제17권3호
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    • pp.120-123
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    • 2007
  • 이 연구에서는 Ta 45/Ru 9.5/IrMn 10/CoFe $3/AlO_x$/자유층/$AlO_x$/CoFe 7/IrMn 10/Ru 60(nm) 구조를 갖는 이중장벽 자기터널접합(double-barrier magnetic tunnel junction: DMTJ)를 다루었다. 자유층은 $Ni_{16}Fe_{62}Si_8B_{14}\;7nm$, $Co_{90}Fe_{10}(fcc)$ 7 nm 및 $CoFet_1$/NiFeSiB $t_2$/CoFe $t_1$으로 구성하였으며 두께 $t_1,\;t_2$는 변화시켰다. 즉 TMR비와 RA를 개선하기 위하여 부분적으로 CoFe층을 대체할 수 있는 비정질 NiFeSiB층이 혼합된 자유층 CoFe/NiFeSiB/CoFe을 갖는 DMTJ를 연구하였다. NiFeSiB($t_1=0,\;t_2=7$)만의 자유층을 갖는 DMTJ는 터널자기저항(TMR)비 28%, 면적-저항곱(RA) $86k{\Omega}{\mu}m^2$, 보자력($H_c$) 11 Oe 및 층간 결합장($H_i$) 20 Oe를 나타내었다. $t_1=1.5,\;t_2=4$인 경우의 하이브리드 DMTJ는 TMR비 30%, RA $68k{\Omega}{\mu}m^2$$H_c\;11\;Oe$를 가졌으나 $H_i$는 37 Oe로 증가하였다. 원자현미경(AFM)과 투과전자현미경(TEM)측정을 통하여 NiFeSiB층 두께가 감소하면 $H_i$가 증가하는 것을 확인하였다. 비정질 NiFeSiB층이 두꺼워지면 보통 계면의 기복을 유도하는 원주형성장(columnar growth)를 지연시키는데 유효하였다. 그러나 NiFeSiB층이 얇으면 표면거칠기는 증가하고 전자기적 Neel 결합 때문에 Hi는 커졌다.

Effects of Phytase Supplementation on the Performance of Broiler Chickens Fed Maize and Wheat Based Diets with Different Levels of Non-phytate Phosphorus

  • Singh, P.K.;Khatta, V.K.;Thakur, R.S.;Dey, S.;Sangwan, M.L.
    • Asian-Australasian Journal of Animal Sciences
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    • 제16권11호
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    • pp.1642-1649
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    • 2003
  • An experiment was conducted to evaluate the effects of phytase supplementation on the growth performance, nutrients utilization and bone mineralization in broiler chickens. Day-old broiler chicks (n=480) were equally devided into eight treatment groups and fed maize or wheat based isocaloric, isonitrogenous and isocalcium diets having two non phytate phosphorus (NPP) concentrations (0.50% and 0.30%) and two phytase levels (0 and 500 phytase units/kg diet) in a 42 days growth trial. Maize based dietary treatments were MC (NPP 0.50%, MN (NPP 0.30%), MNP (MN+500 units of phytase) and MCP (MC+500 units of phytase), whereas wheat based experimental diets were WC (NPP 0.50%), WN (NPP 0.30%), WNP (WN+500 units of phytase) and WCP (WC+500 units of phytase). The NPP levels were maintained by dicalcium phosphate. Reduction in dietary NPP depressed live weight gain and feed intake and increased feed conversion ratio (FCR). Phytase supplementation to low NPP (0.30%) diets significantly (p<0.05) improved the growth performances of broilers. The supplementation to low NPP diets allowed complete, safe and economic replacement of dietary inorganic P (dicalcium phosphate) to reduce feed cost per kg live weight gain of broilers. Reduction in dietary NPP did not affect retention of nutrients except phosphorus (P) but had a significant (p<0.05) depression in tibia ash and minerals (Ca, P) concentration in serum and tibia ash. Phytase supplementation at low NPP level was effective (p<0.05) in improving the retention of dry matter, Ca and P and Ca and P concentration in serum and tibia ash. However, the supplementation was not effective at high level of NPP (0.50%). There were no significant (p>0.05) differences in carcass quality among dietary treatments. The response of phytase was greater in low NPP and maize based diets as compared with high NPP and wheat based diets, respectively. The results show that phytase supplementation to low NPP (0.30%) diets improved the growth performance, relative retention of nutrients (N, Ca and P) and minerals (Ca, P) status of blood and bone in broiler chickens, with a better efficacy in maize based diets.

육계에서 사료내 황토 첨가가 성장 및 체조성에 미치는 영향 (Effects of Dietary Yellow Clay on Growth Performance and Body Composition in Broiler Chicks)

  • 양철주;오종일;최연재;김정빈;문승태;한승관
    • 한국가금학회지
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    • 제33권4호
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    • pp.263-271
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    • 2006
  • 본 연구는 황토의 첨가가 육계의 성장, 사료 이용율, 체조성, 장기의 무게 및 분중 암모니아 생산에 미치는 영향에 대하여 연구하였다. 공시동물은 Ross broiler 216수로 6처리 6반복 반복당 6수씩 사양 시험을 실시하였다. 처리구는 1) 대조구, 2) 황토 0.5% 첨가구, 3) 황토 1.0% 첨가구, 4) 황토 2.0% 첨가구, 5) 황토 4.0% 첨가구, 6) 황토 8.0% 첨가구로 총 6처리로 나누어 실시하였다. 증체량은 황토의 첨가 수준이 증가할수록 감소하는 경향을 보였다(P<0.05). 하지만 사료 섭취량과 사료 요구율은 황토 첨가구와 대조구에서 통계적인 유의차를 보이지 않았다. 산패도는 황토 첨가구와 대조구에서 통계적인 유의차를 보이지 않았다. (P>0.05). 도체내 콜레스테롤 함량은 대조구보다 황토 첨가구에서 감소하는 경향을 보였으며, 통계적인 유의차를 보였다(P<0.05). 암모니아가스 농도를 측정한 결과 평균 농도는 대조구에 비해서 황토 첨가구의 농도가 전체적으로 모두 감소하였다.(P<0.05). 광물질 분석에서 Mn 함량은 황토 8.0% 첨가구가 대조구보다 높은 수치를 보였으며, 통계적인 유의차를 보였다.(P<0.05). 대장의 무게는 황토 2.0, 4.0 및 8.0% 첨가구에서 감소하였으며, 통계적인 유의차를 보였다.(P<0.05). 본 연구를 통하여 황토를 소량 첨가하였을 경우 증체율 개선 효과를 보였으며, 분중 암모니아 가스 농도가 대조구보다 현저히 낮아 사료 첨가제로서의 가능성을 보였다.

XRF (X-ray fluorescence)를 활용한 고온환경에 노출된 시멘트 페이스트 분석의 이해 (Quantitative Analysis of X-Ray Fluorescence for Understanding the Effect of Elevated Temperatures on Cement Pastes)

  • 전길송;허영선
    • 한국구조물진단유지관리공학회 논문집
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    • 제27권6호
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    • pp.130-137
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    • 2023
  • 본 연구는 XRF 장비를 활용하여 고온조건에 노출된 시멘트 페이스트의 화학적 특성변화에 대한 연구를 진행하였다. 고온조건은 전기가열로를 이용하여 상온에서 1000도까지 총 11개의 목표온도를 계획하여 진행하였고, Geo-quant basic 표준 라이브러리를 이용하여 Ca, Si, Al, Fe, S, Mg, Ti, Sr, P, Mn, Zn, K 등 12종의 원소를 분석 대상으로 하였다. 실험 결과 피해온도가 증가할수록 시멘트페이스트를 구성하고 있는 각 원소의 비율이 증가하는 것으로 나타났다. 극히 일부의 미량 원소를 제외하고, 대부분의 원소 구성비율은 피해온도와 높은 상관성을 나타냈는데, R-squared 값 0.98 이상을 나타내었다. 본 연구에서는 100% 정규화 기능을 사용하지 않고 XRF 장비를 이용하여 일반환경과 고온 환경에 노출된 시멘트페이스트를 비교 분석하였는데, 결과의 차이가 발생한 이유에 대해서 일반 시멘트 원재료와 시멘트페이스트를 비교하였을 때 차이가 발생한 이유와 동일한 측면에서 설명하였다. 또한, 이를 통해 XRF 장비를 활용하여 시멘트페이스트를 분석할 때 잠재적으로 가장 중요한 영향인자에 대해 논의하였다.

도토리 전분 겔의 텍스쳐와 노화에 미치는 당류의 영향 (Effect of Saccharides on Texture and Retrogradation of Acorn Starch gels)

  • 이향애;김남희
    • 한국식품과학회지
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    • 제30권4호
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    • pp.803-810
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    • 1998
  • 도토리 전분의 노화에 대한 sucrose 영향을 관찰하기 위해서 기계적 성질과 열적 성질을 조사하였다. 정제 전분의 수분과 아밀로오스 함량은 각각 9.35%, 27%였다. 정제 전분의 중량 평균 분자량과 수 평균 분자량은 각각 $1.22{\times}10^6$$1.37{\times}10^5$이였고 다분산도는 8.90으로 아밀로오스, 아밀로펙틴 보다 높아서 도토리 전분은 불균일계임을 알 수 있었다. Creep 실험으로부터 sucrose 첨가 겔의 creep compliance는 저장 초기에는 sucrose 농도가 증가할수록 감소하였는데 이는 전분, sucrose와 전분내의 자유수와의 상호 작용에 의한 수소결합 형성에 기인한다. DSC 흡열곡선으로부터 호화온도와 엔탈피는 sucrose 농도가 증가할수록 증가하였다. 저장 후기에는 creep compliance가 농도가 증가할수록 증가하여 sucrose는 겔의 softness를 증가시킨다고 볼 수 있으며 재호화 엔탈피는 sucrose 농도가 증가하면 감소하였다. 호화 엔탈피와 재호화 엔탈피로부터 노화비율을 구하였고, sucorse 농도가 증가하면 노화비율은 감소하였다. 기계적 성질과 열적 성질 측정으로부터 sucrose는 도토리 전분의 호화와 노화를 지연시키는 작용을 함을 알 수 있었다.

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Detailed Abundance Analysis for Plant Host Stars

  • 강원석;이상각;김강민
    • 천문학회보
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    • 제36권1호
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    • pp.27.1-27.1
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    • 2011
  • We obtained the spectra of 93 Planet host stars and 73 normal field stars in F, G, K type using BOES at BOAO. We measured the equivalent width of Fe and 25 elements lines using the automatic EW measurement program, TAME(Tools for Automatic Measurement of Equivalent-widths) and estimated the elemental abundances by synth and abfind driver of MOOG code. Since the absence of planets in the normal field stars cannot be "completely" proved, this work focused on the chemical abundances and planet properties of planet host stars, which have the massive planets close to the parent star relatively. We carried out an investigation for the difference of abundances between stars with "Hot Jupiter" and normal field stars with no known planets. We examined the chemical composition of 25 elements, such as C, N, O, S, Na, Mg, Al, Si, K, Ca, Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Sr, Y, Zr, Ba, Ce, Nd, and Eu by EW measurements, and the S abundances were estimated using synthetic spectrum. We have found that [Mg/Fe] and [Al/Fe] for planet host stars have lower limit comparing with those of comparison stars, and [Ca/Fe] of host star with Neptunian planets is relatively lower than the other host stars with massive planets. We have performed the Kolmogorov-Smirnov test, and examined the ratio of planet host stars to all stars for each bin of [X/H]. As a result, we noted that the O, Si, and Ca abfor undances are strongly related with the presence of planets.

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