• 제목/요약/키워드: Mixture Gases

검색결과 313건 처리시간 0.021초

초고속 Marx Generator의 N2, SF6, N2-SF6 혼합가스에 따른 출력 특성 연구 (Ultra fast Marx Generator of N2, SF6, N2-SF6 Mixture Gas based on Research Output Characteristics)

  • 두진석;한승문;허창수;최진수
    • 전기학회논문지
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    • 제59권10호
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    • pp.1850-1855
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    • 2010
  • The application field of the pulse power is very wide. Recently, Pulse power technologies take a large place in several applications. Then, many civil and military applications proceed. Marx generator is widely used in high voltage applications. Marx generator is widely used in high voltage applications, such as eletromagnetic wave and power lasers. This paper, we described about the high voltage pulse generator. A compact size high voltage pulse generator with nanosecnd rise time has been fabricated and investigated experimentally. The marx generator has 2 stages. Each stage was constructed one charging capacitor, two electrodes and one charging resistor. A inductance structure is used in order to improve the switching performances fo the whole generator. The experiments of rise time in pure gas and mixtures of gases were described. We tested the Marx generator at different insulation gas. the results show that the dielectric strength of the $N_2-SF_6$ mixture was significantly increased compared with pure nitrogen gas. The experimental results show that the rise time characteristics of the Marx generator can be controlled through varying insulation gas.

평편한 튜브의 입구 영역에서의 비회복사 (Non-gray Radiation in the Entrance Region of a Smooth Tube)

  • 서태범
    • 태양에너지
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    • 제15권3호
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    • pp.91-103
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    • 1995
  • 튜브 내의 입구영역에서 대류와 비회복사(mon-gray radiation)가 동시에 일어날 때의 열전달 특성을 수치해석적으로 연구하였다. 작동유체는 이산화탄소, 수증기, 질소의 혼합가스라 하였고, 유동은 속도장과 온도장이 동시에 발달하는 층류 유동으로 가정하였다. 복사전달방정식을 풀기 편하게 하기 위해 P-1 근사법이 사용되었고 혼합가스의 비회흡수계수(non-gray sbsorption coefficient)는 지수광폭밴드모형(exponential wide band model)을 이용해서 구하였다. 열전달 특성에 대한 온도조건의 영향을 조사하기 위해 튜브의 축방향에 대한 평균온도와 뉴셀트수(Nusselt number)의 변화를 몇 가지 다른 온도조건에 대해 나타내었다. 속도장과 온도장이 동시에 발달하는 경우의 뉴셀트수를 속도장은 완전히 발달되어 있고 온도장만 발달하는 경우의 뉴셀트 수와 비교하였다. 또한, 가스의 성분조성이 대류와 비회복사 뉴셀트수에 미치는 영향을 조사하였다.

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토치형 상압 플라즈마의 방전특성과 미생물의 국부 살균효과 (Discharge Properties of Torch-Type Atmospheric Pressure Plasma and Its Local Disinfection of Microorganism)

  • 손향호;이원규
    • Korean Chemical Engineering Research
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    • 제49권6호
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    • pp.835-839
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    • 2011
  • 토치형 상압 플라즈마 반응기를 통한 방전 및 플라즈마 flame에 대한 분석과 발생된 플라즈마 현상을 이용하여 E. coli에 대한 살균효과를 측정하였다. 상압 플라즈마 반응기를 통해 나오는 플라즈마 flame의 길이는 입력전압, 반응기의 유량 그리고 아르곤/산소 혼합기체에서의 산소비율에 영향을 크게 받았다. 플라즈마 flame에 의한 가열효과는 10분 조사 후에도 $43^{\circ}C$ 미만으로 저온처리가 가능했다. E. coli에 대한 살균처리에서 입력전압의 증가, 아르곤/산소 혼합기체에서의 산소비율 증가 그리고 플라즈마 flame에 대한 노출시간의 증가에 따라 전체적인 살균효과를 향상되었다. 플라즈마 처리 시에 오존농도가 높은 공정조건에서 플라즈마 flame의 직접적인 접촉시간을 증가시키면 살균효과를 극대화할 수 있다.

Effect of H2 on Formation Behavior of Carbon Nanotubes

  • Chung, Uoo-Chang
    • Bulletin of the Korean Chemical Society
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    • 제25권10호
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    • pp.1521-1524
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    • 2004
  • The effect of $H_2$ gas on the carbon nanotubes (CNTs) synthesis with CO-$H_2$ gas mixture was investigated using mass measurements and scanning electron microscopy (SEM). The maximum weight and yield of the synthesized carbon were obtained when the mixture ratio of $H_2$: CO was 3 : 7 and 9 : 1, respectively. In case of 100% carbon monoxide (CO) without hydrogen ($H_2$) addition, the weight of carbon increased, but CNTs were not observed. The CNTs began to be made when the contents of $H_2$ reaches at least 10%, their structures became more distinct with an increase of $H_2$ addition, and then the shapes of CNTs were more thin and straight. When the contents of $H_2$ was 80% ($H_2$ : CO = 8 : 2), the shapes and growth of CNTs showed an optimal condition. On the other hand, when the contents of $H_2$ was higher than the critical value, the shapes of CNTs became worse due to transition into inactive surface of catalyst. It was considered that the inactive surface of catalyst resulted from decrease of carbon (C) and $H_2$ concentration by facilitation of methane ($CH_4$) gasification reaction (C + 2$H_2$ ${\rightarrow}$ $CH_4$) between C and $H_2$ gases. It was also found that H2 addition had an influence considerably on the shape and structure of CNTs.

Analysis on Temperature Distribution and Current-Carrying Capacity of GIL Filled with Fluoronitriles-CO2 Gas Mixture

  • Chen, Geng;Tu, Youping;Wang, Cong;Cheng, Yi;Jiang, Han;Zhou, Hongyang;Jin, Hua
    • Journal of Electrical Engineering and Technology
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    • 제13권6호
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    • pp.2402-2411
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    • 2018
  • Fluoronitriles-$CO_2$ gas mixtures are promising alternatives to $SF_6$ in environmentally-friendly gas-insulated transmission lines (GILs). Insulating gas heat transfer characteristics are of major significance for the current-carrying capacity design and operational state monitoring of GILs. In this paper, a three-dimensional calculation model was established for a GIL using the thermal-fluid coupled finite element method. The calculated results showed close agreement with experimentally measured data. The temperature distribution of a GIL filled with the Fluoronitriles-$CO_2$ mixture was obtained and compared with those of GILs filled with $CO_2$ and $SF_6$. Furthermore, the effects of the mixture ratio of the component gases and the gas pressure on the temperature rise and current-carrying capacity of the GIL were analyzed. Results indicated that the heat transfer performance of the Fluoronitriles-$CO_2$ gas mixture was better than that of $CO_2$ but worse than that of $SF_6$. When compared with $SF_6$, use of the Fluoronitriles-$CO_2$ gas mixture caused a reduction in the GIL's current-carrying capacity. In addition, increasing the Fluoronitriles gas component ratio or increasing the pressure of the insulating gas mixture could improve the heat dissipation and current-carrying capacity of the GIL. These research results can be used to design environmentally-friendly GILs containing Fluoronitriles-$CO_2$ gas mixtures.

직접접촉식 응축기를 통한 가압순산소 연소 배가스 내 SOx, NOx 동시저감 연구 (Simultaneous Removal of SOx and NOx in Flue Gas of Oxy-fuel Combustion by Direct Contact Condenser)

  • 최솔비;목진성;양원;류창국;최석천
    • 청정기술
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    • 제25권3호
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    • pp.245-255
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    • 2019
  • 가압순산소 연소는 발전 공정의 온실가스 포집 기술의 하나로서, $CO_2$의 압축 전 단계에 FGC (Flue gas condensor)를 통해 배가스 내 수분의 잠열을 회수하여 효율을 높일 수 있다. 또한 FGC는 가스의 용해도를 이용하여 $SO_x$$NO_x$를 동시에 효과적으로 제거할 수 있는 장점이 있다. 이 연구에서는 FGC의 방식 중 하나로서 직접 접촉식 응축기를 고안하여 $SO_x$$NO_x$의 저감율을 평가하였다. 특히 가스가 물에 직접 통과할 때 용해를 통한 저감효율을 측정하기 위해 단독가스와 혼합가스로 분리하여 상압에서 10 bar까지의 압력조건을 변수로 실험을 진행하였다. 단독 가스 실험결과 $NO_x$는 상압에서 저감율이 약 20%, 10 bar 압력조건에서 약 76%로 크게 증가하였다. 또한 $SO_2$는 높은 용해도로 전량이 용해하여 초기 저감율에 큰 차이가 나타나지 않았으나, 압력이 증가할수록 최고 저감율이 유지되는 시간이 증가하였다. 동시저감 실험 결과 상압에서 $NO_x$의 저감율은 13%이나, 압력이 상승할수록 헨리법칙에 의한 용해도 증가에 따라 20 bar에서 56%로 증가하였다. $SO_2$는 초기에 다량 용해된 후 다시 배출 농도가 증가하는 폭이 상압에서는 1,219 ppm, 20 bar에서는 165 ppm으로 감소하였다. 결론적으로 $NO_x$$SO_x$ 모두 압력이 높아질수록 저감율이 증가하였으나, 단독가스 실험과 비교하면 저감율이 감소함을 확인하였다. 이는 혼합가스 투입으로 인해 반응기 내부에 채운 물의 산성화가 빠르게 이루어졌기 때문이다.

PEMOCVD of Ti(C,N) Thin Films on D2 Steel and Si(100) Substrates at Low Growth Temperatures

  • Kim, Myung-Chan;Heo, Cheol-Ho;Boo, Jin-Hyo;Cho,Yong-Ki;Han, Jeon-Geon
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1999년도 제17회 학술발표회 논문개요집
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    • pp.211-211
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    • 1999
  • Titanium nitride (TiN) thin films have useful properties including high hardness, good electrical conductivity, high melting point, and chemical inertness. The applications have included wear-resistant hard coatings on machine tools and bearings, decorative coating making use of the golden color, thermal control coatings for widows, and erosion resistant coatings for spacecraft plasma probes. For all these applications as feature sizes shrink and aspect ratios grow, the issue of good step coverage becomes increasingly important. It is therefore essential to manufacture conformal coatings of TiN. The growth of TiN thin films by chemical vapor deposition (CVD) is of great interest for achieving conformal deposition. The most widely used precursor for TiN is TiCl4 and NH3. However, chlorine impurity in the as-grown films and relatively high deposition temperature (>$600^{\circ}C$) are considered major drawbacks from actual device fabrication. To overcome these problems, recently, MOCVD processes including plasma assisted have been suggested. In this study, therefore, we have doposited Ti(C, N) thin films on Si(100) and D2 steel substrates in the temperature range of 150-30$0^{\circ}C$ using tetrakis diethylamido titanium (TDEAT) and titanium isopropoxide (TIP) by pulsed DC plamsa enhanced metal-organic chemical vapor deposition (PEMOCVD) method. Polycrystalline Ti(C, N) thin films were successfully grown on either D2 steel or Si(100) surfaces at temperature as low as 15$0^{\circ}C$. Compositions of the as-grown films were determined with XPS and RBS. From XPS analysis, thin films of Ti(C, N) with low oxygen concentration were obtained. RBS data were also confirmed the changes of stoichiometry and microhardness of our films. Radical formation and ionization behaviors in plasma are analyzed by optical emission spectroscopy (OES) at various pulsed bias and gases conditions. H2 and He+H2 gases are used as carrier gases to compare plasma parameter and the effect of N2 and NH3 gases as reactive gas is also evaluated in reduction of C content of the films. In this study, we fond that He and H2 mixture gas is very effective in enhancing ionization of radicals, especially N resulting is high hardness. The higher hardness of film is obtained to be ca. 1700 HK 0.01 but it depends on gas species and bias voltage. The proper process is evident for H and N2 gas atmosphere and bias voltage of 600V. However, NH3 gas highly reduces formation of CN radical, thereby decreasing C content of Ti(C, N) thin films in a great deal. Compared to PVD TiN films, the Ti(C, N) film grown by PEMOCVD has very good conformability; the step coverage exceeds 85% with an aspect ratio of more than 3.

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폐타이어 열분해에 의한 카본블랙을 이용한 황화수소와 암모니아 제거를 위한 흡착제 개발 (Development of Adsorbents for Removal of Hydrogen Sulfide and Ammonia Using Carbon Black from Pyrolysis of Waste Tires)

  • 서양곤;김창준;김대혁
    • 청정기술
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    • 제21권2호
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    • pp.108-116
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    • 2015
  • 황화수소와 암모니아는 많은 하수처리장과 산업 플랜트로부터의 배출가스에서 발견되어질 수 있는 가장 흔한 악취성분이다. 이들 유해물질들은 인간에게 건강 문제를 일으키고 촉매에 악영향을 미치기 때문에 생활환경과 산업 현장에서의 제거는 매우 중요하다. 본 연구에서는 황화수소와 암모니아에 대한 우수한 흡착능력을 가지는 흡착제를 개발하기 위하여 폐타이어의 열분해 생성물인 카본블랙을 이용하였다. 카본블랙, 금속산화물과 산 또는 염기를 혼합하여 펠렛형 흡착제를 제조하였고, 상온상압에서 고정층 흡착탑의 파과곡선을 이용하여 황화수소와 암모니아에 대한 흡착성능을 평가하였다. 카본블랙, 산화철(III)과 수산화나트륨 혼합물로 제조된 흡착제가 황화수소에 대한 가장 우수한 작업능력을 나타내었다. 암모니아에 대해서는 카본블랙, 산화구리(II), 염산의 혼합물로 제조된 흡착제가 우수한 작업능력을 보였다.

분사각 및 분공 직경이 예혼합 압축착화 엔진 연소에 미치는 영향 (The Effect of Injection Angle and Nozzle Diameter on HCCI Combustion)

  • 국상훈;공장식;박세익;배충식;김장헌
    • 한국자동차공학회논문집
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    • 제15권2호
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    • pp.1-7
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    • 2007
  • The effect of injector geometries including the injection angle and number of nozzle holes on homogeneous charge compression ignition (HCCI) engine combustion has been investigated in an automotive-size single-cylinder diesel engine. The HCCI engine has advantages of simultaneous reduction of PM and NOx emissions by achieving the spatially homogenous distribution of diesel fuel and air mixture, which results in no fuel-rich zones and low combustion temperature. To make homogeneous mixture in a direct-injection diesel engine, the fuel is injected at early timing. The early injection guarantees long ignition delay period resulting in long mixing period to form a homogeneous mixture. The wall-impingement of the diesel spray is a serious problem in this type of application. The impingement occurs due to the low in-cylinder density and temperature as the spray penetrates too deep into the combustion chamber. A hole-type injector (5 holes) with smaller angle ($100^{\circ}$) than the conventional one ($150^{\circ}$) was applied to resolve this problem. The multi-hole injector (14 holes) was also tested to maximize the atomization of diesel fuel. The macroscopic spray structure was visualized in a spray chamber, and the spray penetration was analyzed. Moreover, the effect of injector geometries on the power output and exhaust gases was tested in a single-cylinder diesel engine. Results showed that the small injection angle minimizes the wall-impingement of diesel fuel that results in high power output and low PM emission. The multi-hole injector could not decrease the spray penetration at low in-cylinder pressure and temperature, but still showed the advantages in atomization and premixing.

자동차용 강판의 MAG 용접시 최적용접조건 선정에 관한 연구 (A Study on the Prediction of the Optimal Welding Condition for Automotive Steel Sheets in MAG Welding Process)

  • 방한서;방희선;주성민;노찬승;성보람;석한길
    • Journal of Welding and Joining
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    • 제27권3호
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    • pp.38-43
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    • 2009
  • The optimization of the welding parameters was studied to maximize the weldability and minimize the amount of spatter in the MAG welding of automotive steel sheets under different shielding gas composition ratio. JS-EFSC, JS-SPHC steel plates and Ar mixture gases were used as a substrate and shielding gas for welding respectively. The five welding parameters were selected through preliminary experiments and their effects on the weldability were analyzed. Experiments were performed using the Taguchi experimental method. As results, appropriate range for welding could be achieved. Amount of spatter in 80%Ar+20%$CO_2$ shielding gas was 20% of that of $CO_2$welding. Therefore, in terms of high productivity and welding cost, Ar mixture gas(80%Ar+20%$CO_2$) was recommended as a shielding gas for application of MAG process, indicating the low spatter and good weld quality.