• 제목/요약/키워드: Mixture Electrode

검색결과 248건 처리시간 0.026초

High Xe-content PDP

  • Oversluizen, G.;Dekker, T.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.55-58
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    • 2004
  • High Xe-content PDP characteristics are discussed. A high efficacy, up to 5 lm/W for a 50% Xe in Ne gas mixture, is realized in 4-inch color PDP test panel designs with low cost stripe-type barrier rib structures, that are powder blasted in soda lime glass. Furthermore, for a high Xe-content a high luminance can be obtained with a relatively small electrode area. Therefore the inter cell gap and the driving margin can be increased in a stripe-type barrier rib structure. Finally, for a high Xe-content the panel lifetime increases, due to increasing luminance and firing voltage stability. Clearly, these findings may direct the design development for next generation PDPs towards a high Xe-content

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방전여기 KrF 엑사이머 레이저의 에비전리 영향에 관한연구 (A Study on preionization effect of discharge excited KrF excimer laser)

  • 김상욱;최부연;이주희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1990년도 하계학술대회 논문집
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    • pp.459-461
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    • 1990
  • Me performed an experiment about preionization electron number density of charge transfer type KrF excimer laser. At the total pressure of 1.8 and 2.2 atm with helium (He) buffer gas, the experimental range of the electron number density is 8-9 ${\times}$ 10 cm The distance between electrode and preionization pin is 15 mJ at charging voltage of 27kV,gas pressure of 2.2 atm,gas mixture of F /Kr/He = 0.3/396.7(%).

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리튬 2차전지용 $LiCoO_2$양극의 제조 및 특성 (Preparation and properties of $LiCoO_2$ cathode for Li rechargeable cell)

  • 문성인;정의덕;도칠훈;윤문수
    • E2M - 전기 전자와 첨단 소재
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    • 제7권4호
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    • pp.317-324
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    • 1994
  • In this study, new preparation method of LiCoO$_{2}$ was applied to develop cathode active material for Li rechargeable cell, and followed by X-ray diffraction analysis, electrochemical properties and initial charge/discharge characteristics as function of current density. HC8A72- and CC9A24-LiCoO$_{2}$ were prepared by heating treatment of the mixture of LiOH H$_{2}$O/CoCO$_{3}$(1:1 mole ratio) and the mixture of Li$_{2}$CO$_{3}$/CoCO$_{3}$(1:2 mole ratio) at 850 and 900.deg. C, respectively. Two prepared LiCoO$_{2}$s were identified as same structure by X-ray diffraction analysis. a and c lattice constant were 2.816.angs. and 14.046.angs., respectively. The electrochemical potential of CFM-LiCoO$_{2}$(Cyprus Foote Mineral Co.'s product), HC8A72-LiCoO$_{2}$ and CC9A24 LiCoO$_{2}$ electrode were approximately between 3.32V and 3.42V vs. Li/Li reference electrode. Stable cycling behavior was obtained during the cyclic voltammetry of LiCoO$_{2}$ electrode. According as scan rate increases, cathodic capacity decreases, but redox coulombic efficiency was about 100% at potential range between 3.6V and 4.2V vs. Li/Li reference electrode. Cathodic capacity of HC8A72-LiCoO$_{2}$ was 32% higher than that of CFM-LiCoO$_{2}$ and that of CC9A24-LiCoO$_{2}$ was 47% lower than that of CFM-LiCoO$_{2}$ at 130th cycle in the condition of lmV/sec scan rate. Constant cur-rent charge/discharge characteristics of LiCoO$_{2}$/Li cell showed increasing Ah efficiency with initial charge/discharge cycle. Specific discharge capacities of CFM and HC8A72-LiCoO$_{2}$ cathode active materials were about 93mAh/g correspondent to 34% of theretical value, 110mAh/g correspondent to 40% of theretical value, respectively. In the view of reversibility, HC8A72-LiCoO$_{2}$ was also more excellent than CFM- and CC9A24-LiCoO$_{2}$.

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Characterization of Water-Filled Ag/AgCl Reference Electrode

  • Bahn Chi Bum;Oh Sihyoung;Hwang Il Soon;Chung Hahn Sup;Jegarl Sung
    • 전기화학회지
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    • 제4권3호
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    • pp.87-93
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    • 2001
  • 외부 Ag/AgCl 기준 전극은 가압형 및 비등형 경수로 환경에 널리 사용되었다. 전극의 채움 용액 (Siting solution)으로 통상 KCl을 사용하는데, 다공성 지르코니아로 만들어지는 플러그를 통한 Cl 이온의 누설이 전극의 전위차 변동을 유발하는 문제가 있다. 누설로 인한 전위차 변동의 문제를 해결하기 위해 채움 용액으로 순수를 사용하였다 순수를 사용하는 경우 상온에서의 AgCl용해도에 의해 Cl이온의 농도가 결정된다. 붕산과 수산화리튬 혼합용액으로 $288^{\circ}C$에서 전극의 안정성 실험을 실시하였다. 약 일주일간 전위차 변화는 10mV 이내였으며, $288^{\circ}C$$240^{\circ}C$에서의 온도 사이클링 시험 전후의 전위차 변화는 15mV 이내였다. 이온의 limiting equivalent conductances와 Agar의 수역학적 이론을 토대로 하여 전극의 TLJP을 계산하였다. 전극 채움 용액 내의 Cl이온 농도를 상온에서 측정한 값으로 보정하여 이론값을 계산할 경우, 실험값과 비교적 잘 일치하는 것을 알 수 있었다.

Sphingomyelin과 Polyamic Acid의 농도 변화에 대한 단분자 LB막의 전기화학적 특성에 관한 연구 (A Study on the Electrochemical Properties of Langmuir-Blodgett Monolayer Film for the Changes of Concentration with Polyamic Acid and Sphingomyelin Mixture)

  • 박근호
    • 한국응용과학기술학회지
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    • 제30권4호
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    • pp.754-760
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    • 2013
  • 순환전압전류법에 의한 인지질(sphingomyelin, SP)과 polyamic acid(PAA) 혼합물의 농도(몰비 1:1, 2:1 및 3:1)를 변화시켜 혼합단분자 LB막에 대한 전기화학적 특성을 조사하였다. SP과 PAA 혼합물의 단분자 LB막은 ITO glass에 LB법을 사용하여 제막하였다. 전기화학적 특성은 $KClO_4$ 용액에서 3 전극 시스템으로 측정하였다. 측정 범위는 연속적으로 1650 mV로 산화시키고, 초기 전위인 -1350 mV로 환원시켰다. 주사속도는 각각 50~250 mV/s로 설정하였다. 그 결과 SP와 PAA 혼합물의 LB막은 순환전압전류도표로부터 환원전류로 인한 비가역공정으로 나타났다. 혼합물 LB막의 혼합(SP:PAA) 몰비가 1:1, 2:1 및 3:1에서 확산계수(D)는 각각 $2.670{\times}10^{-5}$, $3.562{\times}10^{-5}$$1.005{\times}10^{-5}cm^2s^{-1}$을 얻었다.

인지질(Sphingomyelin)과 Polyamic Acid 혼합물의 단분자 LB막의 전기화학적 특성에 관한 연구 (A Study on the Electrochemical Properties of Langmuir-Blodgett Monolayer Film Mixed with Polyamic Acid and Sphingomyelin)

  • 박근호
    • 한국응용과학기술학회지
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    • 제30권1호
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    • pp.64-70
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    • 2013
  • 우리는 순환전압전류법에 의한 인지질(sphingomyelin)과 polyamic acid 혼합물의 단분자 LB막에 대한 전기화학적 특성을 조사하였다. Sphingomyelin과 polyamic acid 혼합물의 단분자 LB막은 ITO glass에 LB법을 사용하여 제막하였다. 전기화학적 특성은 $KClO_4$ 용액에서 3 전극 시스템으로 측정하였다. 측정 범위는 연속적으로 1650 mV로 산화시키고, 초기 전위인 -1350 mV로 환원시켰다. 주사속도는 각각 50, 100, 150, 200 및 250 mV/s로 설정하였다. 그 결과 sphingomyelin과 polyamic acid 혼합물의 LB막은 순환전압전류도표로부터 환원전류로 인한 비가역공정으로 나타났다. Sphingomyelin과 polyamic acid 혼합물 LB막에서 전해질농도가 0.1N과 0.2N에서 확산계수(D)는 각각 $2.67cm^2s^{-1}{\times}10^5$$5.23cm^2s^{-1}{\times}10^6$을 얻었다.

링 블로우를 이용한 펄스형 $CO_2$ 레이저 시스템의 효율 향상과 동작 특성에 관한 연구 (A Study on Efficiency Improvement and Optimization of Operating Characteristics of Pulsed $CO_2$ Laser System using Ring Blower)

  • 김도완;정현주;박성준;정종한;이동훈;김희제;조정수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 영호남학술대회 논문집
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    • pp.57-60
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    • 2000
  • In this paper, it is purpose to develop a pulsed $CO_2$ laser with stable output at pulse repetition rate range of 2 KHz. We used a IGBT as a switching device. The laser cavity was fabricated as an axial and water cooled type. It was used a ring blower to increase a cooling effect The laser performance characteristics as parameters, such as pulse repetition rate, gas pressure have been investigated. The experiment was done under 3 electrode-type instead of 2 electrode-type. To achieve 3 electrode-type, we used two pulse-transformers which is operated parallel. As a result, the maximum output was about 28 W at the total pressure of 20 Torr, the gas mixture $Co_2$:$N_2$:He=1:9:15 and the pulse repetition rate of 1300 Hz.

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아르곤 가스의 주입이 붕소 도핑 다이아몬드 전극의 특성에 미치는 효과 (Effect of Argon Addition on Properties of the Boron-Doped Diamond Electrode)

  • 최용선;이영기;김정열;이유기
    • 한국재료학회지
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    • 제28권5호
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    • pp.301-307
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    • 2018
  • A boron-doped diamond(BDD) electrode is attractive for many electrochemical applications due to its distinctive properties: an extremely wide potential window in aqueous and non-aqueous electrolytes, a very low and stable background current and a high resistance to surface fouling. An Ar gas mixture of $H_2$, $CH_4$ and trimethylboron (TMB, 0.1 % $C_3H_9B$ in $H_2$) is used in a hot filament chemical vapor deposition(HFCVD) reactor. The effect of argon addition on quality, structure and electrochemical property is investigated by scanning electron microscope(SEM), X-ray diffraction(XRD) and cyclic voltammetry(CV). In this study, BDD electrodes are manufactured using different $Ar/CH_4$ ratios ($Ar/CH_4$ = 0, 1, 2 and 4). The results of this study show that the diamond grain size decreases with increasing $Ar/CH_4$ ratios. On the other hand, the samples with an $Ar/CH_4$ ratio above 5 fail to produce a BDD electrode. In addition, the BDD electrodes manufactured by introducing different $Ar/CH_4$ ratios result in the most inclined to (111) preferential growth when the $Ar/CH_4$ ratio is 2. It is also noted that the electrochemical properties of the BDD electrode improve with the process of adding argon.

지방산과 인지질 혼합 LB막의 전기화학적 특성 (The Electrochemical Characterization of Mixture LB Films of Fatty Acid and Phospholipids)

  • 손태철;김남석;박근호
    • 한국응용과학기술학회지
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    • 제20권2호
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    • pp.94-100
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    • 2003
  • We studied electrochemical characteristics of Langmuir-Blodgett(LB) films by using cyclic voltammetry with a three-electrode system. An Ag/AgCl as a reference electrode, a platinum wire as a counter electrode and LB film-coated indium tin oxide(ITO) as a working electrode were used to study electrochemical characteristics at a various concentration of $NaClO_4$ solution. LB films were reduced from initial potential to -1350 mV, continuously oxidized to l650mV and returned to the initial point. The scan rate was l00mV/s. The monolayer surface morphology of the LB film have been measured by Atomic Force Microscope(AFM). As a result, We comfirmed that the microscopic properties of LB film by AFM showed the good orientation of momolayer molecules and the thickness of monolayer was 3.5-4.lnm. The cyclic voltammograms(CV) of the ITO-coated glass showed the peak potentials for the reduction-oxidation reation. LB films of 4-octyl-4'-(5-carboxypentamethyleneoxy) azobenzene(8A5H) / L-${\alpha}$-phosphayidyl choline, dilauroyl(DLPC) seemed to be irreversible process caused by only the oxidation current from the cyclic voltammogram. The current of oxidatation increased at cyclic voltammogram by increasing 8A5H density in LB films. The diffusivity(D) of LB films increased with increasing of a 8A5H amount and was inversely proportional to the concentration of $NaClO_4$ solution.

3전극 방식과 링 블로우를 이용한 펄스형 $CO_2$ 레이저 시스템의 효율 향상과 동작 특성에 관한 연구 (A Study on Efficiency Improvement and Optimization of Operating Characteristics of Pulsed $CO_2$ Laser System using 3 Electrode-type and Ring Blower)

  • 김도완;정현주;박성준;이유수;이동훈;김희제;조정수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 하계학술대회 논문집 C
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    • pp.2101-2103
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    • 2000
  • In this paper, it is purpose to develop a pulsed $CO_2$ laser with stable output at pulse repetition rate range of 2 kHz. We used a IGBT as a switching device. The laser cavity was fabricated as an axial and water cooled type. It was used a ring blower to increase a cooling effect. The laser performance characteristics as parameters, such as pulse repetition rate, gas pressure have been investigated. The experiment was done under 3 electrode-type instead of 2 electrode-type. To achieve 3 electrode-type, we used two pulse-transformers which is operated parallel. As a result. the maximum output was about 28 W at the total pressure, of 20 Torr(the gas mixture $CO_2$:$N_2$:He=1:9:15 and the pulse repetition rate of 1300 Hz).

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