Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
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A Study on the Electrochemical Properties of Langmuir-Blodgett Monolayer Film for the Changes of Concentration with Polyamic Acid and Sphingomyelin Mixture

Sphingomyelin과 Polyamic Acid의 농도 변화에 대한 단분자 LB막의 전기화학적 특성에 관한 연구

  • Park, Keun-Ho (Dept. of Chemical Engineering, Changwon National University)
  • 박근호 (창원대학교 화공시스템공학과)
  • Received : 2013.12.10
  • Accepted : 2013.12.30
  • Published : 2013.12.30
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Abstract

We investigated an electrochemical properties for Langmuir-Blodgett (LB) monolayer films of sphingomyelin(SP) and polyamic acid(PAA) mixture(1:1, 2:1 and 3:1 molar ratio). LB monolayer films of mixture was deposited by the LB method on the indium tin oxide(ITO) glass. The electrochemical properties measured by cyclic voltammetry with three-electrode system in 0.1N $KClO_4$ solution. As a result, LB monolayer films of SP and PAA mixture was appeared on irreversible process caused by the reduction current from the cyclic voltammogram. Diffusion coefficient(D) in the SP and PAA mixture was calculated $2.670{\times}10^{-5}$, $3.562{\times}10^{-5}$ and $1.005{\times}10^{-5}cm^2s^{-1}$ at 1:1, 2:1 and 3:1 molar ratio, respectively.

순환전압전류법에 의한 인지질(sphingomyelin, SP)과 polyamic acid(PAA) 혼합물의 농도(몰비 1:1, 2:1 및 3:1)를 변화시켜 혼합단분자 LB막에 대한 전기화학적 특성을 조사하였다. SP과 PAA 혼합물의 단분자 LB막은 ITO glass에 LB법을 사용하여 제막하였다. 전기화학적 특성은 $KClO_4$ 용액에서 3 전극 시스템으로 측정하였다. 측정 범위는 연속적으로 1650 mV로 산화시키고, 초기 전위인 -1350 mV로 환원시켰다. 주사속도는 각각 50~250 mV/s로 설정하였다. 그 결과 SP와 PAA 혼합물의 LB막은 순환전압전류도표로부터 환원전류로 인한 비가역공정으로 나타났다. 혼합물 LB막의 혼합(SP:PAA) 몰비가 1:1, 2:1 및 3:1에서 확산계수(D)는 각각 $2.670{\times}10^{-5}$, $3.562{\times}10^{-5}$ 및 $1.005{\times}10^{-5}cm^2s^{-1}$을 얻었다.

Keywords

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