• 제목/요약/키워드: Mixed waste acid

검색결과 78건 처리시간 0.027초

A novel combination of sodium metabisulfite and a chemical mixture based on sodium benzoate, potassium sorbate, and sodium nitrite for aerobic preservation of fruit and vegetable discards and lactic acid fermentation in a total mixed ration for ruminants

  • Ahmadi, Farhad;Lee, Won Hee;Kwak, Wan Sup
    • Animal Bioscience
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    • 제34권9호
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    • pp.1479-1490
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    • 2021
  • Objective: Our recent findings confirmed the effectiveness of sodium metabisulfite (SMB) in controlling the growth of undesirable microorganisms in fruit and vegetable discards (FVD); however, lactic acid bacteria (LAB) are susceptible to its antibacterial effects. Two series of experiments were conducted to enable the survivability of LAB during silage fermentation of a total mixed ration (TMR) containing SMB-treated FVD. Methods: In Exp. 1, the objective was to isolate a strain of LAB tolerable to the toxic effect of SMB. In Exp. 2, the SMB load was minimized through its partial replacement with a chemical mixture (CM) based on sodium benzoate (57%), potassium sorbate (29%), and sodium nitrite (14%). FVD was treated with SMB + CM (2 g each/kg biomass) and added to the TMR at varying levels (0%, 10%, or 20%), with or without KU18 inoculation. Results: The KU18 was screened as a presumptive LAB strain showing superior tolerance to SMB in broth medium, and was identified at the molecular level using 16S rRNA gene sequence analysis as Lactobacillus plantarum. Inoculation of KU18 in TMR containing SMB was not successful for the LAB development, biomass acidification, and organoleptic properties of the resultant silage. In Exp. 2, based on the effectiveness and economic considerations, an equal proportion of SMB and CM (2 g each/kg FVD) was selected as the optimal loads for the subsequent silage fermentation experiment. Slight differences were determined in LAB development, biomass acidification, and sensorial characteristics among the experimental silages, suggesting the low toxicity of the preservatives on LAB growth. Conclusion: Although KU18 strain was not able to efficiently develop in silage mass containing SMB-treated FVD, the partial substitution of SMB load with the CM effectively alleviated the toxic effect of SMB and allowed LAB development during the fermentation of SMB + CM-treated FVD in TMR.

Potential of Sarson Saag Waste-a Cannery Waste as Ruminant Feed

  • Bakshi, M.P.S.;Kaushal, S.;Wadhwa, M.
    • Asian-Australasian Journal of Animal Sciences
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    • 제18권4호
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    • pp.479-482
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    • 2005
  • The nutritional worth of Sarson Saag Waste (SSW), a cannery waste, was assessed in comparison with conventional complete diet as a total mixed ration (TMR), and a conventional green fodder, Avena sativa. Each diet was offered ad libitum, supplemented with mineral mixture and common salt, to 4 male murrah buffaloes. The control TMR was made iso-nitrogenous to SSW. Simultaneously, each diet was offered to 3 rumen fistulated male buffaloes for assessing the biochemical changes in the rumen. The nutrient digestibility of unconventional SSW was comparable to that of conventional green fodder-A. sativa but significantly (p<0.05) higher than that of control TMR. The tri-chloro acetic acid (TCA) precipitable-N in the strained rumen liquor of animals fed SSW was considerably higher than that of animals fed A.sativa. The urinary excretion of total purine derivatives was comparable in animals fed SSW and conventional green fodder but significantly (p<0.05) higher than those fed conventional control TMR. The significantly (p<0.05) lower purine nitrogen index (PNI) in animals fed control TMR resulted in significantly (p<0.05) lower microbial protein synthesis than that in animals fed SSW and conventional green fodder. The N-excretion as per cent of nitrogen intake was significantly (p<0.05) lower in animals fed SSW as compared to either of the conventional feeds tested, resulting in significantly (p<0.05) higher Nretention and apparent biological value. SSW supplemented with mineral mixture could serve as an excellent source of nutrients for ruminants.

반도체 제조공정에서 발생하는 혼산폐액으로부터 고순도 인산 회수 (Recovery of phosphoric acid from the waste acids in semiconductor manufacturing process)

  • 박성국;노유미;이상길;김주엽;신창훈;안재우
    • 한국자원리싸이클링학회:학술대회논문집
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    • 한국자원리싸이클링학회 2006년도 춘계임시총회 및 제27회 학술발표대회
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    • pp.90-94
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    • 2006
  • 액정(LCD)과 반도체 제조공정에서 발생하는 인산, 질산, 초산, Al, Mo 등이 혼재하고 있는 인산계 혼산폐액을 액정제조공정에서 사용할 수 있는 고순도 에칭액으로 재활용하기 위해서 용매추출법, 진공 증발법, 확산투석법 및 이온교환법의 각각의 기술적 특성을 살린 혼합 처리공정을 이용하여 고순도 인산 회수 기술을 확립하고 상용화 시스템을 개발하고자 하였다. 시험 결과 진공증발에 의해 질산과 초산을 100% 제거할 수 있었고, TOP를 사용한 용매추출에서도 추출 4단, 탈거 6단, 상비 1/3으로 완벽하게 제거할 수 있었다. 이온교환의 전단계로 적용한 확산투석에서 Al 97%, Mo 75% 제거할 수 있었고 이온교환공정에서 Al 및 Mo를 각각 1ppm 이하로 정제할 수 있었다.

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Physical and Mechanical Properties and Fire-endurance Characteristics of Recycled Particleboards

  • Suh, Jin-Suk;Han, Tae-Hyung;Park, Joo-Saeng;Park, Jong-Young
    • 한국가구학회지
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    • 제19권6호
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    • pp.475-486
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    • 2008
  • In this study, fire-retardant chemicals were melt with mixed composition ratios of dibasic ammonium phosphate and each half of boric acid and borax in hot water, in which hammer-milled chips were immersed to increase swelling of waste particleboards. Also, fire-retardant treated particles from sawn lumber chip and recycled particleboard chip were composed in ratio of 70:30 in core layer to improve boards' properties. Retention ratio of fire-retardant chemicals for the particles for face layer was high due to high specific surface area, and that of sawn lumber chips was somewhat higher than that of recycled particleboard chips. The mixture of particles from sawn lumber chips and recycled PB of 70:30 in weight ratio exceeded bending strength of 100 $kgf/cm^2$. It seemed that the relatively greater portions of dibasic ammonium phosphate affected adversely to dimensional stability, however fire-retardants treatment resulted in distinct effect lowering formaldehyde emission such as $E_0$ type(0.5mg/$\ell$ or less) in KS F 3104. In fire-retardancy, the recycled boards with a mixed ratio of dibasic ammonium phosphate to boric acid borax(50:50 mixture) of 70% to 30% in weight satisfied fire-retardancy 3rd grade in KS F 2271, and also this composition from cone calorimeter test met same standard grade figuring total heat release of 4.6MJ/$m^2$.

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Evaluation of the Inhibitive Performance of Cyperus Conglomeratus Leaves Extract as a Green Corrosion Inhibitor on Mild Steel XC70 in Acid Medium

  • Belkis, Guessoum;Abdelkader, Hadj Seyd;Oumelkheir, Rahim
    • Corrosion Science and Technology
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    • 제21권3호
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    • pp.171-183
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    • 2022
  • The performance and inhibitory action of the aqueous extract of Cyperus Conglomeratus's leaves against corrosion of XC70 steel in a 1M HCl acid medium are studied by the determination of the weight loss, the potentiodynamic polarization curves analysis, and electrochemical impedance measurements (electrochemical techniques). The corrosion inhibitory efficiency of XC70 steel increases with the increasing concentration of the green inhibitor, however, the corrosion rate of the steel decreases. Weight loss measurements show that the maximum percentage corrosion inhibition efficiency is approximately 61.86%, while the analysis of the mixed character polarization curves shows that the inhibitor could achieve an inhibition efficiency of 86.96%. The electrochemical impedance study confirmed that the value of the charge transfer resistance (Rct) increases and the value of the double layer capacity (Cdl) decreases with increasing concentration of the aqueous extract of Cyperus Conglomeratus's leaves, thus increasing the inhibition efficiency. The study showed that this aqueous extract acts by adsorption on the metal surface; this adsorption follows the Langmuir isotherm. This research work showed that Cyperus Conglomeratus leaves extract acts as an effective and eco-friendly inhibitor on mild steel in an acid medium.

반도체(半導體) 제조공정(製造工程)에서 발생하는 혼산폐액(混酸廢液)으로부터 고순도(高純度) 인산회수(燐酸回收) (Recovery of high-purity phosphoric acid from the waste acids in semiconductor manufacturing process)

  • 박성국;노유미;이상길;김주엽;신창훈;김준영;안재우
    • 자원리싸이클링
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    • 제15권5호
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    • pp.26-32
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    • 2006
  • LCD와 반도체 제조공정에서 발생하는 인산, 질산, 초산, Al, Mo 등이 혼재하고 있는 인산계 혼산폐액을 액정제조공정에서 사용할 수 있는 고순도 에칭액으로 재활용하기 위해서 용매추출법, 진공증발법, 확산투석법 및 이온교환법의 각각의 기술적 특성을 살린 혼합 처리공정을 이용하여 고순도 인산회수 기술을 확립하고 상용화 시스템을 개발하고자 하였다. 시험 결과 진공증발에 의해 질산과 초산을 100% 제거할 수 있었고, TOP를 이용한 용매추출에서도 추출 4단, 탈거 6단으로 완벽하게 제거할 수 있었다. 이온교환의 전단계로 적용한 확산투석에서 Al 97.5%, Mo 36.7% 제거할 수 있었고 이온교환공정에서 Al 및 Mo를 각각 1ppm이하로 정제할 수 있었다.

Asp. usamii shirousamii $U_2$ 균의 국식배양에 의한 유기산 및 당화효소 생성에 관한 연구 (Studies on Formation of Organic Acid and Saccharifing Amylase in Koji Culture by Asp. usamii shirousamii $U_2$)

  • 윤복현;박윤중;이석건
    • 한국식품과학회지
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    • 제6권3호
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    • pp.127-132
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    • 1974
  • Asp. usamii shirousamii $U_2$ 균의 국식 배양에 있어서 유기산 및 당화효소생성 조건에 대하여 실험한 결과는 다음과 같다. (1) 유기산 생산은 밀가루 및 밀기울 배지의 경우 $30^{\circ}C$에서 3일간 배양시에 가장 좋았으며 당화효소력은 밀가루 배지의 경우 $35^{\circ}C$, 3일간 배양시에 가장 높았고 밀기울 배지는 $35^{\circ}C$, 2일간 배양시에 거의 최고 역가를 나타냈다. (2) 3일 배양의 경우 배지의 첨수량은 밀가루 배지에서는 60% 첨수일 때, 밀기울 배지에서는 50% 첨수일 때 유기산 생성이 가장 좋았으며 당화효소 생성은 밀가루, 밀기울의 어느 배지에서나 $90{\sim}100%$ 첨수에서 가장 좋았다. (3) 밀가루와 밀기울의 배지를 비교하여 볼 때 유기산의 생성은 밀가루 배지가 좋았으며 당화효소생성은 밀기울 배지에서 높았다. (4) 고구마 전분박과 밀가루를 동량으로 혼합했을 때 밀가루 단일배지보다 유기산 및 당화효소 생성이 높았으며 밀기울에 고구마전분박 첨가의 효과는 없었다. (5) 밀가루, 밀기울 단일배지에 비하여 고구마전분박 단일배지에서는 유기산 및 당화효소 생성이 극히 나빴다. (5) 60% 첨수의 밀가루배지에서 $30^{\circ}C$, 3일간 배양한 경우 생성유기산 중의 약 90%가 구연산이었다.

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Sustainable self compacting acid and sulphate resistance RAC by two stage mixing approaches

  • Rajhans, Puja;Kisku, Nishikant;Nayak, Sanket;Panda, Sarat Kumar
    • Advances in concrete construction
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    • 제9권1호
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    • pp.55-70
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    • 2020
  • In this research article, acid resistance, sulphate resistance and sorptivity of self compacted concrete (SCC) prepared from C&D waste have been discussed. To improve the above properties of self compacted recycled aggregate concrete (SCRAC) along with mechanical and durability properties, different two stage mixing approaches (TSMA and TSMAsfc) were followed. In the proposed two stage mixing approach (TSMAsfc), silica fume, a proportional amount of cement and a proportional amount of water were mixed in premix stage which fills the pores and cracks of recycled aggregate concrete (RAC). The concrete specimen prepared using above mixing approaches were immersed in 1% concentration of sulphuric acid (H2SO4) and magnesium sulphate (MgSO4) solution for 28, 90 and 180 days for evaluating the acid resistance of SCRAC. Experimental results concluded that the proposed two stage mixing approach (TSMAsfc) is most suitable for acid resistance and sulphate resistance in terms of weight loss and strength loss due to the elimination of pores and cracks in the interfacial transition zone (ITZ). In modified two stage mixing approach, the pores and cracks of recycled concrete aggregate (RCA) were filled up and make ITZs of SCRAC stronger. Microstructure analysis was carried out to justify the reason of improvement of ITZs by electron probe micro analyser (EPMA) analysis. X-ray mapping was also done to know the presence of strength contributing elements presents in the concrete sample. It was established that SCRAC with modified mixing approach have shown improved results in terms of acid resistance, sulphate resistance, sorptivity and mechanical properties.

방사성폐기물 중의 $^129I$ 정량을 위한 요오드의 분리 및 회수 (Separation and Recovery of Iodide in Radioactive Waste for $^129I$)

  • 최계천;한선호;지광용;임석남;박상규
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2003년도 가을 학술논문집
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    • pp.632-635
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    • 2003
  • 원자력 발전소에서 배출되고 있는 방사성 폐기물의 운반 및 처분과 관련하여 규제가 예상되는 대상 핵종을 선정하고, 특히 방사능 계측기로 직접 측정이 불가능한 드럼 내 방출핵종에${\alpha}{\cdot}{\beta}$ 대한 농도 예측과 검증방법에 관한 연구가 진행되고 있다. 본 연구에서는 $\beta$방출 핵종이면서 반감기가 매우 긴 $^129I(t_{1/2}=1.57{\times}10^7)$의 정량을 위하여 모의 폐기물 중에 함유되어 있는 요오드의 분리 및 회수율을 측정하였다. 모의 폐기물중 가용성 및 난용성 시료의 전처리 방법으로 혼합산 분해법과 알칼리 용융방법을 각각 이용하였으며 두 방법에 대한 요오드의 회수율을 비교하였다. 요오드의 측정방법으로 이온 크로마토그라피를 이용하였으며 매질의 음이온성분에 의한 영향은 없었다. 두 방법의 전체 공정에서 혼합산분해에 의한 요오드의 회수율은 76.7 (RSD 1.7%)이고 알칼리용융에 의한 방법에서 모직물의 경우에는 74.3(RSD 2.2%)이고 Resin의 경우 56.5(5.6%)로 각각 나타났다.

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음식물쓰레기와 폐활성슬러지의 혼합물로부터 혐기성 바이오 수소 생산 (Biological Hydrogen Production from Mixed Waste of Food and Activated Sludge)

  • 정종민;홍석원;박철희;김영오;이상협
    • 상하수도학회지
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    • 제22권5호
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    • pp.571-580
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    • 2008
  • The influence of bacterial stress on anaerobic hydrogen-producing microorganisms was investigated in batch tests using serum bottles. Several physical and chemical stresses (i.e., heating, adding methane producing inhibitor and chemical acidification) were adapted as a pretreament of the seed sludge. In this experiment, the cultivation temperature were set at mesophilic ($35^{\circ}C$) and thermophilic conditions ($55^{\circ}C$) with adjusting pH at 5, 6, and 7 when using the mixture of food waste and activated sludge as a substrate. In conjunction with the pretreatment, hydrogen production was significantly enhanced as compared with that from untreated sludge. However, less biogas (hydrogen and methane) was produced without the pH control, resulted from the decrease of pH to below 4, mainly due to the formation of VFAs. Hydrogen and carbon dioxide gas were analyzed as main components of the biogas while methane not detected. With an application of chemical acidification, the highest hydrogen production value of 248 ml/l/day achieved at pH 7 and $35^{\circ}C$. In addition, more hydrogen gas produced when the ratio of butyric/acetic acid ratio increased. The optimum pH and temperature for hydrogen production were found to be 7 and $35^{\circ}C$, respectively.