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Mixed Micellization of Anionic Ammonium Dodecyl Sulfate and

  • Gang, Gye Hong;Kim, Hong Un;Im, Gyeong Hui;Jeong, No Hui
    • Bulletin of the Korean Chemical Society
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    • v.22 no.9
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    • pp.1009-1014
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    • 2001
  • In aqueous mixtures of cationic OTAC (octadecyl trimethyl ammonium chloride) and anionic ADS (ammonium dodecyl sulfate) surfactants, mixed micelles were formed at low (< 0.2 wt %) total surfactant concentrations. For these mixtures mixed micelliza tion and interaction of surfactant molecules were examined. Mixed critical micelle concentration (CMC), thermodynamic potentials of micellization, and minimum area per surfactant molecule at the interface were obtained from surface tensiometry and electrical conductometry. The mixed micellar compositions and the estimation of interacting forces were determined on the basis of a regular solution model. The CMCs were reduced, although not substantial, and synergistic behavior of the ADS and OTAC in the mixed micelles was observed. The CMC reductions in this anionic/cationic system were comparable to those in nonionic/anionic surfactant systems. The interaction parameter $\beta$ of the regular solution model was estimated to be -5 and this negative value of $\beta$ indicated an overall attractive force in the mixed state.

Effects of Rain Gardens on Removal of Urban Non-point Source Pollutants under Experimental Conditions (실험실 조건에서 레인가든의 도시 비점오염물질 제거효과)

  • Kim, Changsoo;Sung, Kijune
    • Journal of Korean Society on Water Environment
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    • v.28 no.5
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    • pp.676-685
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    • 2012
  • As impermeable layer continues to increase with the urbanization process, direct input of nonpoint source pollutants into water bodies via stormwater has caused serious effects on the aquatic ecosystem. Potential applications of rain gardens are increasing not only as best management practices (BMP) for reducing the level of nonpoint source pollutants but also as an ecological engineering alternative for low impact development (LID). In this study, remediation performance of various planting types, such as a mixed planting system with shrubs and herbaceous plants, was assessed quantitatively to effectively manage stormwater and increase landscape applicability. The mixed planting system with Rhododendron lateritium and Zoysia japonica showed the highest removal performance of $76.9{\pm}7.6%$ and $58.4{\pm}5.0%$ for total nitrogen and $89.9{\pm}7.9%$ and $82.4{\pm}5.2%$ for total phosphorus at rainfall intensities of 2.5 mm/h and 5.0 mm/h, respectively. The mixed planting system also showed the highest removal performance for heavy metals. The results suggest that a rain garden with the mixed planting system has high potential applicability as a natural reduction system for nonpoint source pollutants in order to manage stormwater with low concentrations of pollutants and will increase water recycling in urban areas.

A Study on Physico-Chemical Properties on Mixed Fuel Oil of Very Low Sulfur Fuel Oil-High Sulfur Fuel Oil (VLSFO-HSFO) (저유황-고유황 혼합연료유의 물리화학적 특성연구)

  • Song, In-Chul;Shin, Su-Hyun;Kim, Sae-Mi;Lee, Hee-Jin;Seo, Jeong-Mog
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.7
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    • pp.864-872
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    • 2020
  • In accordance with the sulfur regulations of the International Maritime Organization (IMO), very low sulfur fuel oil (VLSFO) shows various production-dependent physico-chemical properties. This study aims to use as basic data for oil spill response according to study of physico-chemical characteristics of VLSFO and mixed fuel oil of VLSFO-HSFO. The mixed fuel oil was prepared by mixing 25, 50, 75 mass% of HSFO with VLSFO containing 0.46 and 0.36 mass% of sulfur. The physico-chemical properties such as the kinematic viscosity, pour point and distribution of Saturates, Aromatics, Resins, and Asphaltenes (SARA) were studied in the laboratory. As mixed of 75 mass% of HSFO with high the kinematic viscosity and low pour point in VLSFO, the kinematic viscosity of the mixed fuel oil increased to 350.2 %, and VLSFO with pour point of 23℃ and -11℃ lowered or raised to -3℃ and -6℃ respectively. As HSFO was mixed in VLSFO with a small Asphaltenes distribution, the Saturates distribution decreased to 68.8% and Asphaltenes distribution increased to 1,417 % dramatically.

A Study on Changes in the Carotene Content of Korean Laver according to different Cooking method (한국산 김의 조리방법에 따른 Carotene 함량변화와 관한 연구)

  • 장기숙
    • Journal of the Korean Home Economics Association
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    • v.17 no.3
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    • pp.53-59
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    • 1979
  • Vitamin contents of three grades of Korean laver high, medium and low were measured. They were cooked by different methods to examine changes in their vitamin content. Results of this experiment are as follows ; 1. Vitamin contained in loogr of laver amount to 13,200 I.U, for high grade, 16,100 for mediium grade, and 16,400 for low grade . The low -grade laver, which is interwoven with green laver, showed the highest vitamin content. 2. When laver was broiled sheet by sheet, its vitamin loss rate was 11% for high grade, 19% for medium grade, and 20% for low grade. Thus , the one with a higher vitamin content showed a higher vitamin loss rate. When two sheets of laver, which were put upon each other, were broiled, their vitamin loss rates were 2.3% for high grade, 1.73 % for medium grade, and 2.64% for low grade. Thus broiling laver at the unitof two to three sheets together is a way of decreasing the vitamin loss rate. 3. When laver was broiled with salt applied on its surface , its vitamin loss rate was 8.3% for high grade, 13% for medium grade, and 10.9% for low grade. When laver was broied at the unit of two sheets together after salt and sesame oil were added, its vitamin loss rate was 2.2% for high grade, 5.2% for medium grade, and 8.2% for low grade . The one with a higher vitamin content showed a higher vitamin loss rate. 4. When laver was mixed seasoned soysauce, its vitamin loss rate increased in process of time. In 48 hours after laver was mixed with seasoned soysauce , its vitamin loss rate read 24.2%, 27.1% and 35% respectively, for the three grades of laver. Thus the laver mixed with seasoned soysauce has to be used right after so cooked so as to obtained the highest possible vitamin content.

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Ductile Fracture Behavior of AS4P Under Mixed Mode (I/II) Loading

  • Oh, Dong-Joon
    • Journal of Mechanical Science and Technology
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    • v.16 no.4
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    • pp.476-484
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    • 2002
  • The aim of this study is to investigate the ductile fracture behavior under mixed mode (I/II) loading using SA533B pressure vessel steel. Anti-symmetric 4-point (AS4P) bending tests were performed to obtain the J-R curves under two different mixed mode (I/II) loadings. In addition, finite element analysis using Rousselier Ductile Damage Theory was carried out to predict the J-R curves under mixed mode (I/II) loadings. In conclusions, the J-R curves under. Mixed Mode (I/II) loading were located between those of Mode I and Mode II loading. When the mixity of mixed mode (I/II) loading was high, the J-R curve of mixed mode (I/II) loading approached that of pure mode I loading after some amount of crack propagation. In contrast with the above fact, if the mixity was low, the J-R curve took after that of pure mode II loading. Finally, it was found that the predicted J-R curves made a good agreement with the test data through the tuning procedures of $\beta$ values at the different mixed mode (I/II) loading.

Analog-Digital Switching Mixed Mode Low Ripple - High Efficiency Li-Ion Battery Charger (아날로그 - 디지털 스위칭 혼합형 저 리플- 고 효율 Li-Ion 배터리 충전기)

  • Jung, Sang-Hwa;Woo, Young-Jin;Kim, Nam-In;Cho, Gyu-Hyeong
    • Proceedings of the KIEE Conference
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    • 2001.07d
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    • pp.2531-2533
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    • 2001
  • This paper describes a low noise and high efficiency analog-digital switching mixed mode battery charger for production facilities of Li-Ion batteries. The requirements for battery chargers for production facilities are very strict. The accuracy of output voltage and output current should be below 0.1% with very low ripple current. Therefore analog type linear regulators are widely used for battery charger in spite of their inefficiency and bulkiness. We combined linear regulator as a voltage source with digital switching converter as a dependent current source. Low current ripple and high accuracy are obtained by linear regulator while high efficiency is achieved by digital switching converter. Experimental results show that proposed method has 0.1% ripple and 90% efficiency at an output current of 1A for a battery voltage of 4V.

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Improvement of Hole Geometric Accuracy by Powder Mixed Electro-chemical Discharge Machining Process (Powder Mixed ECDM (Electro-Chemical Discharge Machining)을 이용한 미세구멍가공의 정밀도 개선)

  • 한민섭;민병권;이상조
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.42-45
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    • 2004
  • Electrochemical discharge machining (ECDM) has been found to be suitable for the micro-hole machining of nonconductive materials such as ceramics or glass compared with existing conventional and also non-conventional machining methods. However this machining process has some problems such as low geometric accuracy and low machining efficiency due to the random spark generation at the end of the electrode. This paper proposes the methods to improve the geometric accuracy of micro-hole using powder mixed ECDM process. The experimental results show the effects of powder producing improved geometric accuracy of machined hole and decreased concentration of spark energy.

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Craniospinal Metastasis from a Metastasizing Mixed Tumor of Salivary Gland : Unusual Presentation

  • Ye, Hyun-Hee;Cho, Chang-Won;Jeon, Mi-Young;Kim, Dae-Jo
    • Journal of Korean Neurosurgical Society
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    • v.41 no.3
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    • pp.186-189
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    • 2007
  • Metastasizing mixed tumors [MMT] of salivary glands are inexplicably metastasize maintaining benign histology. There is no pathologic and flow cytometric analysis criteria to predict the metastasis. MMT is known to metastasize by local implantation, vascular and lymphatic embolization after multiple surgery to local recurrences of primary tumor. However, multiple metastasis including cranium and spine occurred even without surgery to the primary tumor in this case. No pathological evidence of malignancy could be found in both primary and metastatic tumor. MMT is considered as an low grade malignancy based on clinical behavior rather than histologic evidence, such as low mortality rate, long delay of metastasis after primary lesion. Cranial metastasis is also extremely rare and only two cases have been reported. We report this unusual case with a literature review.

An Experimental Study on the Development of Hybrid Discontinuous Fiber Reinforced Cementitious Composite (하이브리드형 단섬유보강 시멘트복합재료의 개발에 관한 실험적 연구)

  • 김영덕;조봉석;김재환;김용로;윤현도;김무한
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2003.05a
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    • pp.57-60
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    • 2003
  • Generally, normal concrete has the disadvantages of low tensile strength, low ductility and volume instability. To improve its performance, fiber reinforced cimentitious composite(FRCC) have been development. These composites are composed of cement, sand, water, a small amount of admixtures, and an optimal amount of fiber like synthetic fiber and steel fiber. This research investigates influence of sand, hybrid fiber and fiber volume fraction, and reports the test results of mechanical properties, fracture behavior and failure pattern of the FRCC. Our experiment was observed that sand mixed FRCC has lower compressive strength and higher bending strength than no sand mixed FRCC, and more steel fiber mixed FRCC has higher compressive strength and bending strength. Hybrid FRCC of steel and polypropylene had superior properties than FRCC of polypropylene only in same fiber volume fraction.

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3-Gb/s 60-GHz Link With SiGe BiCMOS Receiver Front-End and CMOS Mixed-Mode QPSK Demodulator

  • Ko, Min-Su;Kim, Du-Ho;Rucker, Holger;Choi, Woo-Young
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.11 no.4
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    • pp.256-261
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    • 2011
  • We demonstrate 3-Gb/s wireless link using a 60-GHz receiver front-end fabricated in $0.25-{\mu}m$ SiGe:C bipolar complementary metal oxide semiconductor (BiCMOS) and a mixed-mode quadrature phase-shift keying (QPSK) demodulator fabricated in 60-nm CMOS. The 60-GHz receiver consists of a low-noise amplifier and a down-conversion mixer. It has the peak conversion gain of 16 dB at 62 GHz and the 3-dB intermediate-frequency bandwidth of 6 GHz. The demodulator using 1-bit sampling scheme can demodulate up to 4.8-Gb/s QPSK signals. We achieve successful transmission of 3-Gb/s data in 60 GHz through 2-m wireless link.