• 제목/요약/키워드: Mixed Gases

검색결과 229건 처리시간 0.022초

가축분에 몇가지 석회 화합물 처리에 의한 질소손실 경감과 $NH_3$ 가스 발생 감소에 미치는 영향 (Effects of Lime Compounds on the Reduction of Ammonia Gas Formation and Nitrogen Loss During the Formation of Poultry Manure-Sawdust)

  • 박창규;양장석;조광래;원선이
    • 한국유기농업학회지
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    • 제8권2호
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    • pp.89-96
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    • 2000
  • To reduce loss of nitrogen and generation of ammonia gas during composting, poultry manure and sawdust were mixed at the equivalent ratio and calcium chloride, fused superphosphate and vermiculite were added. Ammonia and sulfurous gas during composting, and NH4-N and NO3-N contents of composts were periodically measured. With the treatments of 0.5∼3% calcium chloride and 3% fused superphosphate, ammonia and sulfurous gas during composting significantly decreased, and especially generation of gases sharply reduced and a increase of calcium chlorde. Extractable NH4-N content in composts treasted with calcium chloride and fused superphosphate were high but extractable NO3-N markedly decreased. In conclusion, the results suggest that it is necessary the additon of 1∼3% calcium chloride or 3% fused superphosphate to reduce loss of nirogen and generation of offensive odor during composting of poultry manure mixed with sawdust.

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수소 첨가가 예혼합 메탄 화염의 NOx 생성에 미치는 영향 (Hydrogen Enrichment Effects on NOx Formation in Pre-mixed Methane Flame)

  • 김한석;안국영
    • 한국수소및신에너지학회논문집
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    • 제18권1호
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    • pp.75-84
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    • 2007
  • The effects of hydrogen enrichment to methane on NOx formation have been investigated with swirl stabilized pre-mixed hydrogen enriched methane flame in a laboratory-scale pre-mixed combustor(nominally of 5,000 kcal/hr). The hydrogen enriched methane fuel and air were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame stability was examined for different amount of hydrogen addition to the methane fuel, different combustion air flow rates and swirl strengths by comparing equivalence ratio at the lean flame limit. The hydrogen addition effects and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using gas analyzers, and OH chemiluminescence techniques to provide information about species concentration of emission gases and flowfield. The results of NOx and CO emissions were compared with a diffusion flame type combustor. The results show that the lean stability limit depends on the amount of hydrogen addition and the swirl intensity. The lean stability limit is extended by hydrogen addition, and is reduced for higher swirl intensity at lower equivalence ratio. The addition of hydrogen increases the NOx emission, however, this effect can be reduced by increasing either the excess air or swirl intensity. The NOx emission of hydrogen enriched methane premixed flame was lower than the corresponding diffusion flame under the fuel lean condition.

Effect of Continuous Treatment of Mixed Organic Fertilizer With Food Waste on the Growth and Yield of Solarium lycopersicum

  • Ho-Jun Gam;Yosep Kang;Eun-Jung Park;Seong-Heon Kim;Sang-Mo Kang;In-Jung Lee
    • 한국작물학회:학술대회논문집
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    • 한국작물학회 2022년도 추계학술대회
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    • pp.110-110
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    • 2022
  • According to the statistics of the Ministry of Environment, the amount of food waste generated in Korea is 15,903 tons, which accounts for about 30% of the daily household waste. Food waste in Korea is on the rise, and various odors, greenhouse gases, and leachate generated in the process of discharging, transporting, and processing are emerging as social problems. Accordingly, there is a need for a method for recycling food waste. Therefore, this study was carried out to establish an appropriate limiting dose by manufacturing fertilizer mixed with food waste powder and treating it on tomatoes to investigate the growth and yield of crops. The experiment was carried out with continuous cultivation in 2021 (1st year) and 2022 (2nd year), and the treatment groups were set to No Treatment (NT), Chemical Fertilizer (CF), Mixed Fertilizer (MF), and Mixed Fertilizer×2 (MF×2). As a result of the 1st year growth survey, shoot and root length did not show a significant difference between the treatment groups, and the fresh weight showed a significant difference between the MF and MF×2. As a result of the 2nd year growth survey, there was no significant difference in shoot length, root length, and dry weight between the treatment groups, and the fresh weight of the CF was significantly greater than that of the MF×2. The yield of 1st year, MF×2 increased significantly compared to other treatment groups. In the case of 2nd year, CF, and MF×2 show significantly high values compared to NT. Judging from these results, continuous cultivation using food waste powder mixed fertilizer did not have a significant effect on crop growth and yield. However, it is considered that several studies including continuous cultivation experiments are needed to accurately set the appropriate application amount and limit the application amount of the mixed fertilizer for food waste.

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가스상 대기오염물질에 의한 종이 기록물의 가속열화 특성 연구 (Studies on the Accelerated Aging Characteristics of Paper Records by Gaseous Air Pollutants)

  • 정소윤;전수연;백소라;정현석;이진희;김형진
    • 펄프종이기술
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    • 제47권4호
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    • pp.151-159
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    • 2015
  • Paper records were generally degraded by some factors from atmospheric environments, like temperature, relative humidity or air pollutants. In this study, the degradation behavior of paper records by single or mixed gases of $NO_2$, $SO_2$, HCHO and TVOC was evaluated. The mechanical, optical and chemical properties of 4 kinds of paper (acid and neutral-based printing paper, traditional Hanji, and filter paper) were directly and indirectly affected by gaseous harmful materials. The brightness and $L^*$ value in all papers were slightly increased by accelerated aging under gaseous HCHO and TVOCs, but highly decreased by conditions under gases $NO_2$ and $SO_2$. The optical properties of paper records were most vulnerable in acid-based paper and high stable in filter paper and traditional Hanji by air pollutant degradation. The aging treatments under mixed gas pollutants including $NO_2$ resulted in decrease of physical, mechanical and optical properties of paper, so it was supposed that the concentration of $NO_2$ gas would be strictly controlled for optimum indoor air quality management in domestic storage centers for paper records.

가소화 저항 향상을 위한 기체분리막 소재 개발 동향 (Review on Membrane Materials to Improve Plasticization Resistance for Gas Separations)

  • 조진희;지원석
    • 멤브레인
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    • 제30권6호
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    • pp.385-394
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    • 2020
  • 기체분리공정에서 사용되는 분리막은 높은 기체 투과 및 분리성능과 고온·고압 조건에서 높은 안정성을 보여야 한다. 하지만 고분자분리막(특히, 유리상 고분자)은 응축 가능한 기체 분자(예를 들어, CO2, H2S, hydrocarbon 등)에 노출되면 고분자 사슬이 부풀어 오르는 가소화 현상을 보여 안정성 측면에서 한계를 보인다. 이러한 가소화 현상은 고압의 복합기체 분리공정에서 선택도를 감소시켜 장기적으로는 고분자분리막이 분리공정에 도입될 수 없는 문제를 가져온다. 이러한 가소화 현상 문제를 해결하기 위해서 분리막 연구자들은 분리막 열처리, 고분자 혼합, 고분자구조의 열적 재배열, 혼합매질분리막 제작, 가교화 방법 등을 통하여 분리막의 가소화 저항을 향상시켰다. 본 총설에서는 고분자 분리막의 가소화 저항의 개념 및 현상에 대해서 알아보고 이를 해결할 수 있는 인자들과 그와 연관된 연구들을 살펴보도록 할 것이다.

Corrosion Behavior of Stainless Steel 316 for Carbon Anode Oxide Reduction Application

  • Jeon, Min Ku;Kim, Sung-Wook;Choi, Eun-Young
    • 방사성폐기물학회지
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    • 제18권2호
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    • pp.169-177
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    • 2020
  • Here, the stability of stainless steel 316 (SS-316) was investigated to identify its applicability in the oxide reduction process, as a component in related equipment, to produce a complicated gas mixture composed of O2 and Cl2 under an argon (Ar) atmosphere. The effects of the mixed gas composition were investigated at flow rates of 30 mL/min O2, 20 mL/min O2 + 10 mL/min Cl2, 10 mL/min O2 + 20 mL/min Cl2, and 30 mL/min Cl2, each at 600℃, during a constant argon flow rate of 170 mL/min. It was found that the corrosion of SS-316 by the chlorine gas was suppressed by the presence of oxygen, while the reaction proceeded linearly with the reaction time regardless of gas composition. Surface observation results revealed an uneven surface with circular pits in the samples that were fed mixed gases. Thermodynamic calculations proposed the combination of Fe and Ni chlorination reactions as an explanation for this pit formation phenomenon. An exponential increase in the corrosion rate was observed with an increase in the reaction temperature in a range of 300 ~ 600℃ under a flow of 30 mL/min Cl2 + 170 mL/min Ar.

클로로포름($CHCl_3$)을 첨가한 고농도 폴리실리콘 이방성 식각 기술 (Anisotropic Etching Technology of Highly Doped Polysilicon by Mixed Chloroform)

  • 이정환;서희돈;최세곤
    • 한국전기전자재료학회논문지
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    • 제11권2호
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    • pp.101-105
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    • 1998
  • This paper describes anisotropic etching technology of highly doped polysilicon. The main etching gases are $Cl_2$ and $SiCl_4$ for reactive ion etching of polysilicon. The mixed $CHCl_3$ to main etching gas makes polymer on etching side wall, so it prevents side etching of polysilicon. The etch rate of polysilicon is increased with increasing RF power. But the etching rate is decreased as the flow rate of $CHCl_3$ is increased with fixed RF power. The etch selectivity of polysilicon and $SiO_2$ is about 12:1. And that of polysilicon and $Si_3N_4$ is about 19:1. In the main etching gas condition, the slope of polysilicon is same as that of photoresist. But in the mixed $CHCl_3$ condition, the slope of polysilicon is larger than that of photoresist. This represents that the polymer made on side wall by added $CHCl_3$ prevents side etching, so anisotropic etching can be possible by polymer.

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고분자막을 이용한 $N_2-SO_2$ 혼합기체의 분리에 관한 연구 (A Study on Separation of $N_2-SO_2$ Mixed Gas by Polymer Membranes)

  • 김성준;민병렬;이태희
    • 멤브레인
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    • 제2권2호
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    • pp.135-143
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    • 1992
  • 여러가지 고분자막을 이용하여 $N_2-SO_2$ 혼합기체를 분리하는 데 있어서 압력, 온도 등을 조작변수로 하여 투과계수와 분리인자를 계산하고 이에 따른 기체투과 특성을 규명하고 분리성능을 측정하였다. 실험한 압력의 범위는 0.1~1.0 MPa이었으며, 온도범위는 283~303 K이었다. 압력이 커질수록 투과계수와 분리인자가 증가하였으나, 온도증가에 따라 투과계수와 분리인자는 감소하였다. 본 실험에서 사용된 막 중 Film-Tech사의 FT-30이 $N_2-SO_2$ 혼합기체의 분리능력이 가장 뛰어난 것으로 나타났다.

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Corrosion of Carbon Steel with and without Aluminized Coating in (O, S, H)-containing Gases at 500-800℃

  • Lee, Dong Bok;Abro, Waheed Ali;Lee, Kun Sang;Abro, Muhammad Ali
    • 한국표면공학회지
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    • 제50권2호
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    • pp.85-90
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    • 2017
  • The carbon steel formed the thick, somewhat porous, loosely adherent iron oxide scale when oxidized at $500-800^{\circ}C$ for 15 h in air. It formed the thicker, more porous, nonadherent scale consisting of FeS plus iron oxides in $Ar/1%SO_2$-mixed gas. It formed the much thicker, more porous, nonadherent scale consisting of FeS plus iron oxides in Ar/0.1% $H_2S$-mixed gas. However, the aluminized carbon steel formed the thin, protective $Al_2O_3$ surface scale even in $Ar/1%SO_2$-, and $Ar/0.1%H_2S$-mixed gas. Aluminizing drastically improved the corrosion resistance in (O, S, H)-containing gas.

Fe-(8.5~36.9) wt% Cr합금의 600~800℃, (N2,H2S,수증기)-혼합 가스분위기에서의 부식 (Corrosion of Fe-(8.5~36.9) wt% Cr Alloys at 600~800℃ in (N2, H2S, H2O)-Mixed Gases)

  • 김민정;이동복
    • 대한금속재료학회지
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    • 제50권3호
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    • pp.218-223
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    • 2012
  • Fe-(8.5, 18.5, 28.3, 36.9) wt% Cr alloys were corroded between 600 and $800^{\circ}C$ for up to 70 h in a 1 atm gas mixture that consisted of 0.0242 atm of $H_2S$, 0.031 atm of water vapor, and 0.9448 atm of nitrogen gas. Their corrosion resistance increased with an increment in the Cr content. The Fe-8.5%Cr alloy corroded fast, forming thick, fragile, nonadherent scales that consisted primarily of an outer FeS layer and an inner (Fe, Cr, O, S)-mixed layer. The outer FeS layer grew into the air by the outward diffusion of $Fe^{2+}$ ions, whereas the inner mixed layer grew by the inward diffusion of oxygen and sulfur ions. At the interface of the outer and inner scales, voids developed and cracking occurred. The Fe-(18.5, 28.3, 36.9)% Cr alloys displayed much better corrosion resistance than the Fe-8.5Cr alloy, because thin $Cr_2O_3$ or $Cr_2S_3$ scales formed.