• Title/Summary/Keyword: Mixed Gases

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Effects of Lime Compounds on the Reduction of Ammonia Gas Formation and Nitrogen Loss During the Formation of Poultry Manure-Sawdust (가축분에 몇가지 석회 화합물 처리에 의한 질소손실 경감과 $NH_3$ 가스 발생 감소에 미치는 영향)

  • 박창규;양장석;조광래;원선이
    • Korean Journal of Organic Agriculture
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    • v.8 no.2
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    • pp.89-96
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    • 2000
  • To reduce loss of nitrogen and generation of ammonia gas during composting, poultry manure and sawdust were mixed at the equivalent ratio and calcium chloride, fused superphosphate and vermiculite were added. Ammonia and sulfurous gas during composting, and NH4-N and NO3-N contents of composts were periodically measured. With the treatments of 0.5∼3% calcium chloride and 3% fused superphosphate, ammonia and sulfurous gas during composting significantly decreased, and especially generation of gases sharply reduced and a increase of calcium chlorde. Extractable NH4-N content in composts treasted with calcium chloride and fused superphosphate were high but extractable NO3-N markedly decreased. In conclusion, the results suggest that it is necessary the additon of 1∼3% calcium chloride or 3% fused superphosphate to reduce loss of nirogen and generation of offensive odor during composting of poultry manure mixed with sawdust.

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Hydrogen Enrichment Effects on NOx Formation in Pre-mixed Methane Flame (수소 첨가가 예혼합 메탄 화염의 NOx 생성에 미치는 영향)

  • Kim, H.S.;Ahn, K.Y.;Gupta, A.K.
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.1
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    • pp.75-84
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    • 2007
  • The effects of hydrogen enrichment to methane on NOx formation have been investigated with swirl stabilized pre-mixed hydrogen enriched methane flame in a laboratory-scale pre-mixed combustor(nominally of 5,000 kcal/hr). The hydrogen enriched methane fuel and air were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame stability was examined for different amount of hydrogen addition to the methane fuel, different combustion air flow rates and swirl strengths by comparing equivalence ratio at the lean flame limit. The hydrogen addition effects and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using gas analyzers, and OH chemiluminescence techniques to provide information about species concentration of emission gases and flowfield. The results of NOx and CO emissions were compared with a diffusion flame type combustor. The results show that the lean stability limit depends on the amount of hydrogen addition and the swirl intensity. The lean stability limit is extended by hydrogen addition, and is reduced for higher swirl intensity at lower equivalence ratio. The addition of hydrogen increases the NOx emission, however, this effect can be reduced by increasing either the excess air or swirl intensity. The NOx emission of hydrogen enriched methane premixed flame was lower than the corresponding diffusion flame under the fuel lean condition.

Effect of Continuous Treatment of Mixed Organic Fertilizer With Food Waste on the Growth and Yield of Solarium lycopersicum

  • Ho-Jun Gam;Yosep Kang;Eun-Jung Park;Seong-Heon Kim;Sang-Mo Kang;In-Jung Lee
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.110-110
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    • 2022
  • According to the statistics of the Ministry of Environment, the amount of food waste generated in Korea is 15,903 tons, which accounts for about 30% of the daily household waste. Food waste in Korea is on the rise, and various odors, greenhouse gases, and leachate generated in the process of discharging, transporting, and processing are emerging as social problems. Accordingly, there is a need for a method for recycling food waste. Therefore, this study was carried out to establish an appropriate limiting dose by manufacturing fertilizer mixed with food waste powder and treating it on tomatoes to investigate the growth and yield of crops. The experiment was carried out with continuous cultivation in 2021 (1st year) and 2022 (2nd year), and the treatment groups were set to No Treatment (NT), Chemical Fertilizer (CF), Mixed Fertilizer (MF), and Mixed Fertilizer×2 (MF×2). As a result of the 1st year growth survey, shoot and root length did not show a significant difference between the treatment groups, and the fresh weight showed a significant difference between the MF and MF×2. As a result of the 2nd year growth survey, there was no significant difference in shoot length, root length, and dry weight between the treatment groups, and the fresh weight of the CF was significantly greater than that of the MF×2. The yield of 1st year, MF×2 increased significantly compared to other treatment groups. In the case of 2nd year, CF, and MF×2 show significantly high values compared to NT. Judging from these results, continuous cultivation using food waste powder mixed fertilizer did not have a significant effect on crop growth and yield. However, it is considered that several studies including continuous cultivation experiments are needed to accurately set the appropriate application amount and limit the application amount of the mixed fertilizer for food waste.

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Studies on the Accelerated Aging Characteristics of Paper Records by Gaseous Air Pollutants (가스상 대기오염물질에 의한 종이 기록물의 가속열화 특성 연구)

  • Jeong, So-Yoon;Jeon, Soo-Yeon;Baek, So-Ra;Jeong, Hyun-Seok;Lee, Jin-Hee;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.4
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    • pp.151-159
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    • 2015
  • Paper records were generally degraded by some factors from atmospheric environments, like temperature, relative humidity or air pollutants. In this study, the degradation behavior of paper records by single or mixed gases of $NO_2$, $SO_2$, HCHO and TVOC was evaluated. The mechanical, optical and chemical properties of 4 kinds of paper (acid and neutral-based printing paper, traditional Hanji, and filter paper) were directly and indirectly affected by gaseous harmful materials. The brightness and $L^*$ value in all papers were slightly increased by accelerated aging under gaseous HCHO and TVOCs, but highly decreased by conditions under gases $NO_2$ and $SO_2$. The optical properties of paper records were most vulnerable in acid-based paper and high stable in filter paper and traditional Hanji by air pollutant degradation. The aging treatments under mixed gas pollutants including $NO_2$ resulted in decrease of physical, mechanical and optical properties of paper, so it was supposed that the concentration of $NO_2$ gas would be strictly controlled for optimum indoor air quality management in domestic storage centers for paper records.

Review on Membrane Materials to Improve Plasticization Resistance for Gas Separations (가소화 저항 향상을 위한 기체분리막 소재 개발 동향)

  • Jo, Jin Hui;Chi, Won Seok
    • Membrane Journal
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    • v.30 no.6
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    • pp.385-394
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    • 2020
  • In the gas separation process, the separation membranes have to not only show high gas transport and selectivity but also exhibit exceptional stability at high temperature and pressure. However, when the polymeric membranes (particularly, glassy polymers) are exposed to the condensable gases (i.e., CO2, H2S, hydrocarbon, etc.), the polymer chains are prone to swell, leading to low stability. As a result, the plasticization behavior reduces the gas selectivity in the separation of mixture gases at high pressures and thus results in limited applications to the separation processes. To address these issues, many strategies have been studied such as thermal treatment, polymer blending, thermally rearrangement, mixed-matrix membranes, cross-linking, etc. In this review, we will understand the plasticization behavior and suggest potential methods based on the previously reported studies.

Corrosion Behavior of Stainless Steel 316 for Carbon Anode Oxide Reduction Application

  • Jeon, Min Ku;Kim, Sung-Wook;Choi, Eun-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.2
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    • pp.169-177
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    • 2020
  • Here, the stability of stainless steel 316 (SS-316) was investigated to identify its applicability in the oxide reduction process, as a component in related equipment, to produce a complicated gas mixture composed of O2 and Cl2 under an argon (Ar) atmosphere. The effects of the mixed gas composition were investigated at flow rates of 30 mL/min O2, 20 mL/min O2 + 10 mL/min Cl2, 10 mL/min O2 + 20 mL/min Cl2, and 30 mL/min Cl2, each at 600℃, during a constant argon flow rate of 170 mL/min. It was found that the corrosion of SS-316 by the chlorine gas was suppressed by the presence of oxygen, while the reaction proceeded linearly with the reaction time regardless of gas composition. Surface observation results revealed an uneven surface with circular pits in the samples that were fed mixed gases. Thermodynamic calculations proposed the combination of Fe and Ni chlorination reactions as an explanation for this pit formation phenomenon. An exponential increase in the corrosion rate was observed with an increase in the reaction temperature in a range of 300 ~ 600℃ under a flow of 30 mL/min Cl2 + 170 mL/min Ar.

Anisotropic Etching Technology of Highly Doped Polysilicon by Mixed Chloroform (클로로포름($CHCl_3$)을 첨가한 고농도 폴리실리콘 이방성 식각 기술)

  • Lee, Jung-Hwan;Seo, Hee-Don;Choi, Se-Gon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.2
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    • pp.101-105
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    • 1998
  • This paper describes anisotropic etching technology of highly doped polysilicon. The main etching gases are $Cl_2$ and $SiCl_4$ for reactive ion etching of polysilicon. The mixed $CHCl_3$ to main etching gas makes polymer on etching side wall, so it prevents side etching of polysilicon. The etch rate of polysilicon is increased with increasing RF power. But the etching rate is decreased as the flow rate of $CHCl_3$ is increased with fixed RF power. The etch selectivity of polysilicon and $SiO_2$ is about 12:1. And that of polysilicon and $Si_3N_4$ is about 19:1. In the main etching gas condition, the slope of polysilicon is same as that of photoresist. But in the mixed $CHCl_3$ condition, the slope of polysilicon is larger than that of photoresist. This represents that the polymer made on side wall by added $CHCl_3$ prevents side etching, so anisotropic etching can be possible by polymer.

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A Study on Separation of $N_2-SO_2$ Mixed Gas by Polymer Membranes (고분자막을 이용한 $N_2-SO_2$ 혼합기체의 분리에 관한 연구)

  • 김성준;민병렬;이태희
    • Membrane Journal
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    • v.2 no.2
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    • pp.135-143
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    • 1992
  • Separation of $N_2-SO_2$ mixed gas by polymer membranes, SEPA-97(CA), TFC, and FT-30 membrane, was investigated by varying pressure and temperature. The permeability coefficients and the separation factors of mixed gases were measured, and the influence of various factors on the gas permeability characteristics and separation performance were investigated. The range of pressure was 0.1~1.0 MPa, and that of temperature was 283~303 K. The experimental results showed that the permeability coefficients and the separation factors were increased with an increase in pressure, but they were deereased with increasing temperature. Among the examined membranes, FT-30 possessed the best gas-separating characteristics.

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Corrosion of Carbon Steel with and without Aluminized Coating in (O, S, H)-containing Gases at 500-800℃

  • Lee, Dong Bok;Abro, Waheed Ali;Lee, Kun Sang;Abro, Muhammad Ali
    • Journal of the Korean institute of surface engineering
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    • v.50 no.2
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    • pp.85-90
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    • 2017
  • The carbon steel formed the thick, somewhat porous, loosely adherent iron oxide scale when oxidized at $500-800^{\circ}C$ for 15 h in air. It formed the thicker, more porous, nonadherent scale consisting of FeS plus iron oxides in $Ar/1%SO_2$-mixed gas. It formed the much thicker, more porous, nonadherent scale consisting of FeS plus iron oxides in Ar/0.1% $H_2S$-mixed gas. However, the aluminized carbon steel formed the thin, protective $Al_2O_3$ surface scale even in $Ar/1%SO_2$-, and $Ar/0.1%H_2S$-mixed gas. Aluminizing drastically improved the corrosion resistance in (O, S, H)-containing gas.

Corrosion of Fe-(8.5~36.9) wt% Cr Alloys at 600~800℃ in (N2, H2S, H2O)-Mixed Gases (Fe-(8.5~36.9) wt% Cr합금의 600~800℃, (N2,H2S,수증기)-혼합 가스분위기에서의 부식)

  • Kim, Min Jung;Lee, Dong Bok
    • Korean Journal of Metals and Materials
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    • v.50 no.3
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    • pp.218-223
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    • 2012
  • Fe-(8.5, 18.5, 28.3, 36.9) wt% Cr alloys were corroded between 600 and $800^{\circ}C$ for up to 70 h in a 1 atm gas mixture that consisted of 0.0242 atm of $H_2S$, 0.031 atm of water vapor, and 0.9448 atm of nitrogen gas. Their corrosion resistance increased with an increment in the Cr content. The Fe-8.5%Cr alloy corroded fast, forming thick, fragile, nonadherent scales that consisted primarily of an outer FeS layer and an inner (Fe, Cr, O, S)-mixed layer. The outer FeS layer grew into the air by the outward diffusion of $Fe^{2+}$ ions, whereas the inner mixed layer grew by the inward diffusion of oxygen and sulfur ions. At the interface of the outer and inner scales, voids developed and cracking occurred. The Fe-(18.5, 28.3, 36.9)% Cr alloys displayed much better corrosion resistance than the Fe-8.5Cr alloy, because thin $Cr_2O_3$ or $Cr_2S_3$ scales formed.