• Title/Summary/Keyword: Mix-Method

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Mixed Micellar Properties of DPC with Other Cationic Surfactants (DTAB, TTAB, and CDEAB) (DPC와 다른 양이온성 계면활성제(DTAB, TTAB 및 CDEAB)와의 혼합마이셀화에 관한 연구)

  • Lee, Byung Hwan
    • Journal of the Korean Chemical Society
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    • v.42 no.5
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    • pp.519-525
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    • 1998
  • The critical micelle concentration $(CMC^{\ast})$ and the counterion binding constant (B) in a micellar state of the mixed surfactant systems of dodecylpyridinium chloride (DPC) with dodecyltrimethylammonium bromide (DTAB), tetradecyltrimethylammonium bromide (TTAB), and cetyldimethylethylammonium bromide (CDEAB) were determined at $25^{\circ}C$ as a function of ${\alpha}_1$ (the overall molc fraction of DPC) by the use of electric conductivity method. Various thermodynamic parameters $(X_{i},\;{\gamma}_{I},\;C_{i},\;a^{M}_{i}, \beta,\;{\Delta}H_{mix}, \;and\; {\Delta}G^{o}_{m})$ for the micellization of DPC/DTAB, DPC/TTAB, and DPC/CDEAB mixtures were calculated and analyzed for each system by means of the equations derived from the pseudophase separation model. The results show that the DPC/DTAB mixed system has the greatest deviation and the DPC/CDEAB mixed system has the smallest deviation from the ideal mixed micellar model.

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Developing and Assessing Geopolymers from Seochun Pond Ash with a Range of Compositional Ratios (서천화력발전소 매립 석탄재로부터 제조한 다양한 조성비의 지오폴리머와 그 특성의 평가)

  • Lee, Sujeong;Jou, Hyeong-Tae;Chon, Chul-Min;Kang, Nam-Hee;Cho, Sung-Baek
    • Journal of the Korean Ceramic Society
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    • v.50 no.2
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    • pp.134-141
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    • 2013
  • Pond ash produced from Seochun Power Station was quantitatively characterized to manufacture geopolymers with a range of Si/Al compositional ratios. Mix consistency was kept nearly constant for comparing the compressive strengths of geopolymers. The amorphous composition of coal ash was determined using XRF and quantitative X-ray diffraction. Different mix compositions were used in order to achieve Si/Al ratios of 2.0, 2.5 and 3.0 in the geopolymer binder. Geopolymers synthesized from coal ash with a Si/Al ratio of 3.0 exhibited the highest compressive strength in this study. It was found that geopolymers activated with aluminate produced different microstructure from that of geopolymers activated with silicate. High silica in alkali activators produced the fine-grained microstructure of geopolymer gel. It was also found that high compressive strength was related to low porosity and a dense, connected microstructure. The outcome of the reported experiment indicates that quantitative formulation method made it possible to choose suitable activators for achieving targeted compositions of geopolymers and to avoid efflorescence.

Methodology for Modifying Aging Condition of Hot-mix Recycled Asphalt Mixture (가열 재생혼합물의 노화특성 개선을 위한 연구)

  • Kim, Kwang-Woo;Hong, Sang-Ki;Lee, Gi-Ho;Doh, Young-Soo
    • International Journal of Highway Engineering
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    • v.7 no.1 s.23
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    • pp.1-9
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    • 2005
  • This is a basic research for producing hot-mix recycled asphalt mixtures and suggesting methods for solving quality problems, if any. Various mixing methods are introduced to mate aging evenly between old and virgin aggregates and to improve aging conditions. Gel-permeation chromatography(GPC) analysis was performed to evaluate aging of binders coated on coarse aggregates and a matrix separately. Round-shaped aggregates(13m gravel) were used in manufacturing mixtures for analysis of aging levels in recycled mixtures. It was found out that there was significant difference in aging levels between the binder coated on RAP's coarse aggregates and on virgin aggregates in a recycled mixture. The difference in the aging level was reduced by modifying mixing method(RAP and virgin binders were mixed first and then virgin aggregates were introduced). Among A to E mixing methods studied, the D was turned out to be the best.

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Effect of Relative Levels of Mineral Admixtures on Strength of Concrete with Ternary Cement Blend

  • Mala, Kanchan;Mullick, A.K.;Jain, K.K.;Singh, P.K.
    • International Journal of Concrete Structures and Materials
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    • v.7 no.3
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    • pp.239-249
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    • 2013
  • In the present scenario to fulfill the demands of sustainable construction, concrete made with multi-blended cement system of OPC and different mineral admixtures, is the judicious choice for the construction industry. Silica fume (SF) and fly ash (FA) are the most commonly used mineral admixtures in ternary blend cement systems. Synergy between the contributions of both on the mechanical properties of the concrete is an important factor. This study reports the effect of replacement of OPC by fly ash (20, 30, 40 and 50 % replacement of OPC) and/or silica fume (7 and 10 %) on the mechanical properties of concrete like compressive strength and split tensile strength, with three different w/b ratio of 0.3, 0.4 and 0.45. The results indicate that, as the total replacement level of OPC in concrete using ternary blend of OPC + FA + SF increases, the strength with respect to control mix increases up to certain replacement level and thereafter decreases. If the cement content of control mixes at each w/b ratio is kept constant, then as w/b ratio decreases, higher percentage of OPC can be replaced with FA + SF to get 28 days strength comparable to the control mix. A new method was proposed to find the efficiency factor of SF and FA individually in ternary blend cement system, based on principle of modified Bolomey's equation for predicting compressive strength of concrete using binary blend cement system. Efficiency factor for SF and FA were always higher in ternary blend cement system than their respective binary blend cement system. Split tensile strength of concrete using binary and ternary cement system were higher than OPC for a given compressive strength level.

Dynamic Resource Allocation Method to improve QoS in the Wireless ATM Networks (무선 ATM망에서 QoS 향상을 위한 동적 자원 할당 방식)

  • Kim, Seung-Hwan;Lee, Sun-Sook;Lee, Jae-Hong;Jang, Dong-Heyok
    • The Transactions of the Korea Information Processing Society
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    • v.7 no.9
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    • pp.2940-2947
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    • 2000
  • In the wireless ATM networks, a Medium Access Control (MAC) protocol is required to support an integrated mix of multimedia traffic services. The MAC protocol should be designed in a way that the limited wireless bandwidth can be efficiently utilized maximizing the Quality of Service (QoS) guarantees for various traffic service classes. In this paper, a Dynamic Resource Allocation-based MAC protocol, which satisfies QoS of each traffic service class in the wireless ATM environment, is proposed. The proposed MAC protocol adopts the dynamic channel allocation schemes for a mix of different traffic service classes. The suggested MAC protocol is designed to provide the QoS guarantees for Constant Bit Rate (CBR) or real-time Variable Bit Rate (VBR) traffic through fixed or dynamic reservation. For Available Bit Rate (ABH) traffic, which has the lowest priority among the traffic classes, large improvement in delay by reserving the minimum bandwidth is shown. And for real-time VBR traffic, increase in throughput of transmission is demonstrated because of bandwidth, which is allocated through contention at the initial phase and without contention thereafter.

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Detecting Structural Change in NBD Model (NBD모형의 구조변화 감지)

  • Joo, Young-Jin
    • Journal of Global Scholars of Marketing Science
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    • v.16 no.1
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    • pp.13-26
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    • 2006
  • In this research, we develope a procedure for detecting a random non-stationarity to the individual's purchasing rate in a stationary NED model. On this purpose, we derive the likelihood ratio statistic for a testing null and alternative hypotheses defined as whether there is no significant structural change in a stationary NED model or any. Where the structural change comes from a random non-stationarity(marketing mix activities or seasonality, for example) to the individual's purchasing rate. We also apply the developed method to a panel data for a frequently purchased good. This research could be a solution to include the non-stationarity in a stationary NED model. We also expect that the developed model could give a signal for an early detection of significant changes in marketing environment, and a mean for a measurement of the effects of marketing mix activities.

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Mechanical Characteristics of Asphalt Stabilized Soil (아스팔트 안정처리토의 역학적 특성 연구)

  • 박태순;최필호
    • Journal of the Korean Geotechnical Society
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    • v.19 no.5
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    • pp.189-197
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    • 2003
  • The treatment and hauling of surplus soils which occur from construction activity are costly and have been demanding a reasonable recycling method. This study presents laboratory test results regarding the mechanistic properties of asphalt stabilized soils. The foamed asphalt equipment which generates the asphalt bubble was used to mix the soil. The marshall stability, indirect tensile test, resilient modulus, creep test and triaxial test(UU) were conducted to find out the performance of the asphalt stabilized soil. The test results were compared with the samples that fabricated in different conditions(the samples without asphalt and the reinforced samples using 2% cement). The inclusion of the asphalt in the soil has improved the marshall stability, resilient modulus and moisture susceptibility, and the addition of the 2% cement has even more increased these properties. The amount of the fines and the optimum moisture contents for mixing affects the mechanistic properties and important parameters for mix design.

A Fundamental Study on the Superplasticized Concrete (유동화(流動化)콘크리트에 관한 기초연구(基礎研究))

  • Moon, Han Young
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.2 no.2
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    • pp.47-59
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    • 1982
  • It is well practised in the field of concrete engineering that the effort of improving the low slumped concrete and uplifting the quality of the soft concrete by adopting the superplasticizer. In this paper, an attempt is made to find out the optimum mix design of the superplasticized concrete with an unit weight of cement 400 kg and the range of $19{\pm}1cm$ of slump by variatlng the sand percentage, unit water content and the dosage of superplasticizer. As a result, the author obtained the basic idea on the optimum mix design and strength of superplasticized concrete. On the other hand, it is also considered during the research the method of preventing the slump loss of the superplasticized concrete due to the delayed time after concrete mixing.

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Comparison of L5178Y tk+/- Mouse Lymphoma Assay and In vitro Chromosome Aberration Test

  • Lee, Michael;Jung Kwon;Cho, Ji-Hee;Hong, Mi-Young;Kim, Eun-Joo;Junghee Han;Chung, Moon-Koo;Han, Sang-Seop
    • Toxicological Research
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    • v.18 no.2
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    • pp.129-138
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    • 2002
  • The mouse lymphoma assay (MLA) has been recently validated as a sensitive and specific test system to determine the genotoxic potential for a chemical. The objective of this study is to evaluate the utility of MLA for detecting mutagens. Especially, to compare MLA with the in vitro chromosomal aberration test (CA), we performed MLA using the microwell method with three chemicals (hydroxyurea, theophylline and amino acid copper complex), which were reportedly positive in the CA. In cell treated with hydroxyurea, anti-neoplastic agent that blocks DNA replication, evidence of a positive response was obtained without S9 mix for 4 h and 24 h. In addition, analysis of colony size distribution at concentration that gave an elevated mutant fraction showed that hydroxyurea induced a high proportion of small type colonies, indicating that hydroxyurea-induced mutation is associated with large chromosomal deletion. Conversely, negative MLA result was obtained for theophylline, which was wed as central nervous system stimulator. Although theophylline increased the mutant frequency at concentration of 1250 $\mu\textrm{g}$/$\textrm{m}{\ell}$ with S9 mix for 4 h, a concentration-related increase in mutant frequency was not observed. The MLA result of amino acid copper complex was considered equivocal because the positive result was obtained at concentration showing 10% or less RS or RTG. Thus, among 3 CA-positive chemicals, positive MLA result was obtained for one. The other two chemicals were negative and equivocal. However MLA, which evaluates mutagenic potential of chemicals through colony formation by cell grouth, may provide a higher predictivity of carcinogenesis than CA.

Effect of steel fibers on surface electric resistivity of steel fiber reinforced concrete for shield segment (강섬유보강 콘크리트 세그먼트의 강섬유가 표면전기저항에 미치는 영향)

  • Moon, Do-Young;Lee, Gyu-Phil;Chang, Soo-Ho;Bae, Gyu-Jin
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.13 no.6
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    • pp.557-569
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    • 2011
  • Steel Fiber Reinforced Concrete (SFRC) is widely used for tunnel structures such as shotcrete and segments. Corrosion of steel fibers and steel reinforcements may affect on the long-term durability of the concrete structures with steel fibers and reinforcement. Therefore, a study on the feasible method to evaluate corrosion possibility and permeability of the concrete structures is required. This experimental study examines the effect of steel fibers and internal reinforcement on the surface resistivity. Steel fiber mix ratio and corrosion of internal reinforcement were considered as variables. In the results, steel fibers significantly reduce the surface resistivity due to those conductive characteristic. In the case of 3% mix ratio, it was difficult to evaluate rate and permeability of corrosion due to the great reduction of resistivity by mixing of steel fibers.