• 제목/요약/키워드: Minimum ignition temperature

검색결과 69건 처리시간 0.03초

페놀의 연소특성치의 측정 및 예측 (Measurement and Prediction of Combustion Properties of n-Phenol)

  • 하동명
    • 한국위험물학회지
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    • 제6권2호
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    • pp.23-29
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    • 2018
  • The fire and explosion properties necessary for waste, safe storage, transport, process design and operation of handling flammable substances are lower explosion limits(LEL), upper explosion limits(UEL), flash point, AIT( minimum autoignition temperature or spontaneous ignition temperature), fire point etc., An accurate knowledge of the combustion properties is important in developing appropriate prevention and control measures fire and explosion protection in chemical plants. In order to know the accuracy of data in MSDSs(material safety data sheets), the flash point of phenol was measured by Setaflash, Pensky-Martens, Tag, and Cleveland testers. And the AIT of phenol was measured by ASTM 659E apparatus. The explosion limits of phenol was investigated in the reference data. The flash point of phenol by using Setaflash and Pensky-Martens closed-cup testers were experimented at $75^{\circ}C$ and $81^{\circ}C$, respectively. The flash points of phenol by Tag and Cleveland open cup testers were experimented at $82^{\circ}C$ and $89^{\circ}C$, respectively. The AIT of phenol was experimented at $589^{\circ}C$. The LEL and UEL calculated by using Setaflash lower and upper flash point value were calculated as 1.36vol% and 8.67vol%, respectively. By using the relationship between the spontaneous ignition temperature and the ignition delay time proposed, it is possible to predict the ignition delay time at different temperatures in the handling process of phenol.

Methyl Ethyl Ketone Peroxide의 위험성을 판단하기 위한 자연발화, 인화점 및 폭발거동에 관한 기초 연구 (A Study of Characteristics such as Spontaneous Ignition, Flash Point and Explosion Behavior of Methyl Ethyl Ketone Peroxide in ender to Determine its Hazardousness)

  • 정두균;최재욱;이인식;임우섭;김동규
    • 한국안전학회지
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    • 제20권3호
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    • pp.78-83
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    • 2005
  • In this study, the evaluate characteristics of fire and explosion of MEK-PO are subjected to spontaneous ignition, flash point and explosion hazard. The minimum ignition temperature and instantaneous ignition temperature for MEK-PO were $188.5^{\circ}C\;and\;230^{\circ}C\;at\;225{\mu}L$. In addition The flash point for MEK-PO was obtained at $49^{\circ}C$. Furthermore, the maximum explosion pressure and the maximum explosion pressure rising velocity: using MCPVT (mini cup pressure vessel tester) were $10.82kgf/cm^2\;and\;33.72kgf/cm^2{\cdot}s$.

고밀도 폴리에틸렌 분진의 열분해성과 착화에너지 (Pyrolysis Characteristic and Ignition Energy of High-Density Polyethylene Powder)

  • 한우섭;이정석
    • 한국가스학회지
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    • 제18권3호
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    • pp.31-37
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    • 2014
  • 본 연구에서는 자료 제공을 목적으로 국내 분진폭발사고에서와 동일한 고밀도 폴리에틸렌(high-density polyethylene, HDPE ) 분진을 사용하여 열분해성과 착화에너지를 실험적으로 조사하였다. 폭발 민감도를 측정하기 위하여 시차주사열량계(differential scanning calorimeter, DSC), 열중량분석기(thermo-gravimetric analysis, TGA) 및 최소착화에너지(minimum ignition energy, MIE) 측정장치를 사용하였다. HDPE의 체적기준 평균입경은 $61.6{\mu}m$가 얻어졌으나, 입자 크기에 따른 입자 수밀도(particle number density) 분석에서는 $0.4{\sim}4{\mu}m$의 미세 입자가 98% 이상의 비율을 갖는 것으로 나타났다. TGA 및 DSC 측정결과로부터 HDPE는 $380{\sim}490^{\circ}C$의 온도 구간에서 발화가 일어날 수 있음을 알 수 있었고, MIE는 $1200{\sim}1800g/m^3$의 HDPE의 농도 범위에서 1 mJ 이하로 측정되었는데, 이는 입자 수밀도 기준에 따른 $0.4{\sim}4{\mu}m$의 미세 입자의 비율(98 %)이 매우 높았던 것이 원인으로 판단된다.

BTX(Benzene, Toluene, Xylenes)의 자연발화온도와 발화지연시간의 측정 (Measurements of Autoigniton Temperature(AIT) and Time Lag of BTX(Benzene, Toluene, Xylenes))

  • 하동명
    • 한국안전학회지
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    • 제21권3호
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    • pp.45-52
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    • 2006
  • The AITs(autoignition temperatures) describe the minimum temperature to which a substance must be heated, without the application of a flame or spark, which will cause that substance to ignite. The AITs are often used as a factor in determining the upper temperature limit for processing operations and conditions for handling, storage and transportation, and in determining potential fire hazard from accidental contact with hot surfaces. The measurement AITs are dependent upon many factors, namely initial temperature, pressure, volume, fuel/air stoichiometry, catalyst material, concentration of vapor, time lag. Therefore, the AITs reported by different ignition conditions are sometimes significantly different. This study measured the AITs of benzene, toluene and xylene isomers from time lag using AS1M E659-78 apparatus. The experimental ignition delay times were a good agreement with the calculated ignition delay times by the proposed equations wtih a few A.A.D.(average absolute deviation). Also The experimental AITs of benzene, toluene, o-xylene, m-xylene and p-xylene were $583^{\circ}C,\;547^{\circ}C,\;480^{\circ}C,\;587^{\circ}C,\;and\;557^{\circ}C$, respectively.

운동에너지탄에 의한 전투시스템의 순간화재 발생가능성에 대한 연구 (A Study on The Possibility of Flash Fire of Combat System by Kinetic Energy Ammunitions)

  • 박영주;이은민;이해평;황미정;이창현
    • 한국안전학회지
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    • 제29권2호
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    • pp.89-97
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    • 2014
  • This study analyzed various possibilities of flash fire which could occur in a variety of combats, in order to predict that of flash fire of combat system armor using Autodyn program. The possibility was judged by the temperature distribution of fuels, which was caused by the impact of parts of fuel systems through an armor, in the event of getting shot by external ammunition. Diverse variables could affect the possibility of flash fire: external ammunition(Type A: penetration 570 mm, Type B: penetration 410 mm), fuels(Gasoline, Diesel, Kerosene), the thickness of an armor(100, 200, 300, 400, 500 mm), the gap of a fuel tank and an armor(45, 95, 145, 195, 245, 295 mm). As a result, when an armor was 20 mm think, the temperature of 3 fuels ranged like this: Gasoline 372~387 K, Diesel 442~408 K, Kerosene 384~395 K. Although they made a little difference among them, they all didn't reach their ignition points. When an armor was 200 mm think, each fuel reached the maximum temperature, not reaching its ignition points as well. The thicker an armor was, the lower the temperature got. When Type B ammunition was used, the temperature of fuels went up 19~59 K higher than Type A was used. In the case that the gap of fuel tank and an armor was 20 mm thick, the temperature distribution of Gasoline showed 389~450 K, the maximum temperature appeared in the gap of 145 mm, and the minimum temperature 295 mm. For Type B, the temperature distribution of fuels ranged 386~401 K, the maximum temperature appeared in the gap of 245 mm, and the minimum temperature 45 mm. There was no significant difference between two cases, and neither of them reached its ignition point. Accordingly, as the tested fuels of combat systems didn't reach their ignition points, it is thought that the possibility of flash point of an armor is low.

알코올화합물의 폭발하한계 추산에 관한 연구 (A Study on Estimation of Lower Explosive Limits of Alcohol Compounds)

  • Dong-Myeong Ha;Yong-Chan Choi;Haejin Oh;Su-kyung Lee
    • 한국산업안전학회:학술대회논문집
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    • 한국안전학회 2002년도 추계 학술논문발표회 논문집
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    • pp.291-296
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    • 2002
  • Flammable compounds are indispensible in domestic as well as in industrial fields as fuel, solvent and raw materials. The fire and explosion properties necessary for safe storage, transport, process design and operation of handling flammable substances are lower explosive limits(LEL), upper explosive limits(UEL), flash point, fire point, AIT(auto ignition temperature), MIE(minimum ignition energy), MOC(minimum oxygen concentration) and heats of combustion.

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n-Propanol과 Formic acid계의 최소자연발화온도의 측정 (Measurement of Autoignition Temperature of n-Propanol and Formic acid System)

  • 조영세;하동명
    • 한국화재소방학회논문지
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    • 제27권5호
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    • pp.64-69
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    • 2013
  • 가연성 혼합물의 최소자연발화온도는 가연성액체의 안전한 취급을 위해서 중요한 지표가 된다. 본 연구에서는 ASTM E659 장치를 이용하여 가연성 혼합물인 n-Propanol과 Formic acid 계의 최소자연발화온도와 발화지연시간을 측정하였다. 2성분계를 구성하는 순수물질인 n-Propanol과 Formic acid의 최소자연발화온도는 각 각 $435^{\circ}C$$498^{\circ}C$로 측정되었다. 그리고 측정된 n-Propanol과 Formic acid 계의 최소자연발화온도는 제시된 식에 의한 예측값과 작은 평균절대오차에서 일치하였다. 그리고 n-Propanol과 Formic acid 계는 일부 혼합 조성에서 두 개의 순수물질 가운데 낮은 AIT보다 낮게 측정된 최소자연발화온도거동(MAITB, Minimum Autoignition Temperature Behavior)을 보이고 있다.

발열의류로 인한 화재위험성 및 저온화상에 대한 분석 연구 (A Study of the analysis on the risk of ignition and low-temperature burns caused by the use of electrically heated clothes)

  • 이정일
    • 한국재난정보학회 논문집
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    • 제14권2호
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    • pp.122-129
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    • 2018
  • 연구목적 : 본 연구는 최근 많이 이용하고 있는 발열조끼에 의한 저온화상과 화재위험성 도출을 목적으로 한다. 연구방법 : 사용전압보다 더 높은 전압에 발열조끼를 연결하는 실험을 실시하였다. 연구결과 : 재현실험한 결과 높은 저온화상과 발화위험성을 알 수 있었다. 또한 같은 전압을 인가했을 때 상대적으로 열선의 저항값이 더 낮은 발열조끼 제품이 더 높은 온도에 도달한다는 것도 알 수 있었다. 결론 : 발열조끼는 온도조절장치나 타이머가 존재하지 않아 온도가 급격히 올라갈 경우 안전장치가 없다는 문제점이 있다. 따라서 화재나 저온화상의 위험성을 줄이기 위해서는 열선의 최소저항값 기준을 설정하고, 낮은 저항값을 가지는 열선 사용의 규제가 필요하다.

A Study on Experiment of CNG as a Clean Fuel for Automobiles in Korea

  • Chauhan, Bhupendra Singh;Cho, Haeng-Muk
    • 한국대기환경학회지
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    • 제26권5호
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    • pp.469-474
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    • 2010
  • Gasoline engines have proven their utility in light, medium and heavy duty vehicles. Concern about long term availability of petroleum and the environment norms by the increased vehicular emission have mandated the search for safe fuel. CNG is an environmentally clean alternative to the existing spark ignition engines with the advantages of minimum change. A higher octane number and a higher self ignition temperature make it an attractive gaseous fuel. The thermal efficiency is better than gasoline for the same engine. The reduced carbon mono oxide, carbon di-oxide, hydrocarbon emissions is a favorable outcome along with a slight increase in $NO_x$ emission when compared with gasoline fuel to a dual fuel mode in the existing spark ignition engines. The result from the experiment shows that CNG could be a potential substitute fuel that maintains performance and emissions characteristics in gasoline engines.

CaO이 첨가된 AZ91D 마그네슘 합금의 발화저항특성 및 용탕보호특성 평가 (Melt Protection Property and Ignition Resistance Property of CaO added AZ91D Mg Alloy)

  • 이진규;하성호;김영직;조형호;김세광
    • 한국주조공학회지
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    • 제27권3호
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    • pp.131-134
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    • 2007
  • [ $SF_6$ ] gas that is used as a protective cover gas for Mg and Mg alloys during melting and casting has extremely high greenhouse effect. CaO added Mg alloys could maintain their original mechanical properties and original abilities such as fluidity and hot tearing susceptibility. The ignition temperature increased with increasing CaO addition under ambient atmosphere and nitrogen atmosphere. The minimum amount of $SF_6$ gas decreased by 0.13 wt%CaO added AZ91D Mg alloy in the sealed condition.