• Title/Summary/Keyword: Minimum Melting Energy

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Study on the Melting Point of Ar by Molecular Dynamic Simulation (Ar의 녹는점에 관한 분자동역학적 고찰)

  • Chung, Jae-Dong
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.19 no.12
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    • pp.883-888
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    • 2007
  • As a starting point of investigating what molecular dynamic simulations can reveal about the nature of atomic level of heating and cooling process, argon described by the LJ potential is considered. Stepwise heating and cooling of constant rates are simulated in the NPT (constant number, pressure and temperature) ensemble. Hysteresis is found due to the superheating and supercooling. Drastic change of volume and energy is involved with phase change, but the melting point can not be obtained by simply observing the changes of these quantities. Since liquid and solid phases can co-exist at the same temperature, Gibbs free energy should be calculated to find the temperature where the Gibbs free energy of liquid is equal to that of the solid since the equilibrium state is the state of minimum Gibbs free energy. The obtained melting temperature, $T^*=0.685$, is close to that of the experiment with only 2% error.

Scale-up of Melting Chamber for a Pyrolysis Melting Incinemtion System (폐기물 열분해/용융 소각 시스템의 용융로 Scale-up 연구)

  • Yang, Won;Kim, Bong-Keun;Yu, Tae-U;Jeun, Keum-Ha
    • 한국연소학회:학술대회논문집
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    • 2007.05a
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    • pp.168-175
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    • 2007
  • Ash melting chamber is one of the key facility of the pyrolysis-melting incineration system, and it should be designed and operated very carefully for avoiding solidification of slag. In this study, an example of numerical and experimental scale-up process of the melting chamber, in which high speed air is injected to the molten slag and generates bubbles, which enhances agitation of the slag and char combustion, is presented. Cold flow test, combustion and melting test in a lab-scale (30 kg/hr) chamber and a pilot scale (200 kg/hr) chamber. Minimum energy for maintaining molten slag is derived, and it was found that the molten slag can be maintained efficiently by concentrating heat into the bubbling slag.

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Study on the Spheroidizing Mechanism of Graphite in Cast Iron (II) (鑄鐵에 있어서의 黑鉛球狀化 機構에 關한 硏究 (Ⅱ))

  • Choi, Hyung-Sup;Park, Won-Koo
    • Journal of the Korean Chemical Society
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    • v.8 no.2
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    • pp.57-61
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    • 1964
  • It was verified at Part Ⅰ of this investigation that there is a minimum wettability between molten iron and graphite, which was preliminarily coated with magnesium, and thus the spheroidization of graphite might have resulted from the lack of wettability between magnesium-adsorbed graphite and iron matrix. Being continued from the last work, the wettability between pure iron and graphite, coated with the various thickness of cerium, are measured at melting point of pure iron in vacuum and 200 mmHg argon gas atmosphere. The result indicates the presence of a minimum wettability at a critical thickness of cerium film as was proved in the case of magnesium. The experimental analysis shows that, the minimum wettability could be attributed entirely to a minimum work of adhesion between liquid iron and graphite at a critical concentration of cerium in the iron-graphite interface.

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Characterization of the Deposited Layer Obtained by Direct Laser Melting of Fe-Cr Based Metal Powder (Fe-Cr계 금속 분말의 직접 레이저 용융을 통해 형성된 적층부 특성 분석)

  • Jang, Jeong-Hwan;Joo, Byeong-Don;Jeon, Chan-Hu;Moon, Young-Hoon
    • Korean Journal of Metals and Materials
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    • v.50 no.2
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    • pp.107-115
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    • 2012
  • Direct laser melting (DLM) is a powder-based additive manufacturing process to produce parts by layer-by-layer laser melting. As the properties of the manufactured parts depend strongly on the deposited laser-melted bead, deposited layers obtained by the DLM process were characterized in this study. This investigation used a 200 W fiber laser to produce single-line beads under a variety of different energy distributions. In order to obtain a feasible range for the two main process parameters (i.e. laser power and scan rate), bead shapes of single track deposition were intensively investigated. The effects of the processing parameters, such as powder layer thickness and scan spacing, on geometries of the deposited layers have also been analyzed. As a result, minimum energy criteria that can achieve a complete melting have been suggested at the given powder layer thickness. The surface roughnesses of the deposited beads were strongly dependent on the overlap ratio of adjacent beads and on the energy distributions of laser power. Through microstructural analysis and hardness measurement, the morphological and mechanical properties of the deposited layers at various overlapped beads have also been characterized.

A Study on Snow Melting System for the Anti-freezing Testing Road (시험선로 결빙방지를 위한 융설시스템에 관한 연구)

  • Han, K.I.;Lee, A.H.;Cho, D.H.
    • Journal of Power System Engineering
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    • v.10 no.1
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    • pp.34-40
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    • 2006
  • The snow melting system by electric heating wires which is adopted in this study is a part of road facilities to keep surface temperature of the road higher than freezing point of water for melting the snow accumulated on it. The system is designed to increase traffic safety and capacity. The electric heating wires are buried under paved road at a certain depth and operated automatically and manually. Design theory, amount of heating, and installation standard vary according to economic situation, weather condition, and installation place where the system applies. It is tried to figure out that the appropriate range of required heat capacity and installation depth and intervals for solving snowdrifts and freezing problems with the minimum electric power consumption. The most important factors to design the system are calculation of heating capacity depending on weather condition and depth and interval of the electric heating wires depending on air condition respectively. The study were performed under the range of the air temperatures($-2^{\circ}C,\;-5^{\circ}C,\;-8^{\circ}C$), the intervals of the electric heating wires(70mm, 100mm, 125mm), and the installation depths(50mm, 70mm, 100mm). The ready made commercial program package was used to verify the experimental results.

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Theoretical Study on Snow Melting Process on Porous Pavement System by using Heat and Mass Transfer (열전달 및 물질전달을 이용한 공극 발열도로에서의 융설 해석에 대한 이론적 연구)

  • Yun, Taeyoung
    • International Journal of Highway Engineering
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    • v.17 no.5
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    • pp.1-10
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    • 2015
  • PURPOSES : A finite difference model considering snow melting process on porous asphalt pavement was derived on the basis of heat transfer and mass transfer theories. The derived model can be applied to predict the region where black-ice develops, as well as to predict temperature profile of pavement systems where a de-icing system is installed. In addition, the model can be used to determined the minimum energy required to melt the ice formed on the pavement. METHODS : The snow on the porous asphalt pavement, whose porosity must be considered in thermal analysis, is divided into several layers such as dry snow layer, saturated snow layer, water+pavement surface, pavement surface, and sublayer. The mass balance and heat balance equations are derived to describe conductive, convective, radiative, and latent transfer of heat and mass in each layer. The finite differential method is used to implement the derived equations, boundary conditions, and the testing method to determine the thermal properties are suggested for each layer. RESULTS: The finite differential equations that describe the icing and deicing on pavements are derived, and we have presented them in our work. The framework to develop a temperature-forecasting model is successfully created. CONCLUSIONS : We conclude by successfully creating framework for the finite difference model based on the heat and mass transfer theories. To complete implementation, laboratory tests required to be performed.

The Effects of Fuel Pellet Eccentricity on Fuel Rod Thermal Performance (핵연료의 편심이 연료봉 열적 성능에 미치는 영향)

  • Suh Young-Keun;Sohn Dong-Seong
    • Nuclear Engineering and Technology
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    • v.20 no.3
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    • pp.189-196
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    • 1988
  • This study investigates the effect of fuel pellet eccentricity on fuel rod thermal performance under the steady state condition. The governing equations in the fuel pellet and the cladding region are set up in 2-dimensional cylindrical coordinate (r, $\theta$) and are solved by finite element method. The angular-dependent heat transfer coefficient in the gap region is used in order to account for the asymmetry of gap width. Material propeties are used as a function of temperature and volumetric heat generation as a function of radial position. The results show the increase of maximum local heat flux at the cladding outer surface and the decrease of maximum and average fuel temperatures due to eccentricity. The former is expected to affect the uncertainties in the minimum DNBR calculation. The latter two are expected to reduce the possibility of fuel melting and the fuel stored energy. Also, the fuel pellet eccentricity introduces asymmetry in fuel pellet temperature and movement of the location of maximum fuel pellet temperature.

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Comparison of the Thermal-Hydraulic Characteristics of Optimised Fuel Assembly with That of Standard Fuel Assembly (최적 핵연료집합체와 표준 핵연료집합체의 열수력학적 특성비교)

  • Paik, Hyun-Jong;Rim, Chang-Saeng;Park, Goon-Cherl
    • Nuclear Engineering and Technology
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    • v.22 no.1
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    • pp.66-74
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    • 1990
  • The thermal-hydraulic characteristics of the 17$\times$17 OFA (Optimized Fuel Assembly) used in the KNU 7&8 are analyzed and compared with that of the 17$\times$17 SFA (Standard Fuel Assembly) loaded in the KNU 5&6. The thermal-hydraulic characteristics analyzed are minimum DNBR, fuel centerline temperature and exit void fraction at normal operation and design over power transient. Additionally, local linear rod power, which will cause fuel centerline melting, is calculated. The DNBR sensitivity calculations are performed with respect to the reactor operating parameters. COBRA-IV-I code is used for these calculations. The modified W-3 correltion and the drift-flux model are applied for the critical heat flux calculation and the void fraction calculation, respectively. From the calculated results, it has been found that the possibility of DNB occurrence is higher in the OFA than in the SFA. The other hand, the local linear power resulting in fuel centerline moiling of the OFA is nearly equal to that of the SFA.

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Studies in Iron Manufacture Technology through Analysis of Iron Artifact in Han River Basin during the Proto-Three Kingdoms

  • Kim, Soo-Ki
    • Conservation and Restoration of Cultural Heritage
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    • v.1 no.1
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    • pp.9-22
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    • 2012
  • The most widely excavated iron artifacts used as weapons or farm tools from central southern regions of Korea were subjects of non-metallic inclusion analysis through metallographic examination, microhardness measurement, and scanning electron microscopy with energy dispersive X-ray spectroscopy. Through metallographic interpretation and study of the analyzed results, the steel manufacturing and iron smelting using heat processing in the iron artifacts excavated from the central southern region of the ancient Korean peninsula was studied, and the analysis of the non-metallic inclusions mixed within the metallic structures was interpreted as the ternary phase diagram of the oxide to infer the type of iron ores for the iron products and the temperature of the furnace used to smelt them. Most of the ancient forged iron artifacts showed $Al_2O_3/SiO_2$ with high $SiO_2$ contents and relatively low $Al_2O_3$ contents for iron ore, indicating t hat for $Al_2O_3$ below 5%, it is presumed that magnetic iron ores were reduced to bloom iron (sponge iron) with direct-reduction process for production. The temperature for extraction of wustite for $Al_2O_3$ below 1% was found to be $1,020{\sim}1,050^{\circ}C$. Considering the oxide ternary constitutional diagram of glassy inclusions, the steel-manufacturing temperature was presumed to have been near $1,150{\sim}1,280^{\circ}C$ in most cases, and minimum melting temperature of casting iron part excavated in Daeseong-ri. Gyeonggi was near $1,400^{\circ}C$, and it is thought that hypoeutectic cast iron of about 2.3% carbon was casted and fragility of cast iron was improved by decarburizing in solid state.