The adsorption property and ability of domestic zeolites for some heavy metal ions (Ag, Pb, Cr, Cu, Zn, Mn), which may cause a serious environmental problem in industrial wastewater, were evaluated on ore unit through a series of adsorption experiments together with careful examinations of mineral composition and properties of the zeolites. Though the adsorption behavior basically took place in the form of a cation exchange reaction, the higher CEC value does not necessarily to imply the higher adsorption capacity for a specific heavy metal. A general trend of the adsorption selectivity for heavy metals in the zeolites is determined to be as follow: $Ag\geq$Pb>Cr,Cu$\geq$Zn>Mn, but the adsorption properties of heavy metal ions somewhat depend on the species and composition of zeolite. Clinoptilolite tends to adsorb selectively Cu in case of Cr and Cu, whereas heulandite prefers Cr to Cu. A dominant adsorption selectivity of the zeolite ores for Ag and Pb is generally conspicuous regardless of their zeolite species and composition. The zeolite ores exhibit a preferential adsorption especially for $Ag^{+}$ so as not to regenerate when treated with $Na^{+}$ . In the adsorption capacity for heavy meta ions, the zeolites differ in great depending on their species: ferrierite>clinoptilolite>heulandite. Considering the CEC value of mordenite, the mordenite-rich ore appears to be similar to the clinoptilolite ore in the adsorption capacity. The adsorption capacity for heavy metals is not positively proportional to the CEC values of the zeolites measured by the exchange reaction with ammonium ion. In addition, the adsorption capacity roughly tends to depend on the zeolite contents, i.e., the grade of zeolite ore, but the trend is not consistent at all in some ores. These may be caused by the adsorption selectivity for some specific heavy metals, the presence of possible stacking micro-faults and natural cations such as K hardly to exchange in the zeolite. Considering the economic availability and functional effectiveness as natural zeolite resources, clinoptilolite ores could be applicable to utilize the domestic zeolites for the removal of heavy metals.
Journal of the Korean Society of Food Science and Nutrition
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v.33
no.7
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pp.1212-1217
/
2004
The aim of this study was to investigate Quality characteristics of Pleurospermum kamtschaticum to increase the value of functional food resources. To examine Quality characteristics of Pleurospermum kamtschaticum, various factors such as color, texture, fiber, minerals, tannin, crude proteins, crude lipids and sensory quality, were determined using physicochemical methods. The contents of dietary fiber were 0.57% and 0.54% in each 100 g of leaf and stem parts (freeze drying base). In mineral content, potassium was the highest value in both of leaf and stem parts (freeze drying base). The contents of tannin were 108.1 $\mu$g/mL and 20.9 $\mu$g/mL in leaf and stem parts (fresh base) respectively. Blanching stems showed significant difference in hardness from freeze-drying leaves. The antioxidative activity in ethanol extracts of Pleurospermum kamtschaticum was investigated using peroxide value and free radical scavenging activity. Free radical scavenging activity in ethanol extracts of Pleurospermum kamtschaticum was 43.5% in a 100 $\mu$g/mL level, and the antioxidative index was 1.09 in a 500 $\mu$g/mL level. For functional food using Pleurospermum kamtschaticum the contents of crude proteins and lipids were about 9% and 26%, respectively. The results from sensory evaluation of each treatment older age showed a better acceptability.
The site categorization and corresponding site amplification factors in the current Korean seismic design guideline are based on provisions for the western United States (US), although the site effects resulting in the amplification of earthquake ground motions are directly dependent on the regional and local site characteristic conditions. In these seismic codes, two amplification factors called site coefficients, $F_a$ and $F_v$, for the short-period band and midperiod band, respectively, are listed according to a criterion, mean shear wave velocity ($V_S$) to a depth of 30 m, into five classes composed of A to E. To suggest a site classification system reflecting Korean site conditions, in this study, systematic site characterization was carried out at four regional areas, Gyeongju, Hongsung, Haemi and Sacheon, to obtain the $V_S$ profiles from surface to bedrock in field and the non-linear soil properties in laboratory. The soil deposits in Korea, which were shallower and stiffer than those in the western US, were examined, and thus the site period in Korea was distributed in the low and narrow band comparing with those in western US. Based on the geotechnical characteristic properties obtained in the field and laboratory, various site-specific seismic response analyses were conducted for total 75 sites by adopting both equivalent-linear and non-linear methods. The analysis results showed that the site coefficients specified in the current Korean provision underestimate the ground motion in the short-period range and overestimate in the mid-period range. These differences can be explained by the differences in the local site characteristics including the depth to bedrock between Korea and western US. Based on the analysis results in this study and the prior research results for the Korean peninsula, new site classification system was developed by introducing the site period as representative criterion and the mean $V_S$ to a depth of shallower than 30 m as additional criterion, to reliably determine the ground motions and the corresponding design spectra taking into account the regional site characteristics in Korea.
The Miocene andesite and basalt intruded into and/or extruded on the Cretaceous volcanic and granitic rocks over the area of Chenjabong and Sirubong in the vicinity of Jinhae, southern part of Kyongsang basin. The K-Ar ages of the younger volcanic rocks are from 16 Ma (Sirubong andesite) to 10 Ma (Cheonjabong basalt), which indicate the Miocene volcanism in the outer part of the Tertiary basin in the Korean peninsula. The volcanics are divided into Chenjabong andesite, Cheonjabong basaltic andesite, Sirubong andesite and Cheonjabong basalt. The Cheonjabong andesite is composed of phenocrysts of clinopyroxene and plagioclase ($An_{60{\sim}64}$) and groundmass with lath-like plagioclase ($An_{76{\sim}84}$) and glass. The Cheonjabong basaltic andesite is composed of plagioclase phenocryst ($An_{60{\sim}64}$) with plagioclase lath ($An_{65}$) and glass in groundmass. The Sirubong andesite is only consisted of plagiocalse lath ($An_{64{\sim}68}$) and glass with absence of phonocryst. The Cheonjabong basalt shows typical porphyritic texture with phenocrysts of olivine ($Fo_{69-84}$) and clinopyroxene. The groundmass of the Cheonjabong basalt is composed of microphenocrysts of olivine, clinopyroxene and plagioclase ($An_{66{\sim}71}$) and plagioclase laths ($An_{57{\sim}65}$) showing pillotaxitic and intergranular texture. The Cheonjabong andesite, Cheonjabong basaltic andesite, Sirubong andesite are belong to calc-alkialine but the Cheonjabong basalt is alkaline basalt. By tectonic discrimination diagrams the parental magmas of the volcanic rocks have occurred boundary.
Kim, So Ra;Lee, Gwang Soo;Choi, Dong Lim;Kim, Dae Choul;Lee, Tae Hee;Seo, Young Kyo
The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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v.19
no.2
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pp.131-146
/
2014
High-resolution seismic profiles coupled with sediment sampling were analyzed to investigate the acoustic characters and distribution patterns of the late Holocene sediments in Gamak Bay of the South Sea, Korea. The mean grain size of surficial sediment lies around $6.3{\sim}9.7{\Phi}$. Sediments in the bay consist of silt and clay with progressive decrease toward the inner bay. The seismic sedimentary sequence overlying the acoustic basement can be divided into two sedimentary units (GB I and II) by a prominent mid-reflector (Maximum Flooding Surface; MFS). The acoustic basement occurs at the depth between 20 m and 40 m below the sea-level and deepens gradually southward. The GB I, mostly occupying the channel-fill, is characterized by reflection-free seismic facies. It can be formed as late Transgressive System Tract (TST), interpreted tidal environment deposits. MFS appears at the depth of about 15~28 m below the sea-level and is well defined by even and continuous reflectors on the seismic profile. The GB II overlying MFS is composed of acoustically transparent to semitransparent and parallel internal reflectors. GB II is interpreted as the Highstand System Tract (HST) probably deposited during the last 6,000 yrs when the sea level was close to the present level. Especially, it is though that the GB II was subdivided into two layers (GB II-a and II-b) by a HST-reflector and this was classified by wind, sea water flux, and tidal current.
The purpose of this study is to analyze the relationship of hydrochemistry, geology, fault with occurrence of uranium and radon-222 from the groundwater in the Yeongdong area. In this study, 49 groundwater and 4 surface water samples collected in the study area were collected on two separate occasions. The surface radioactivities were measured at 40 points to know the relationship between the occurrence of uranium in groundwater and surface geology. The chemical composition of groundwater showed three types : $Ca-HCO_3$, $Na-HCO_3$ and $Ca-HCO_3(SO_4,\;NO_3)$. Two groundwater of 49 samples exceeded the maximum contaminant levels of uranium, $30{\mu}g/L$, proposed by the Ministry of Environment of Korea and 11 groundwater of 40 samples for Rn-222 concentrations exceeded the 148 Bq/L maximum contaminant level of US EPA. Most of unsuitable groundwater are located in the geological boundary related with the biotite gneiss and the surface radioactivities of rock samples showed no relationship with groundwater geochemical constituents. The strike-slip fault, Youngdong fault, is $N45^{\circ}E$ direction and the high concentrations of uranium in upper part of fault, consisted of granite and granitic gneiss are detected but in lower part, consisted of metamorphic sedimentary rock are not detected. It suggests that the natural radioactive concentrations are related with the geologic characteristics and the migration and diffusion of natural radioactive materials are affected by the fault.
Kang, Hyeok Joong;Piao, Min Yu;Lee, In Kyu;Kim, Hyun Jin;Gu, Min Jeong;Yun, Cheol-Heui;Seo, Jagyeom;Baik, Myunggi
Asian-Australasian Journal of Animal Sciences
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v.30
no.4
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pp.505-513
/
2017
Objective: This study was performed to evaluate whether ambient temperature and dietary glycerol addition affect growth performance, and blood metabolic and immunological parameters, in beef cattle. Methods: Twenty Korean cattle steers ($405.1{\pm}7.11kg$ of body weight [BW], $14.2{\pm}0.15$ months of age) were divided into a conventional control diet group (n = 10) and a 2% glycerol- added group (n = 10). Steers were fed 1.6% BW of a concentrate diet and 0.75% BW of a timothy hay diet for 8 weeks (4 weeks from July 28th to August 26th and 4 weeks from August 27th to September 26th). Blood was collected four times on July 28th, August 11th, August 27th, and September 26th. Results: The maximum indoor ambient temperature-humidity index in August (75.8) was higher (p<0.001) than that in September (70.0), and in August was within the mild heat stress (HS) category range previously reported for dairy cattle. The average daily gain (ADG; p = 0.03) and feed efficiency (p<0.001) were higher in hotter August than in September. Glycerol addition did not affect ADG and feed efficiency. Neither month nor glycerol addition affected blood concentrations of cortisol, triglyceride, or non-esterified fatty acid. Blood concentrations of cholesterol, low-density lipoprotein, high-density lipoprotein, glucose, and albumin were lower (p<0.05) on August 27th than on September 26 th, and blood phosphorus, calcium and magnesium concentrations were also lower on August 27th than on September 27th. Glycerol addition did not affect these blood parameters. Percentages of $CD4^+$ T cells and $CD8^+$ T cells were higher (p<0.05) on July 28th than on August 27th and September 26th. The blood $CD8^+$ T cell population was lower in the glycerol supplemented-group compared to the control group on July 28th and August 27th. Conclusion: Korean cattle may not be significantly affected by mild HS, considering that growth performance of cattle was better in hotter conditions, although some changes in blood metabolic and mineral parameters were observed.
Agricultural sciences field in South Korea has many strong points such as numerous researchers, establishment of research infra-structure, excellence in research competitiveness and high technological level. However, there are also many weaknesses including insufficient leadership at related societies and institutes, deficiency of the next generation research group, and insufficiency in research productivity. There are many opportunities including increasing the importance of the biotechnological industry, activating international cooperation researches, and exploring the multitude of possible research areas to be studied. However, some threats still exist, such as pressure from the government of developed countries to open the agricultural market, the decrease of specialized farms, and intensification for researches to gratify economic and social demands. To encourage research activities in the agricultural sciences field in Korea, the following actions and systems are required: 1) formulation of a mid- and a long-term research master plan, 2) development of a database on the man power in related fields, 3) activation of top-down research topics, and associated increase of individual research grants, 4) development of special national programs for basic researches in agricultural sciences, 5) organization of a committee for policy and planning within the related societies, and 6) system development for the fair evaluation of the research results.
It has recently been proposed that granites can be divided into hot and cold ones by absence and presence of inherited zircon, respectively, which is closely related to zircon saturation temperature. The Phanerozoic granites in South Korea are divided into high- and low-Zr groups in a $SiO_2-Zr$ diagram, which appears to be related to their intrusive age. Most Triassic-Jurassic granites belong to low-Zr group, whereas most Cretaceous-Early Tertiary granites belong to the high-Zr group with the exception of geographically distinct Masan and Jinhae granites that belong low-Zr group. Calculated zircon saturation temperatures using major elements and Zr contents indicate that the Cretaceous-Early Tertiary granites $(608-834^{\circ}C,\;average\; 782\pm31^{\circ}C)$ except for the Masan and Jinhae granites $(average\;759\pm16^{\circ}C)$ show higher temperature than the Triassic-Jurassic granites $(642-824^{\circ}C,\;average\;756\pm31^{\circ}C)$. U-Pb zircon isotope data of the Triassic-Jurassic granites reported so far define discordia in a concordia diagram, which indicates presence of inherited zircon and agrees with their low zircon saturation temperatures. So the Triassic-Jurassic granites appear to belong to cold granite. On the other hand, presence or absence of inherited zircon has not been known for the Cretaceous-Early Tertiary granites with relatively high zircon saturation temperature, so that their classification into hot or cold granite awaits further study. Nevertheless, the Creatceous-Early Tertiary granites may have formed at higher temperature than the Triassic-Jurassic granites, since zircon saturation temperature reflects formation temperature of magma to a certain degree.
Fission-track (FT) thermochronological records from SE Korean Cretaceous-Paleogene granitic plutons in different fault-bounded blocks reveal contrasting cooling and later thermal histories. Overall cooling patterns are represented by a monotonous (J-shaped) curve in most plutons except some Cretaceous granites retaining a complicated (N-shaped) path due to post-reset re-cooling. Discriminative cooling rates over different temperature ranges can be explained for individual plutons with respect to relative pluton sizes, differences in initial heat loss depending on country rocks, and the presence and proximity of later igneous activity. Even within a single batholith, cooling times for different isotherms were roughly contemporaneous with respect to positions. Insignificant deviations in cooling ages from two different plutons in succession across the Yangsan fault may suggest their contemporaneity before major horizontal fault movement. The extent of later thermal rise recorded locally along the Yangsan and Dongnae fault zones were reached the Apatite Partial Stability Zone ($70-125^{\circ}C$), but did not exceed $200^{\circ}C$. Thermal alteration from fractured zones in the Yangsan-Ulsan fault junction may suggest a thermal reset above $290^{\circ}C$ resulting a complete reset in FT sphene age (31 Ma), caused by a tectonic subsidence in Early Oligocene. A consistency in FT zircon/apatite ages (24 Ma) may imply a sudden rapid cooling over $200-105^{\circ}C$, plausibly related to the abrupt tectonic uplift of the Pohang-Gampo Block including the fault junction in Late Oligocene. A remarkable trend of lower cooling ages for $300-200-100^{\circ}C$ isotherms (i.e., 19% for FT sphene and K-Ar biotite; 20% for FT zircon; 27% for FT apatite) from the east of the Ulsan fault (Pohang-Gampo Block) comparing to the west of the fault may be attributed to retarded cooling times from the Paleogene granites and also reflected by their partially-reduced apatite ages due to later thermal effects.
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