• Applied Chemistry for Engineering
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• v.28 no.1
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• pp.101-111
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• 2017

Mineral carbonation is a technology in which carbonates are synthesized from minerals including serpentine and olivine, and industrial wastes such as slag and cement, of which all contain calcium or magnesium when reacted with carbon dioxide. This study aims to develop the mineral carbonation technology for commercialization, which can reduce environmental burden and process cost through the reduction of carbon dioxide using steel slag and the slag reuse after calcium extraction. Calcium extraction was conducted using NH4Cl solution for air-cooled slag and convert slag, and ${\geq}98%$ purity calcium carbonate was synthesized by reaction with calcium-extracted solution and carbon dioxide. And we conducted experimentally to minimize the quantity of by-product, the slag residue after calcium extraction, which has occupied large amount of weight ratio (about 80-90%) at the point of mineral carbonation process using slag. The slag residue was used to replace silica sand in the manufacture of cement panel, and physical properties including compressive strength and flexible strength of panel using the slag residue and normal cement panel, respectively, were analyzed. The calcium concentration in extraction solution was analyzed by inductively coupled plasma optical emission spectrometer (ICP-OES). Field-emission scanning electron microscope (FE-SEM) was also used to identify the surface morphology of calcium carbonate, and XRD was used to analyze the crystallinity and the quantitative analysis of calcium carbonate. In addition, the cement panel evaluation was carried out according to KS L ISO 679, and the compressive strength and flexural strength of the panels were measured.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.12 no.3
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• pp.89-95
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• 2013

This study focused on the development on functional shoe apparatus so that the appropriate impact can be applied to the feet in order to improve the density of mineral bone at lower limbs. The model with structure proposed in this study had an effective stress about 20 to 100% higher by comparing that of the model without it among most of 15 bone extraction points. Though there is a limitation that the finite element analysis data from the human body model are not the value of mineral bone densities by measuring directly but the effective bone stresses against impact, the proposed structure is designed to influence the increase of bone mass and improve the density of mineral bone by effecting the improvement of the density of mineral bone actually.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2004.11a
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• pp.23-28
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• 2004

Various merchandises have appeared in recent markets of mineral water, beverage, food and cosmetics etc. These are almost manufactured by adding raw seawater, desalinated water, brine or salt from Deep Ocean Water(DOW), and it intimated desalination and mineral extraction are key techniques for DOW business. This study aims to verify the functional performance of mineral-controlled water produced by the basic methods which were proposed by authors for industrial purposes. This water revealed the possibility of the radical scavenging effects and moisturizing capability.

• Resources Recycling
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• v.14 no.6 s.68
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• pp.28-36
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• 2005

A hydrometallurgical process to leach cobalt from the waste cathodic active material, $LiCoO_{2}$, and subsequently to separate it by solvent extraction was developed. The optimum leaching conditions for high recovery of colbalt and lithium were obtained: 2.0 M sulfuric acid, 5 $vol.\%$ hydrogen peroxide, $75^{\circ}C$ leaching temperature, 30 minutes leaching time and an initial pulp density of 100 g/L. The respective leaching efficiencies for Co and Li were $93\%$ and $94.5\%$. About $85\%$ Co was extracted from the sulfuric acid leach liquor containing 44.72 g/L Co and 5.43 g/L Li, using 1.5 M Cyanex272 as an extractant at the initial pH 5.0 and in organic to aqueous phase ratio of 1.6:1 under the single stage extraction conditions. The Co in the raraffinate was completely extracted by 0.5 M Na-Cyanex272 at the inital pH 5.0, and an organic to aqueous phase ratio of 1;1. The cobalt sulfate solution of higher than $99.99\%$ purity could be recovered from waste $LiCoO_{2}$, using a series of hydrometallurgical processes: sulfuric acid leaching of waste $LiCoO_{2}$- solvent extraction of Co by Na-Cyanex 271 - scrubbing of Li by sodium carbonate solution - stripping of Co by sulfuric acid solution.

• Resources Recycling
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• v.13 no.5
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• pp.28-36
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• 2004

The extraction of platinum group metals such as Pt, Pd and Rh from spent automobile catalyst has been investigated by leaching in HCl solutions using $HNO_3$ or NaOCl as a oxidant. The effect of type and amount of oxidant, reaction time and pulp density on the extraction of platinum group metals was examined. Platinum group metals were recovered by the cementation method using aluminum as a reducing agent. The extraction ratio was higher when NaOCl was used as a oxidant. The optimum leaching conditions were obtained to be: HCl 8 M, the amount of NaOCl 1.4 mole, leaching temperature $90^{\circ}C$, leaching time 180 minutes, pulp density 400g/L. Under the optimum conditions, the extraction of Pt, Pd and Rh were 96.1%, 93.6% and 77.3%, respectively. With the addition of 2.0g of aluminum which corresponds to 28 equivalent the reduction were 98% for Pt. 98.8% for Pd and 65.3% for Rh, respectively.

• Korean Journal of Metals and Materials
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• v.46 no.4
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• pp.227-232
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• 2008

Solvent extraction reaction of cobalt by Alamine336 from strong hydrochloric acid solution was identified by analyzing the solvent extraction data reported in the literature. Analysis of the data by graphical method revealed that Alamine336 took part in the solvent extraction reaction as a monomer in the concentration ranges, [Co(II)] : 0.0169 - 0.102 M, [Alamine336] ; 0.02- 1.75 M, and [HCl ] : 5 - 10 M. The following solvent extraction reaction and equilibrium constant was obtained from the experimental data by considering the activity coefficients of chemical species present in the aqueous phase. $Co^{2+}+2Cl^{-}+R_3NHCl_{org}=CoCl_3\;R_3NH_{org}$, $K_{ex}=2.21$ The distribution coefficients of cobalt predicted in this study agreed well with those reported in the literature.

• Economic and Environmental Geology
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• v.57 no.2
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• pp.107-117
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• 2024

The objective of this study is to estimate riverbed fluctuations and the volume of aggregate extraction attributable to climate change. Rainfall-runoff modeling, utilizing the SWAT model based on climate change scenarios, as well as long-term riverbed fluctuation modeling, employing the HEC-RAS model, were conducted for the Nonsan River basin. The analysis of rainfall-runoff and sediment transport under the SSP5-8.5 scenario for the early part of the future indicates that differences in annual precipitation may exceed 600 mm, resulting in a corresponding variation in the basin's sediment discharge by more than 30,000 tons per year. Additionally, long-term riverbed fluctuation modeling of the lower reaches of the Nonsan Stream has identified a potential aggregate extraction area. It is estimated that aggregate extraction could be feasible within a 2.455 km stretch upstream, approximately 4.6 to 6.9 km from the confluence with the Geum River. These findings suggest that the risk of climate crises, such as extreme rainfall or droughts, could increase due to abnormal weather conditions, and the increase in variability could affect long-term aggregate extraction. Therefore, it is considered important to take into account the impact of climate change in future long-term aggregate extraction planning and policy formulation.

• Food Science and Preservation
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• v.9 no.4
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• pp.396-399
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• 2002

An attempt was made in this study to investigate the optimum extracting time from meat with bone of goat and the nutritional component of its extract. for the trials, the mixtures of meat with bone and water were adjusted to the ratios of five to four by weight and extracted for 6, 9 and 12 hours at 120$\^{C}$ under autoclave. Judging from the content of mineral and amino acid, nonenzymatic browning and yield, the optimum extracting time was 9 hours. The major components of mineral were composed of 47.7mg％ potassium, 12.7mg% calcium, 150.0mg% sodium, 105.3mg% phosphorus and 0.5mg% iron, and of amino acids composed of 1,308.0mg% glutamic acid, 1,464.2mg% glycine, 750.2mg% alanine and 828.lmg% proline in extract. The yield of extract was 32.1 percentage by dry basis.

• Resources Recycling
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• v.20 no.3
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• pp.68-76
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• 2011

For the separation of aluminum and iron from platinum mixtures, extraction resins were synthesized and separation efficiencies were compared with those by commercial one, $P_{204}$. During synthesis, the suspension polymerization method was adopted with D2EHPA as an extractant. Also, benzoyl peroxide as a starter was divided into 3parts and injected for the uniform size and dispersion of resin particles. Comparison tests resulted in 100% separation of Fe and Pt for both synthetic and $P_{204}$ resins. In case of Al and Pt, synthetic and $P_{204}$ resin gave extraction efficiencies of 99.9% and 98.9%, respectively. Difference in extractant contents of synthetic resin(61.8%) and $P_{204}$(60%) was considered to give differences in separation efficiencies of aluminum and iron elements. For both resins, separation efficiencies of Al and Fe increased up to $55^{\circ}C$. According to FT-IR analyses of both resins, specific peaks of D2EHPA and crosslinked polystyrene were identified at the wavenumber of $1000cm^{-1}$ and $2900cm^{-1}$ respectively.

• Analytical Science and Technology
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• v.9 no.2
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• pp.210-219
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• 1996

Extraction of minerals in deionized water and elimination effect of heavy metals in water by Nohwado Quartz Porphyry were examined. When the Nohwado Quartz Porphyry was immersed and stirred in deionized water at 0.5, 1.0, 1.5 and 2.0% concentration for 3 hours, various minerals concentration of the all stirred water were suitable for potable water. Particularly, when the lead, copper, cadmium and arsenic solution were shaked with Quartz Porphyry at $20^{\circ}C$ for 24 hours, the elimination rate of each mineral was 99.5, 99.9, 95.0 and 66.5%, respectively.