• Title/Summary/Keyword: Microwave synthesis

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Synthesis and Microwave Dielectric Properties of $La(Zn_{1/2}Ti_{1/2})O_3$ ($La(Zn_{1/2}Ti_{1/2})O_3$의 합성 및 고주파 유전특성)

  • 서명기;조서용;홍국선;박순자
    • Journal of the Korean Ceramic Society
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    • v.33 no.9
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    • pp.1019-1023
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    • 1996
  • The dielectric properties at microwave frequencies of B site complex perovskite La(Zn1/2Ti1/2)O3 which has +3 ion in A site were investigated. maximum Q*F value of the specimens was 59000 dielectric constant 34, temperature coefficient of resonant frequency -52 ppm/$^{\circ}C$. XRD pattern of the sintered specimen shows (111) ssuperlattice reflection which indicates Zn and Ti cation ordering.

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Solid-Phase Synthesis of 2-Arylbenzothiazole Using Silica Sulfuric Acid under Microwave Irradiation

  • Niralwad, Kirti S.;Shingate, Bapurao B.;Shingare, Murlidhar S.
    • Bulletin of the Korean Chemical Society
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    • v.31 no.4
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    • pp.981-983
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    • 2010
  • The condensation of several aromatic/heteroaromatic aldehydes with 2-aminothiophenol catalyzed by silica sulfuric acid under microwave irradiation afforded 2-arylbenzothiazoles in high yields and short reaction times under solvent-free conditions. The major advantages of the present method are good yields, ecofriendly, reusable catalyst, mild and solvent-free reaction conditions.

Montmorillonite KSF Clay as Novel and Recyclable Heterogeneous Catalyst for the Microwave Mediated Synthesis of Indan-1,3-Diones

  • Marvi, Omid;Giahi, Masoud
    • Bulletin of the Korean Chemical Society
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    • v.30 no.12
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    • pp.2918-2920
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    • 2009
  • Various indan-1,3-dione derivatives were synthesized from the reaction of different phthalic anhydrides with diethylmalonate using montmorillonite KSF clay as a recyclable heterogeneous acidic catalyst and microwave irradiation in good yields and short reaction times.

Microwave-Assisted Synthesis of Flower-like and Plate-like CuO Nanopowder and Their Photocatalytic Activity for Polluted Lake Water

  • Xu, Ling;Xu, Hai-Yan;Wang, Feng;Zhang, Feng-Jun;Meng, Ze-Da;Zhao, Wei;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.49 no.2
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    • pp.151-154
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    • 2012
  • Flower-like and plate-like CuO nanopowder has been successfully synthesized using a facile microwave-assisted synthetic route. The morphology and size of the final products strongly depended on microwave power. The phase, structures and morphologies of the as-prepared products were investigated in detail by BET surface area analysis, X-ray diffraction (XRD) analysis, and scanning electron microscopy (SEM). In addition, the chemical oxygen demand of polluted lake water was employed for characterization of these new photocatalysts. The results showed correlations between the morphology of CuO micro-crystals and their catalytic properties.

Microwave-assisted Synthesis of 2H-Benzo[b][1,4]oxazin-3(4H)-ones and 1H-Pyrido[2,3-b][1,4]oxazin-2(3H)-ones via Smiles Rearrangement

  • Hua, Zuo;Kam, Kyeong-Hee;Kwon, Hee-Jin;Meng, Lijuan;Ahn, Chul-Jin;Won, Tae-Jin;Kim, Tae-Hyun;Reddy, Ch. Raji;Chandrasekhar, S.;Shin, Dong-Soo
    • Bulletin of the Korean Chemical Society
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    • v.29 no.7
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    • pp.1379-1385
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    • 2008
  • Highly efficient synthesis of substituted benzo[1,4]oxazin-3-ones and pyrido[1,4]oxazin-2-ones under microwave irradiation via Smiles rearrangement is reported. Substituted benzo[1,4]oxazin-3-ones and pyrido[1,4]oxazin-2-ones were obtained by treatment of substituted 2-chlorophenols or 2-chloropyridols with N-substituted 2-chloroacetamide in the presence of potassium carbonate in MeCN and subsequent exposure to cesium carbonate in DMF. All the reactions which take 2-10 hours under conventional condition were completed successfully within a few minutes under microwave irradiation giving moderate to excellent yields.

Microwave Synthesis of a Porous Metal-Organic Framework, Nickel(II) Dihydroxyterephthalate and its Catalytic Properties in Oxidation of Cyclohexene

  • Lee, Ji-Sun;Halligudi, Shiva B.;Jang, Nak-Han;Hwang, Dong-Won;Chang, Jong-San;Hwang, Young-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.31 no.6
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    • pp.1489-1495
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    • 2010
  • A porous coordination solid of nickel(II) dihydroxyterephthalate has been synthesized by the microwave-assisted (MW) method. The synthesized nickel(II) dihyroxylterephthalate was designated by the general formula of [$Ni_2$(dhtp) $(H_2O)_2]{\cdot}8H_2O$ (where, dhtp = 2,5-dihydroxyterephthalate, denoted by Ni-DHTP). The effect of microwave-irradiation temperature and time of irradiation on the porosity and morphological changes in the solids have also been investigated. The catalytic performance of Ni-DHTP synthesized by MW method has been studied in the oxidation of cyclohexene with aqueous $H_2O_2$, which gave cyclohexene oxide as the primary product and 2-cyclohexene-1-ol as a major product.

Effect of Oxygen for Diamond Film Synthesis with C-Hexane in Microwave Plasma Enhanced CVD Process

  • Han, Sang-Bo
    • Journal of Electrical Engineering and Technology
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    • v.7 no.6
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    • pp.983-989
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    • 2012
  • The purpose of this paper is to decide the optimum synthesis conditions of polycrystalline diamond films according to the ratio of gas mixture. Diamond films were deposited with cyclo-hexane as a carbon precursor by the microwave plasma enhanced chemical vapor deposition process. The optimum oxygen ratio to cyclo-hexane was reached about 125 % under the fixed 0.3% c-hexane in hydrogen. Oxygen plays a role in etching the graphitic components of carbon sp2 bond effectively. By OES measurement, the best synthesis conditions found out about 12.5 % and 15.75 %, which is the emission intensity ratios of CH(B-X) and $H{\beta}$ on $H{\alpha}$, respectively. Also, the electron temperature was similar about 5,000 to 5,200 K in this work.

Design of the microwave narrow-band waveguide bandpass filters for MDR (Microwave Digital Relay) system using the modified double E-plane structures (수정된 이중 E-평면 구조를 이용한 MDR(Microwave Digital Relay)장비용 마이크로파대 협대역 도파관형 대역통과 여파기의 설계)

  • 임재봉;박준석
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.32A no.7
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    • pp.36-42
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    • 1995
  • In this paper, the CAD program for designing the microwave waveguide narrow-band bandpass filters has been developed by the passband correction method with filter synthesis for the MDR(Microwave Digital Relay) system. Here, the modified double E-plane structures are employed in the filter structure which is analyzed by the variational method. Using the developed CAD program, 0.01dB equi-ripple chebyshev type 6-section bandpass filters used in the MDR system operating nationally is designed at the center frequency of 11.0GHz, fabricated with tunable type and then measured by tuning process. The experimantal results show good agreements with the theoretical results.

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Microwave Induced Reduction/Oxidation Reaction by SHS Technique (마이크로파를 이용한 SHS 방법에 의한 분말의 산화-환원반응)

  • 김석범
    • Korean Journal of Crystallography
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    • v.9 no.1
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    • pp.44-47
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    • 1998
  • A reduction/oxidation reaction between A1 metal powder and SiO2 powder was performed by Self-propagating High-temperature Synthesis (SHS) reaction induced by microwave energy to produce a composite of Al2O3 and Si powders by using a 2.45 GHz kitchen model microwave oven. A Microwave Hybrid Heating(MHH) method was applied by using SiC powders as a suscepting material to raise the temperature of the disk samples and the heat increase rate of over 100℃/min were obtained before the reaction. The reaction started around 850℃ and the heat increase rate jumped to over 200℃/min after the reaction took place.

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