• Korean Journal of Materials Research
• /
• v.9 no.8
• /
• pp.804-809
• /
• 1999

Silica films were prepared on Si single crystal substrates by a sol-gel process without DMF using TEOS as a starting material. Films were fabricated by spin coating technique. For films having a composition of TEOS : HCI(1:0.05mol), gelation time, the thickness of films, the formation of cracks and the microstructure of the films were investigated as a function of the molar ratio of $CH_3OH and H_2O$. With 8mol $CH_3OH$, the longest gelation time was measured to be 640hr. The thickness of the coated films was decreased with increasing content of $CH_3OH$. The films were sintered at $500^{\circ}C$ for 1hr with a heating rate of $0.6^{\circ}C$/min. The coated films showed worm-like grains and partially cracked microstructures at an amount of $CH_3OH$ 2mol and 4mol. The addition of more than 8 mole of $CH_2OH$ resulted in crack-free silica films. This suggests that crack-free films can be fabricated by controlling the surface tension energy of the sol solutions without DMF.

• Korean Journal of Materials Research
• /
• v.10 no.7
• /
• pp.464-470
• /
• 2000

The compacting and sintering behavior of titanium powders containing oxygen in the range of 1980~8450 ppm was examined. The powders were prepared by the hydride-dehydride (HDH) and by the deoxidation by solid state(DOSS) methods. Their compaction density ranged from 69.0% to 62.3% and decreased with the increase in the oxygen content. It was explained by the effect of oxygen on the hardness of powders. Unlike the compaction density, the oxygen content did not affect the apparent density greatly being 90.5$\pm$0.5% after sintering at $1100^{\circ}C$ for 2 hours. Their average grain size was $60\mu\textrm{m}$ and the size and distribution of pores were about the same for all cases. The hardness of sintered samples showed a linear increase with oxygen and could be expressed as VHN(sintered)= 135.5+64.3$\times$$(wt{\%}O_2)$ The exami-nation of fracture surface revealed that the ductile-brittle transition occurs at oxygen contents of 2987~5582 ppm.

• Korean Journal of Materials Research
• /
• v.10 no.7
• /
• pp.515-521
• /
• 2000

The effect of precipitates on the high temperature tensile properties of cast alloy 718 was investigated by phase extraction method and microstructural observation. The value of tensile strength and elongation gradually decreased with increasing testing temperature up to $760^{\circ}C$. Elongation of the alloy increased, while tensile strength decreased above 76$0^{\circ}C$. The amount of precipitates in the specimen that tensile tested at $760^{\circ}C$ showed maximum owing to stress assisted precipitation. Therefore, the alloy exhibited the lowest value of the elongation and the degree of decrease in yield strength at this temperature due to high flow stress of precipitates. Little amount of precipitate, especially $\gamma$' and $\gamma$＂, resulted in softening of the alloy at the temperature above $760^{\circ}C$.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.17 no.8
• /
• pp.706-713
• /
• 2016

In this study, the welding characteristics of friction stir welding were investigated in accordance with the tool plunge position and cooling to the base materials for the joining of dissimilar materials (A6005-AZ61). Other different welding conditions, such as the tool rotation speed and welding speed, were fixed to 500rpm-30mm/min, respectively, and welding was then carried out by placing the Mg alloy (AZ61) on the advancing side and Al alloy(A6005) on the retreating side. Welding was conducted under six different conditions. To investigate the welding characteristic, tensile test and microstructure observations using an optical microscope were carried out. As the tensile test result, the maximum strength appeared under the condition in which the tool is moved 1 mm to the Mg alloy direction and cooling to the base materials. Under the same welding conditions, the strength with cooling was approximately two times higher than that without cooling. The tool was located in each direction of 1.7 mm from the weld line. Therefore, in the excessive off-set of tool position, the welding integrity was in an extremely poor condition due to the lack of stirring. This study was confirmed by the A6005-AZ61 dissimilar friction stir welding the welding speed and the tool rotation speed. In addition, the temperature control and tool plunge position are important welding parameters.

• Proceedings of the Korean Institute of Resources Recycling Conference
• /
• 2004.12a
• /
• pp.27-34
• /
• 2004

This experiment was carried out to examine the effects of morphology on properties of La-Co substituted SrM ferrite. The magnetic properties of calcined and sintered materials varied with the substitutional amount of La and Co elements in Sr-ferrite. In the substituted SrM ferrite, the atomic fraction x of La is directly related to the mole ratio n of iron oxide and the atomic fraction y of Co by equation x=2ny. The HcJ values of the calcined powder were about 270 kA/m and 240 kA/m with x=0.3 and K=0.2, respectively at stoichiometriy, n=6.0. Crystallites of the sintered material were grown with a plate shape, and their size decreased with increasing mole ratios. Such a shape was caused by the initial state of crystallite formed after calcination. In case of x=0.3 and n=6.0, Br was 415 mT and HcJ was 355 kA/m, and in x=0.2 and n=6.0, Br was 410 mT and HcJ was 370kA/m. The squareness in 2nd quarter of BH curve with x=0.2 was smoothly improved compared with x=0.3

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.13 no.9
• /
• pp.735-744
• /
• 2000

The electrical procerties and stability of ZnO-Pr$_{6}$O$_{11}$-CoO-Cr$_2$O$_3$-Er$_2$O$_3$ (ZPCCE) based varistors were investigated in the Er$_2$O$_3$content range of 0.0 to 4.0 mol%. ZPCCE ceramics containing 2.0 mol% Er$_2$O$_3$ exhibited the highest density of 5.74 g/㎤ corresponding to 99.3% of theoretical density. The varistors with 0.5 mol% and 2.0 mol% Er$_2$O$_3$exhibited a relatively satisfying nonlinearity, which the nonlinear exponent is 40.50 and 47.15, respectively and the leakage current is 2.66 $mutextrm{A}$, respectively. Under more severe d.c. stress, such as (0.80 V$_{1mA}$/9$0^{\circ}C$/12h)+(0.85 V$_{1mA}$115$^{\circ}C$/12h)+(0.90 V$_{1mA}$12$0^{\circ}C$/12h)+(0.95 V$_{1mA}$1$25^{\circ}C$12h), they showed a very excellent stability, which the variation rate of the variator voltage is -0.89% and -0.15%, the variation rate of the nonlinear coefficient is -4.67% and -3.56%, and the variation rate of leakage current is -6.02% and -19.56%, respectively. It is surely bellived that ZnO-0.5 mol% Pr$_{6}$O$_{11}$-1.0 mol% CoO-0.5 mol% Cr$_2$O$_3$-x mol% Er$_2$O$_3$(x=0.5, 2.0) based varistors will be greatly contributed to develop the advanced Pr$_{6}$O$_{11}$-based ZnO varistors in future.uture. future.uture.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.21 no.4
• /
• pp.588-595
• /
• 2020

This study examined the catalytic property of Ni-catalyst used in the gas purifying process to manufacture inert gases of N2 and Ar with high-purity over 9N for semiconductor industrial applications. Two types of Ni-catalysts with a cylindrical shape (C1) and churros shape structure (C2) were compared for the assessment. Optical microscopy and FESEM were used to analyze the shape and microstructure of the Ni-catalyst. EDS, XRD, and micro-Raman characterization were performed to examine the composition and properties. BET and Pulse Titration analyses were conducted to check the surface area and catalytic property of the Ni-catalyst. From the composition analysis results, C1 contained a relatively large amount of graphite as an impurity, and C2 contained higher Ni contents than C1. From specific surface area analysis, the specific surface area of C2 was approximately 1.69 times larger than that of C1. From catalytic property analysis, outstanding performance in O₂ and CO impurity removal was observed at room temperature. Therefore, C2, having low-impurity and large specific surface area, is a suitable catalyst for the high-purity inert gas process in the semiconductor industry because of its outstanding performance in O₂ and CO impurity removal at room temperature.

• Journal of Conservation Science
• /
• v.27 no.4
• /
• pp.421-430
• /
• 2011

Thermal conditions in practice at the traditional bronze workshop of the Korean Folk Village in Yongin were examined along with the microstructures of some high tin bronze objects made there. Laboratory experiments approximating the conditions of the workshop were also carried out and the results were compared. The operating temperature of the workshop furnace was measured to range from $750^{\circ}C$ to $850^{\circ}C$ while the surface temperature of an object, upon its removal from the furnace for additional thermo-mechanical treatments, was generally in the range of $600^{\circ}C$ to $685^{\circ}C$. This variation in working temperatures was reflected in varying microstructures developed upon quenching. The products of the Folk Village were found to consist of microstructures where the ${\alpha}$ grains of the Cu-Sn system were distributed in the background of different phases including the ${\beta}$-martensite phase, retained ${\gamma}$ phase, ${\alpha}+{\delta}$ eutectoid or their mixtures. This variability, which is also identified in objects made in ancient times as well as in our laboratory experiments, suggests that the actual thermal conditions given during the quenching treatments are much more complicated than is inferred from the temperature measurements. This paper will present detailed accounts of the thermo-mechanical treatments as observed in the high tin bronze workshop of the Korean Folk Village and discuss the evolution of varying microstructures in terms of the substantial variability involved in the implementation of the traditional forged high tin bronze technology of Korea.

• Journal of Conservation Science
• /
• v.29 no.2
• /
• pp.139-147
• /
• 2013

This study focused on iron making related information through analyzing slags and furnace wall collected from iron production site of Suryong-ri Wonmorongi, Chungju. Total Fe content of slags were from 36.98% to 44.47% and this range was general recovery rate of iron in ancient. Compounds of calcium included slags was supposed to add intentionally during smelting process as deoxidation agent in order that these helped to separate iron from impurities. Furnace wall didn't make of high alumina clay because of low $Al_2O_3$. Microstructure and main components of slags show that No. 1 to 3 slags with fayalite and wustite were products of iron ore smelting. However, No.4 slag is more likely to smelt by iron sand because of ulvospinel with $TiO_2$ in No. 4 slag. Therefore, iron ore were not only used but iron sand in smelting and furnace wall made of general clay with low $Al_2O_3$ content in this area.

• Journal of Conservation Science
• /
• v.33 no.3
• /
• pp.155-165
• /
• 2017

As interest in the public display of art and outdoor sculptures is increasing, the conservation and treatment of these sculptures is becoming increasingly crucial. Long-term exposure to the natural elements and atmospheric pollution can cause corrosion and deterioration in outdoor sculptures. In the case of Kim Chan Shik's "Feeling", which was exhibited in the outdoor sculpture park at the National Museum of Modern and Contemporary Art (MMCA), the patina of the sculpture was damaged during a long outdoor exhibition. Therefore, the treatment process was as follows: recording of condition, sanding, repatination, and wax coating. Consequently, the sculpture was restored similar to the original. Chemical analysis revealed that the sculpture was crafted from bronze and was cast from a quaternary alloy of Cu-Pb-Sn-Zn. The welding is lower in Zn, Sn, and Pb content than the metal used in the sculpture itself. Bright strains contain about 13.0 wt% Sn and 10.5 wt% Pb. The strains are higher in Sn and Pb content than the rest of the metal in the sculpture (7.0 wt% Sn and 4.4 wt% Pb). As a result of component analysis and microstructure observation, the material is estimated to have been made by casting without artificial treatment.