• Title/Summary/Keyword: Micro pore

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Effect of KOH Addition on Pore Structure of Glassy Carbon Prepared by Polymerization of Phenolic Resin (KOH 첨가에 의한 페놀수지로 제조된 유리상탄소의 미세구조제어)

  • 김지현;박세민;임연수;박홍수;김명수
    • Polymer(Korea)
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    • v.26 no.4
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    • pp.477-482
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    • 2002
  • In order to control the micro-pore structure of glassy carbon (GC), an activation agent of KOH was introduced as the glassy carbon was prepared from phenolic resin with a curing agent of phosphoric acid. The yield and properties of GC were investigated as a function of KOH content. Although the GC produced without KOH had nonporous structure except the trace of bubble formation, the GC with KOH had very porous structure. The surface area of GC with KOH increased continuously up to 870 $m^2$/g with the increase of KOH content. The carbonization yield and apparent density measured in water reduced from 40 to 15% and iron 1.5 to 0.9 g/$cm^3$, respectively, and the electrical resistivity increased from $50{\times}10^{-4}$ to $60{\times}10^{-4}$$\Omega$.cm with the increase of KOH content.

Fabrication of Fe Foam using Slurry Coating Process (슬러리 코팅 공정을 이용한 Fe 폼의 제조에 대한 연구)

  • Yun, Jung-Yeul;Park, Dahee;Yang, Sangsun;Wang, Jei-Pil
    • Resources Recycling
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    • v.26 no.6
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    • pp.97-101
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    • 2017
  • Metal foams have a cellular structure consisting of a solid metal containing a large volume fraction of pores. In particular, open pores which are penetrable pores are necessary for industrial applications such as in high temperature filters and as support for catalysts. In this study, Fe foam with greater than 90% porosity and 2-mm pore size was successfully fabricated using a slurry coating process and the pore properties were characterized. The Fe and $Fe_2O_3$ powder mixing ratios were controlled to produce Fe foam samples with different pore sizes and porosity. First, the slurry was prepared through the uniform mixing of powders, distilled water, and polyvinyl alcohol(PVA). The amount of slurry coated with the PU foam increased with increasing $Fe_2O_3$ mixing powder ratio, but the shrinkage and porosity of the Fe foams decreased, respectively, with increasing $Fe_2O_3$ mixing powder ratio.

Fabrication of Nanopatterns for Biochip by Nanoimprint Lithography (나노임프린트를 이용한 바이오칩용 나노 패턴 제작)

  • Choi, Ho-Gil;Kim, Soon-Joong;Oh, Byung-Ken;Choi, Jeong-Woo
    • KSBB Journal
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    • v.22 no.6
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    • pp.433-437
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    • 2007
  • A constant desire has been to fabricate nanopatterns for biochip and the Ultraviolet-nano imprint lithography (UV-NIL) is promising technology especially compared with thermal type in view of cost effectiveness. By using this method, nano-scale to micro-scale structures also called nanopore structures can be fabricated on large scale gold plate at normal conditions such as room temperature or low pressure which is not possible in thermal type lithography. One of the most important methods in fabricating biochips, immobilizing, was processed successfully by using this technology. That means immobilizing proteins only on the nanopore structures based on gold, not on hardened resin by UV is now possible by utilizing this method. So this selective nano-patterning process of protein can be useful method fabricating nanoscale protein chip.

Physical Properties of Polymer Concrete Composite Using Rapid-Cooled Steel Slag (I) (Use of Rapid-Cooled Steel Slag in Replacement of Fine Aggregate) (급냉 제강슬래그를 사용한 폴리머 콘크리트 복합재료의 물성(I) (잔골재를 급냉 제강슬래그로 대체 사용))

  • Hwang, Eui-Hwan;Lee, Choul-Ho;Kim, Jin-Man
    • Applied Chemistry for Engineering
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    • v.23 no.2
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    • pp.210-216
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    • 2012
  • For the recycling of rapid-cooled steel slag, various specimens were prepared with the various replacement ratios of the rapid-cooled steel slag and the addition ratios of polymer binders. The physical properties of these specimens were then investigated by absorption test, compressive strength test, flexural strength test and hot water resistance test, and the pore and the micro-structure analysis was performed using scanning electron microscope. Results showed that the flexural strength increased with the increase of rapid-cooled steel slag and polymer binder, but the compressive strength showed a maximum strength at a certain proportion. By the hot water resistance test, compressive strength and flexural strength decreased remarkably and the total pore volume increased but the pore diameter decreased. SEM observation of the structure before the hot water resistance test revealed a very compact infusion of structure but the decomposition or thermal degradation appeared in polymer binders when observed after the hot water resistance test.

Development of a Pipe Network Fluid-Flow Modelling Technique for Porous Media based on Statistical Percolation Theory (통계적 확산이론에 기초한 다공질체의 유동관망 유동해석 기법 개발)

  • Shin, Hyu-Soung
    • The Journal of Engineering Geology
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    • v.23 no.4
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    • pp.447-455
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    • 2013
  • A micro-mechanical pipe network model with the shape of a cube was developed to simulate the behavior of fluid flow through a porous medium. The fluid-flow mechanism through the cubic pipe network channels was defined mainly by introducing a well-known percolation theory (Stauffer and Aharony, 1994). A non-uniform flow generally appeared because all of the pipe diameters were allocated individually in a stochastic manner based on a given pore-size distribution curve and porosity. Fluid was supplied to one surface of the pipe network under a certain driving pressure head and allowed to percolate through the pipe networks. A percolation condition defined by capillary pressure with respect to each pipe diameter was applied first to all of the network pipes. That is, depending on pipe diameter, the fluid may or may not penetrate a specific pipe. Once pore pressures had reached equilibrium and steady-state flow had been attained throughout the network system, Darcy's law was used to compute the resultant permeability. This study investigated the sensitivity of network size to permeability calculations in order to find out the optimum network size which would be used for all the network modelling in this study. Mean pore size and pore size distribution curve obtained from field are used to define each of pipe sizes as being representative of actual oil sites. The calculated and measured permeabilities are in good agreement.

Physical properties of PU coated fabric with collagen (콜라겐을 첨가한 폴리우레탄 코팅직물의 물성)

  • 백천의;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.6
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    • pp.800-808
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    • 1999
  • The demand for PU coated synthetic leather is increasing as a high fashion material. But it has some faults of water vapor permeability surface tacky property and static electricity. Therefore the purpose of this study was the produce of PU coated fabric added collagen with hydrophilic property and soft touch. In the PU coated fabric water vapor permeability water vaper absorption and frictional electronic voltage were investigated surface bending and compression properties were also examined by the use of KES-FB System. The followings were the results of this study. 1. There was no Cr in the collagen so that Cr was not treated in the collagen. 2. The surface and cross sectional layer of PU coated fabric with collagen were highly developed by micro porous structure. 3. The water vapor permeability of PU coated fabric was increased as collagen concentration increased. 4. The water vapor absorption of PU coated fabric was increased as collagen concentration increased. 5. The frictional electronic voltage of PU coated fabric was decreased in accordance with the increase of collagen concentration. Especially it effectively decreased by the use of only 5% collagen concentration. 6,. The bending and compression properties of PU coated fabric were increased in accordance with the increase of collagen concentration so that it became stiff. 7. The Value of MIU, SMD was decreased in accordance with the increase of collagen concentration so that the PU coated fabric became smooth.

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Improvement of mechanical properties of interior fabric using soluble micro-fiber and low melting PET (용출형 극세사와 저온 융착사를 이용한 인테리어 직물의 기계적 물성 개선)

  • Kwon, Yoon-Jung;Ahn, Young-Moo
    • Journal of Fashion Business
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    • v.13 no.1
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    • pp.82-90
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    • 2009
  • This research was made to manufacture the fabric for interior uses by spinning a low melting mono 4 denier PET staple fiber with a soluble 1.4 denier fine PET fiber. The blended yarn has a thickness ranging from 10's to 14's, and the soluble PET fine fiber was dissolved to make a pore in the polymer. Thereby a snap property was decreased and a resilience property was improved to be suitable for a functional synthetic leather. In order to attain the optimum condition, a mechanical property according to fineness, and mixing ratio of low melting polymer, warp density, weft density and blending ratio, and a heat contraction ratio according to blending ratio were experimented. The warp density, 220 T/inch of fine denier PET and the weft density, 64 T/inch of thick denier PET were generated to 4/4 both twill weave fabric having constant tensile property and thickness.

Effects of Powder Melting Degree on Microstructural Features of Plasma Sprayed Y2O3 Coating (플라즈마 제트에서의 분말 용융특성에 따른 Y2O3 코팅층의 미세조직 형성거동)

  • Kang, Sang-Woon;Baik, Kyeong-Ho
    • Korean Journal of Materials Research
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    • v.26 no.5
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    • pp.229-234
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    • 2016
  • In this study, the degree of particle melting in $Y_2O_3$ plasma spraying and its effects on coating characteristics have been investigated in terms of microstructural features, microhardness and scratch resistance. Plasma sprayed $Y_2O_3$ coatings were formed using two different powder feeding systems: a system in which the powder is fed inside the plasma gun and a system in which the powder is fed externally. The internal powder spraying method generated a well-defined lamellae structure that was characterized by a thin porous layer at the splat boundary and microcracks within individual splats. Such micro-defects were generated by the large thermal contraction of splats from fully-molten droplets. The external powder spraying method formed a relatively dense coating with a particulate deposition mode, and the deposition of a higher fraction of partially-melted droplets led to a much reduced number of inter-splat pores and intra-splat microcracks. The microhardness and scratch resistance of the $Y_2O_3$ coatings were improved by external powder spraying; this result was mainly attributed to the reduced number of micro-defects.

BMP-2 Immoblized in BCP-Chitosan-Hyaluronic Acid Hybrid Scaffold for Bone Tissue Engineering

  • Nath, Subrata Deb;Abueva, Celine;Sarkar, Swapan Kumar;Lee, Byong Taek
    • Korean Journal of Materials Research
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    • v.24 no.12
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    • pp.704-709
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    • 2014
  • In this study, we fabricated a novel micro porous hybrid scaffold of biphasic calcium phosphate (BCP) and a polylectrolyte complex (PEC) of chitosan (CS) and hyaluronic acid (HA). The fabrication process included loading of CS-HA PEC in a bare BCP scaffold followed by lypophilization. SEM observation and porosimetry revealed that the scaffold was full of micro and macro pores with total porosity of more than 60 % and pore size in the range of $20{\sim}200{\mu}m$. The composite scaffold was mechanically stronger than the bare BCP scaffold and was significantly stronger than the CS-HA PEC polymer scaffold. Bone morphogenetic growth factor (BMP-2) was immobilized in CS-HA PEC in order to integrate the osteoinductive potentiality required for osteogenesis. The BCP frame, prepared by sponge replica, worked as a physical barrier that prolonged the BMP-2 release significantly. The preliminary biocompatibility data show improved biological performance of the BMP-2 immobilized hybrid scaffold in the presence of rabbit bone marrow stem cells (rBMSC).

A study of Frictional Behavior of SCM415 Steel as a Function of Density of Micro Dimples (미세 딤플의 밀도에 따른 SCM415강의 마찰 거동 연구)

  • Cho, Min-Haeng;Lee, Seung-Hyuk;Park, Sang-Il;Lyo, In-Woong
    • Tribology and Lubricants
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    • v.26 no.6
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    • pp.311-316
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    • 2010
  • Surface texturing of micro dimple or pore-shaped pattern was prepared using a fiber laser system. Surface texturing was designed to have a square pattern with a particular pitch distance for each corresponding density of 5, 10, 20, and 30%. Thermal damages such as bulges and burrs formed during laser irradiation were observed around the dimples. Thermal damages were later removed by lapping using alumina particles of $0.3{\mu}m$ in diameter. Oscillating friction tests were performed against heat-treated high speed steels under lubricated condition. The lubricant used was SAE 5W-30 automotive engine oil. Normal contact pressure and oscillating frequency was 0.28 MPa and 20 Hz, respectively. The tests were continued for 20 minutes, and friction plots were recorded for examination. Results revealed that the coefficient of friction was lowered regardless of texturing density. Moreover, the lowest coefficient of friction was obtained for 10% density texturing. It is attributed to increased lubricity due to the introduction of surface texturing. In addition, it is concluded that the optimum texturing density and pattern must be found for the best lubricity and low friction.