• Transactions of the Korean Society of Mechanical Engineers A
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• v.23 no.11 s.170
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• pp.2014-2021
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• 1999

The present investigation is concerned with the degradation characteristics of cast stainless steel(CF8M), exposed to the $\sigma$-phase degradation at $700^{\circ}C$. In the present paper, the degradation of CF8 M at $700^{\circ}C$ is evaluated by a non-destructive test, DL-EPR(double loop electrochemical potentiokinetic reactivation). The surface of specimens is observed by using scanning electron microscopy after DL-EPR test. Also. chromium contents of matrix, grain boundary and ferrite phase are analyzed by electron probe X-ray micro analyzer. Through the experiments, the following results are obtained 1) The degree of sensitization(DOS) of CF8M aged up to 15hr at $700^{\circ}C$ is increased with acing time while that is decreased with aging time from 15hr to 150hr. 2) The impact energy decreases with increase of $\sigma$-phase while DOS increases with $\sigma$-phase until aging time reaches to 15hr. After the aging time. 15hr, the $\sigma$-phase and the rate of impact energy with respect to aging time decreases. Therefore the degradation behavior of the CF8M can be evaluated by comparing SEM micrographs and the value of DOS.

• Bulletin of the Korean Chemical Society
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• v.35 no.12
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• pp.3576-3582
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• 2014

Zeolite-templated carbons (ZTCs), which have high specific surface area, were prepared by a conventional templating method using microporous zeolite-Y for catalyst supports in direct methanol fuel cells. The ZTCs were synthesized at different temperatures to investigate the characteristics of the surface produced and their electrochemical properties. Thereafter, Pt-Ru was deposited at different carbonization temperatures by a chemical reduction method. The crystalline and structural features were investigated using X-ray diffraction and scanning electron microscopy. The textural properties of the ZTCs were investigated by analyzing $N_2$/77 K adsorption isotherms using the Brunauer-Emmett-Teller equation, while the micro- and meso-pore size distributions were analyzed using the Barrett-Joyner-Halenda and Harvarth-Kawazoe methods, respectively. The surface morphology was characterized using transmission electron microscopy and inductively coupled plasma-mass spectrometry. The electrochemical properties of the Pt-Ru/ZTCs catalysts were also analyzed by cyclic voltammetry measurements. From the results, the ZTCs carbonized at $900^{\circ}C$ show the highest specific surface areas. In addition, ZTC900-PR led to uniform dispersion of Pt-Ru on the ZTCs, which enhanced the electro-catalytic activity of the Pt-Ru catalysts. The particle size of ZTC900-PR catalyst is about 3.4 nm, also peak current density from the CV plot is $12.5mA/cm^2$. Therefore, electro-catalytic activity of the ZTC900-PR catalyst is higher than those of ZTC1000-PR catalyst.

• Journal of the Korean Society for Heat Treatment
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• v.13 no.5
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• pp.309-317
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• 2000

Demand for new nondestructive evaluations is growing to detect tensile crack growth behavior to predict long term performance of materials and structure in aggressive environments, especially when they are in non-visible area. Acoustic emission technique is well suited to these problems and has drawn a keen interests because of its dynamic detection ability, extreme sensitivity and location of growing defects. In this study, we investigated the strength of fire resistance steel for frame structure by tensile test after degradation treatment and analysed acoustic emission signals obtained from tensile test with time frequency analysis methods. In the T and TN specimens(under $600^{\circ}C$-10min ) consisting of ferrite and pearlite structure, most of acoustic emission events were produced near yield point, mainly due to the dislocation activities during the deformation. However, B specimen under $600^{\circ}C$-10min had a two peak which was attribute to the presence of martensite phase. The first peak is before yield point and the second after yield point. The sources of second acoustic emission peak were the debonding of martensite-martensite interface and the micro-cracking of brittle martensite phase. In $600^{\circ}C$-30min to $700^{\circ}C$-60min, many signals were observed before yield point and were decreased after yield point.

• Journal of Korean Society of Water and Wastewater
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• v.14 no.1
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• pp.84-98
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• 2000

Control of Trihalomethanes(THMs) is a major concern of many water treatment plants. A number of researchers have studied the effectiveness of activated carbon adsorption process in removing THMs or organic halogen compounds. Recently, attention has been paid to the biological activated carbon (BAC) treatment of THM precursors as an alternative to the carbon adsorption treatment because of its effectiveness as well as its low running cost. In this study, changes of THM formation potential(THMFP) and removal of substrates in the SBR effluent were investigated in an attempt to clarify the mechanisms of the decrease/increase of THMFP in the BAC treatment. The increase and decrease of THMFP concentrations were observed in effluents during prolonged operation. When PCP or DBS was feeded as substrate contained in SBR effluent, the THMFPs were easyly removed with TOCs removal. But the case of SBR effluent containing SDS or glycine was introduced, and when microbial growth came to its near steady state, the THMFPs of treated effluents were increased more or less in comparison to those in the influents. Such increases of THMFP coincided with the increase in microbial growth within the activated carbon fiber(ACF) column. In the case of only sucrose was feeded as substrate on ACF colume, THMFP concentrations of effluent were higher than those of influent. The THMFP concentration was significantly increased on inlet part of ACF column, which biomass inhabits abundantly, then they were decreased gradually. These increases mean production of the secondary THM precursors by biological activities, which can be removed by adsorption and biological degradation on ACF column.

• Journal of Korean Association for Spatial Structures
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• v.10 no.2
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• pp.61-68
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• 2010

The collapsing accidents of pipe greenhouses in the farmhouse have been increased duo to heavy snow load. However, the study on exact structure analysis to prevent the collapse of pipe greenhouses is rare and the damage of the farmhouse is annually repeated. The method of existing structure analysis is basically made of linear elastic analysis based on the micro displacement. But the actual stiffness of the pipe greenhouse is significantly weaker than the stiffness of buildings and the load acting on the greenhouses gets to become relatively bigger. It means that the geometry shape of greenhouses changes so that the relation of strain-displacement gets to indicate a nonlinear behavior. Therefore, this study is performed to evaluate the structural safety so as to prevent the collapse of pipe greenhouses, which are the single-span greenhouse(farmhouse guidance shape, G) and multi-span greenhouse(farmhouse supply shape, 1-2W), by performing the large-displacement analysis considering nonlinear effects.

• Journal of the Korean Ceramic Society
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• v.49 no.2
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• pp.173-178
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• 2012

The $Y_2O_3$ ceramics have been widely used as plasma resistant materials in the semiconductor industry. In this study, composites made of plasma resistant $Y_2O_3$ and electrically conductive carbon have been produced. The electrical properties of this composite were measured with respect to the size, volume fraction of the conductive carbon phase, and sintering temperature. When micro-sized carbon was used, the composites were insulating up to 5 wt% addition of the carbon. However, when nano-sized carbon of around 60 ~100 nm was used, the composites became conductive over threshold volume fraction of carbon, which increased with increasing sintering temperature. This behavior of electrical conductivity of the composites was discussed in terms of the percolation theory. The percolation threshold of the conductivity seemed to be affected by the grain growth and coalescences of dispersed conductive carbon phases with grain growth of matrix $Y_2O_3$.

• Journal of the Korean Geotechnical Society
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• v.21 no.2
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• pp.5-16
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• 2005

Tn this study, model soil deposits are prepared in large test chambers to minimize the scale effects. Also, slurry of mixture containing 50 percent kaolin clay and 50 percent silica has been consolidated to simulate the process of natural soil deposit formation and to reduce the consolidation time. To provide a more detailed description of varying soil properties along the soil profile of model clay deposits and to compare the in-situ test results with those from prototype tests, miniature in-situ tests, including vane shear, piezoprobe, and cone penetration tests were conducted in each of the clay deposits. The current results indicate that consistent soil deposits were prepared for the current and previous test programs. Also, reasonable predicting methods of prototype behavior based on model in-situ test results were suggested in this study by examining differences between the test results from both the model and prototype tests.

• The Journal of the Korea Contents Association
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• v.16 no.4
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• pp.114-122
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• 2016

Concrete is cost-benefit and high-durable construction material, however durability problem can be caused due to steel corrosion under chloride attack. Recently deicing salt has been widely spread in snowing season, which accelerates micro-cracks and scaling in surface concrete and the melted deicing salt causes corrosion in embedded steel. The previous governing equation of Fick's 2nd Law cannot evaluate the deteriorated surface concrete so that another technique is needed for the surface effect. This paper presents chloride penetration analysis technique for concrete subjected to deicing salt utilizing multi-layer diffusion model and time-dependent diffusion behavior. For the work, field investigation results of concrete pavement exposed deicing salt for 18 years are adopted. Through reverse analysis, deteriorated depth and increased diffusion coefficient in the depth are evaluated, which shows 12.5~15.0mm of deteriorated depth and increased diffusion coefficient by 2.0 times. The proposed technique can be effectively applied to concrete with two different diffusion coefficients considering enhanced or deteriorated surface conditions.

• Proceedings of the KOSOMBE Conference
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• v.1997 no.11
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• pp.337-342
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• 1997

Dental implant has been increasingly used to recover the masticatory unction of tooth. It has been well known that the success of dental implant is heavily dependent on initial stability and long-term osseointegration due to optimal stress distribution in the surrounding bones. The role of periodontal ligament, removed during operation, is to absorb impact force and to distribute them to alveolar bone. or this reason, the study for artificial periodontal ligament has become an important issue in this field. In this study, chitosan was coated on dental implant or the purpose of replacing the role of intact periodontal ligament. The results by experiment and FEM analysis showed : I) Initial stability of dental implant was significantly increased(35%) when the implant was coated with chitosan. II) The coated implant showed higher impact absorption, more even stress distribution and lower stress magnitude under impact force than uncoated implant. Accordingly, the micro-fracture of the surrounding bones due to impact force would be lessened by chitosan coating on dental implant.

• Explosives and Blasting
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• v.29 no.1
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• pp.34-40
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• 2011

In this study, effects that thermal stress and water pressure have on the deformation behaviour of granite specimens recovered in Gagok Mine are estimated. To analyze effects of the thermal stress and water pressure on the deformation behaviour, granite specimens were preheated with cycles of predetermined temperatures ranging $200^{\circ}C$ to $700^{\circ}C$ and 500, 600, $700^{\circ}C$ specimens were pressurized to 7.5 MPa. The deformation behaviour of the specimens had been studied by performing uniaxial compressive tests. Axial and lateral strains of specimens were found to increase with increasing temperature, and above $600^{\circ}C$, the increase of strains were more pronounced. The reduction trends of uniaxial compressive strength and Young's modulus with temperature appeared to follow an exponential decay function. Specimens under water pressure showed the more inelastic deformation characteristics, which means that water pressure has an effect on the widening and extending of micro-cracks existed in preheated specimens.