• Proceedings of the Materials Research Society of Korea Conference
• /
• 2011.10a
• /
• pp.33.2-33.2
• /
• 2011

고온형 SOFC의 개발에 있어 스택의 신뢰성을 확보하는데 가장 중요한 핵심기술은 스택 구성요소 사이를 접합하는데 필요한 고온형 밀봉재의 개발이다. SOFC 스택에서의 밀봉재는 고체전해질과 접속자 사이에서 음극에 공급되는 연료가스와 양극에 공급되는 공기가 서로 혼합되는 것을 방지하는 역할은 물론 기계적으로 취약한 단전지의 보호 및 스택전체 구조물의 구조적 일체성(Structural integrity)을 부여하는데 주목적이 있다. 현재 기체 기밀성을 유지하기 위한 밀봉재는 크게 유리 및 결정화 유리계, mica및 mica/유리복합재료, 유리/충전재 복합재료 등이 사용되고 있으나 다수의 단위전지로 구성되는 스택 구성에서 스택의 열기계적 안정성 및 장기수명을 보장하기 위해서는 본 연구에서 개발하고자 하는 복합밀봉재가 가장 적합할 것으로 예상되고 있다. 본 연구에서는 $SiO_2-B_2O_3-RO$계에 BaO, SrO를 일정비율로 첨가하여 제작된 유리 frit을 열처리하여 물리화학적 물성변화를 검토하였으며, $700^{\circ}C$ 이하의 연화점을 갖는 유리를 기지상으로 하고 세라믹 보강재를 첨가한 고온형 복합밀봉재를 개발하고 그 물리화학적 안정성, 열기계적 안정성 및 밀봉 특성을 평가하였다.

• Journal of the Korean Society for Precision Engineering
• /
• v.21 no.12
• /
• pp.167-173
• /
• 2004

Recently, it has been reported that frictional behavior at nanometer scale can be different from that at macro scale. In this article, friction and wear tests were conducted using an AFM to investigate the effect of real contact area on the coefficient of friction and wear property. SiO$_2$, Hica, and SiGe were used in friction test and the AFM tip was Si$_3$N$_4$. The real contact area between an AFM tip and flat surface was calculated by the Johnson-Kendall-Roberts (JKR) theory. Wear specimen was Mica, and the diamond tip was used. We found that the coefficient of friction is constant below a critical area, but it is degraded over the area. Moreover, it is found that wear depth increased rapidly from a certain load and was degraded as a function of the number of the scanning cycles. Also, the range of scanning velocity used in this study had little effect on the wear depth.

• The Journal of the Petrological Society of Korea
• /
• v.11 no.3_4
• /
• pp.250-258
• /
• 2002

The wavy extinction of quartz can be used as a standard indicator showing the degree of rock deformation. To determine the degree of rock deformation, the intensity of wavy extinction (IWE) of quartz was measured using petroggraphic microscope, digital camera, and NIH image. In this study, this method was applied to the Cheongsan porphyritic granite, Cheongsan two mica granite, and Baekrok granite to investigate the deformation intensity of Cheongsan area. NIH Image data show a high-grade deformation in the vicinity of the strike-slip fault (between Cheongsan granite and Baekrok granite) and the unconformity (between Cheongsan granite and Youngdong basin). Thus, the main deformation in these areas is most likely to be concentrated on the faults that generate Yeongdong basin and the strike slip faults between Cheongsan granite and Baekrok granite.

• Journal of Environmental Science International
• /
• v.6 no.5
• /
• pp.489-496
• /
• 1997

The arm of this study is to determine harmful radioactive gas($Rn^{222}$)-concentrations in soils and to suggest the anormalous regions of $Rn^{222}$-concentration in Taejeon area. The range of $Rn^{222}$-concentration in the soils (45 samples) of the survey area is 100 to 2, 475 (pCi/L) and mean$\pm$$\sigma$ of those values is 489$\pm$ 505 (pCi/L). The 2% (4 samples) of soil-gas samples (45 ones) collected In the survey area is corresponded to high rusk level, 53% (24 samples) to medium one and 43% (19 samples) to low one. Especially. The $Rn^{222}$-concentration is relatively higher in schistose granite region than in other rock Mts (two-mica granite and biotite ganite) in the survey area. The $Rn^{222}$-concentration is propotional to the uranium contents in the soils. The soil hardness among the various factors is correlative with $Rn^{222}$-concentrations. To prevent the damage from $Rn^{222}$-concentrations, It is necessary to close the cracks of underground structure and to consider methods reducing $Rn^{222}$-concentration for the anormalous regions.

• Tunnel and Underground Space
• /
• v.21 no.4
• /
• pp.251-263
• /
• 2011

The geomechanical characteristics of rock and the structural geological feature of the fault should be studied and examined for the successful construction of large-span tunnel. In this case study, that is a important case for the tunnel collapse and reinforcement during the construction for the waterway tunnel at large thrust fault zone in schist, we carried out geological and geotechnical survey for make the cause and mechanism of tunnel collapse. Also, we have designed the reinforcement and re-excavation for the safe construction for collapse zone and have carried out successfully the re-excavation and finished the final concrete lining.

• Journal of Electrical Engineering and Technology
• /
• v.13 no.6
• /
• pp.2425-2433
• /
• 2018

This study investigates a new organic based material and its dielectric and mechanical properties. It is a comprehensive nanocomposite comprising a combination of various types of nanofillers with hydrophobic silica nanoparticles (AEROSIL R 974) as a matrix modifier and a polyamide nano nonwoven textile, Ultramid-Polyamide 6, pulped in the electrostatic field as a dielectric barrier. The polymer matrix is an epoxy network based on diglycidyl ether of bisphenol A (DGEBA) and cycloaliphatic diamine (Laromine C260). The designed nanocomposite material is an alternative to the conventional three-component composites containing fiberglass and mica with properties that exceed current electroinsulating systems (volume resistivity on the order of $10^{16}{\Omega}{\cdot}m$, dissipation factor tan ${\delta}=4.7{\cdot}10^{-3}$, dielectric strength 39 kV/mm).

• 한국신재생에너지학회:학술대회논문집
• /
• 2009.06a
• /
• pp.303-306
• /
• 2009

High temperature solid oxide fuel cells (SOFCs) offer a clean, pollution-free technology to electrochemically generate electricity at high efficiencies. Solid oxide fuel cells in several different designs have been investigated; these include planar and tubular geometries. The tubular type cell is widely researched due to it have advantages about thermal expansion and sealing issues. Unfortunately, lab scale tubular cell for testing has thermal expansion and sealing problems. The previous Jig for lab scale tubular cell testing has many sealing problems. When we feed fuel gas to jig inlet, ceramic glue sealant has amount of gas expansion pressure, because temperature of feeding gas changes ambient temperature to high temperature ($700{\sim}900^{\circ}C$). Furthermore, when we carry out long time test, something like degradation test, crack of ceramic glue sealant due to weakness of mechanical properties can make stop working the test. Additionally, we reduce setting process for assembling, because micanite is not required drying or debinding process.

• Economic and Environmental Geology
• /
• v.28 no.2
• /
• pp.139-145
• /
• 1995

Tungsten skarn mineralization of the Sangdong mine is localized in the interbedded limestone layers of the Myobong Slate Formation and in the limestone of the Pungchon Limestone Formation of Cambrian age. Fluid inclusion, gas composition and Nd-Sr isotope for granites and skarns have been investigated. Gas compositions show $CO_2$ rich in the Sangdong granite and CH, rich in the Nonggeori and Eopyeong granites. The initial $^{87}Sr/^{86}Sr$ and $^{143}Nd/^{144}Nd$ ratios of the Sangdong granites have 0.714~0.716(${\varepsilon}_{Sr}$=138~162) and 0.51173~0.51178(${\varepsilon}_{Nd}$=-14.4~15.5), respectively. And their two stage model ages range from 1687 to 1764 Ma. The granite characterized by high strontium initial ratios and negative eNd value could have originated from the old continental crust source. Low homogenization temperature of the Sangdong granite having $203{\sim}296^{\circ}C$ with 1.9~9.2 NaCl equiv. wt% indicates the post-magmatic hydrothermal alteration temperature. Skarn ore fluid responsible for tungsten mineralization has been evolved from CH, rich fluid of early pyroxene garnet skarn to $CO_2$ rich later quartz-mica skarn.

• Geomechanics and Engineering
• /
• v.20 no.4
• /
• pp.359-370
• /
• 2020

Prestressed ground anchors are important structural elements in geotechnical engineering. Despite their widespread usage, the design process is often significantly simplified. One of the major drawbacks of commonly used design methods is the assumption that skin friction is mobilized uniformly along an anchor's fixed length, one consequence of which is that a progressive failure phenomenon is neglected. The following paper introduces an alternative design approach - a computer algorithm employing the load-transfer method. The method is modified for the analysis of anchors and combined with a procedure for the derivation of load-transfer functions based on commonly available laboratory tests. The load-transfer function is divided into a pre-failure (hardening) and a post-failure (softening) segment. In this way, an aspect of non-linear stress-strain soil behavior is incorporated into the algorithm. The influence of post-grouting in terms of radial stress update, diameter enlargement, and grout consolidation is included. The axial stiffness of the anchor body is not held constant. Instead, it gradually decreases as a direct consequence of tensile cracks spreading in the grout material. An analysis of the program's operation is performed via a series of parametric studies in which the influence of governing parameters is investigated. Finally, two case studies concerning three investigation anchor load tests are presented.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2006.11a
• /
• pp.255-256
• /
• 2006

The electrical properties of viologen ($VC_8SH$) were studied in terms of the tunneling current characteristics using self-assembling techniques and ultra high vacuum scanning tunneling microscopy (UHV-STM). We fabricated the Au substrate were deposited by thermal evaporation system($420^{\circ}C$). Self-assembled monolayers (SAMs) were prepared on Au(111), which had been thermally deposited onto freshly cleaved, heated mica. The Au substrate was exposed to a 1 mM/L solution of Octanethiol in ethanol for 24 h to form a monolayer. After through rinsing the sample, it was exposed to a 0.1 mM/L solution of $VC_8SH$ in ethanol for 30 min. We measurement of the morphology on the single viologen molecule. The current-voltage (I-V) properties were measured at arbitary configured points on the surface of the sample by using a STS.