• Korean Chemical Engineering Research
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• v.44 no.3
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• pp.284-288
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• 2006

$(Ca,Sr)_{2-y}MgSi_2O_7:Eu^{2+}{_y}$ (CMS) phosphor particles were prepared by using a spray pyrolysis process. The luminescent property was optimized by changing the content of Eu and the post-treatment temperature. The luminescence characteristics were also monitored with changing the ratio of Ca to Sr. The pure tetragonal $Ca_2MgSi_2O_7$ or $Sr_2MgSi_2O_7$ particles were obtained when the post-treatment temperature was over $1,000^{\circ}C$. The highest emission intensity of CMS particles were achieved when the concentration (y) of Eu and the treatment temperature were 0.05 and $1,250^{\circ}C$,respectively. The emission wavelength $({\lambda}_{max})$ of ${(Ca_{1-x},Sr_x)}_{1.95}MgSi_2O_7:{Eu^{2+}}_{0.05}$ was gradually shifted from 524 nm to 456 nm with increasing the content of Sr due to the reduction of crystal field strength. The emission intensity and its width of $Sr_2MgSi_2O_7:Eu$ was greatly enhanced by substituting Ca of less than 10 mol％ for Sr without any significant peak shift. The morphology of as-prepared particles was spherical, but changed to irregular-shaped one after the post treatment at the temperature range from 900 at $1,300^{\circ}C$.

• Journal of the Korean Society of Marine Environment & Safety
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• v.19 no.6
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• pp.658-665
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• 2013

In this study, we measured particulate matter(PM) which emerged as the hot issue from the International Maritime Organization(IMO) and the exhaust emission using HANBADA, the training ship of Korea Maritime University. In particular, the PM was obtained with TEM grid. PM structure was observed by electron microscopy. And exhaust gases such as NOx, $CO_2$, and CO were measured using the combustion gas analyzer(PG-250A, HORIBA). The results of this study are as follows. 1) When the ship departed from the port, the maximum difference in PM emissions were up to 30 % due to the Bunker Change. 2) Under the steady navigation, emission of PM was $1.34mg/m^3$ when Bunker-A is changing L.R.F.O(3 %). And, at the fixed L.R.F.O (3 %), emission of PM was $1.19mg/m^3$. When the main engine RPM increased up to 20 % with fixed L.R.F.O(3 %), emission of PM was $1.40mg/m^3$. When we changed to low quality oil(L.R.F.O(3 %)), CO concentration from main engine increased about 16 %. On the other hand, when the main engine RPM is rising up to 20 %, CO concentration is increased more than 152 percent. These results imply that the changes of RPM is a dominant factor in exhaust emission although fuel oil type is an important factor. 3) The diameter of PM obtained with TEM grid is about $4{\sim}10{\mu}m$ and its structure shows porous aggregate.

• Korean Journal of Food Science and Technology
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• v.26 no.5
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• pp.596-602
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• 1994

To separate and concentrate mucilage from yam(Dioscorea batatas DECNE), yam was dried, microparticulated using impact mill and air-classified at different air classifying wheel speed(ACWS) in classifier. As ACWS increased from 5,000 rpm to 22,500 rpm, the contents of dietary fiber, protein and lipid of air classified microparticles(ACM) increased remarkably. Especially the ACM with ACWS over 15,000 rpm showed 36.41% dietary fiber and 16.66% protein. The dietary fiber and protein components were concentrated to $2.5{\sim}9.0$ times as compared with whole yam powder. Concomitantly the non-fibrous carbohydrate decreased from 88.31% to 16.84. The damaged starch(%), WSI and WAI of ACM of ACWS over 15,000 rpm were $1.5{\sim}3.0$ times higher than those of ACM under ACWS 15,000 rpm. The apparent viscosity of ACM was 0.0800 Pa s over ACWS 15,000 rpm and 0.0080 Pa s under ACWS 15,000 rpm. Judging from viscosity of ACM, the mucilage component of yam was concentrated to 10 times. In conclusion, the optimum process to separate and concentrate the mucilage from yam consisted of the microparticulation to $5{\sim}30{\mu}m$ and the air-classification at ACWS over 15,000 rpm.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.6
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• pp.329-337
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• 2019

We synthesized potassium titanates having splinter and plate shape and evaluated frictional and wear properties of brake pad using them as reinforcements in friction materials. For splinter-shaped potassium titanates, potassium tetratitanate (K₂O·4TiO₂, PT4) with plate shape was prepared, then K ion of the titanate was leached by acid to make potassium hexatitanate (K₂O·6TiO₂, PT6), which was transformed to splinter-shaped PT6 by thermal treatment at 800℃. Plate-shaped potassium magnesium titanate (K_0.8Mg_0.4Ti_1.6O₄, PMT) was prepared by adding Mg in the potassium titanate using KCl as a flux. Using PT6 and PMT as reinforcements in friction materials of brake pad, we evaluated frictional and wear properties using 1/5-scale dynamometer. According to dynamometer test results, both reinforcements shows similar friction coefficient and fade & recovery behavior to conventional material and plate-shaped PMT exhibits higher wear resistance than splinter-shaped PT6.

• Journal of the Korean Society of Food Science and Nutrition
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• v.32 no.7
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• pp.953-959
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• 2003

This study examined physicochemical properties of two waxy rice starches, shinsun and black rice starches. Proximate compositions of both samples were similar. The major minerals in the shinsun rice starches were Ca, Mg, P and Na, whereas those in black rice starches were Ca, P, Fe and Mg. The major particle size of shinsun rice starch was 6.97 micron and that of black rice starch was 6.27 micron. In iodine reaction, maximum absorbance wavelength (λmax) and absorbance at 625nm of black rice starch were higher than those of shinsun rice starch. Intrinsic viscosity of black rice starch (183mL/g) was higher than that of shinsun rice starch (178 mL/g). Water binding capacity was similar in both samples. Swelling power and solubility of black rice starch were lower than those of shinsun rice starch. X-ray diffraction patterns of all samples showed traditional A type of cereals as shown peaks at 15.2 (15.0), 17.2 (17.15), 18.05 (17.95), 23.25 (23.15)$^{\circ}$. The common shape of SEM was observed in both waxy rice starches.

• Applied Biological Chemistry
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• v.24 no.1
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• pp.59-66
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• 1981

Trichoxanthes Kirilowii with high starch-content was investigated to utilize as a food source. The weight and starch content of Trichoxanthes Kirilowii roots increased rapid1y in proporion to the growth period. The seasonal variations of the starch content were $36.5{\sim}48.0%$ (dry basis) from June to December. The chemical properties of natural growth soils of Trichoxanthes Kirilowii contained more organic matter and total nitrogen content than citrus orchard soils, but less mineral; P,K,Ca and Mg. To prepare starch with the plant root, the centrifugal method(3,000 rpm, 20 min) obtained the highest yield. The industrial-scale method, was similar to the processing of sweetpotato starch (tank precipitation method), and was good in quality. The starch granules were mainly spherical with diameters ranging from $5{\sim}16{\mu}$. The density of the starch was 1.535 and amylose content was about 26.7%. The X-ray diffraction pattern showed that the granules were of the B-type. The blue value of starch, amylose and amylopectin was 0.46, 0.80 and 0.18, respectively. The starch contained 0.05% ash, 0.35% crude protein and 34 mg% phosphorus. and had an inital pasting temperature of $63.5^{\circ}C$. The color intensity of the starch which iodine gave rise to absorption maxima at 670nm. The starch paste showed high stability during cold storage at $5^{\circ}C$.

• The Journal of the Petrological Society of Korea
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• v.6 no.2
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• pp.111-122
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• 1997

Provenance type and paleoclimate of the Jinju and Iljig formation were studied on the basis of compositions of sandstones from the western Euiseong area in the northern part of Kyong-sang basin. The average compositions of quartz, feldspar and lithic grain(Q:F:L) from the sandstones are 53:40:7 and 50:46:4 for Jinju and Iljig formations, respectively. The values fall into the arkosic arenite field. Petrographic detrital modes of the sandstones mainly suggest transitional continental block for the tectonic setting of the provenance. All sandstones from the Jinju and IIjig formations show chemical compositions close to average values of arkose(Pettijohn, 1975). $Na_2O$ contents is relatively high. $Fe_2O_3$(total iron) and MgO contents decrease with increasing $SiO_2$ contents since the framework grains of arkoses supposed to be derived from granitic rocks are poor in ferromagnesian minerals. The detrital framework grains still possess climatic signs even though the grains were more or less altered during deep burial. Bivariant plot of Suttner and Dutta(1986) suggests semi-arid to semi-humid paleoclimate during the deposition of the Jinju and Iljig sandstones.

• Journal of the Korea Organic Resources Recycling Association
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• v.22 no.3
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• pp.23-32
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• 2014

Recently, it is increase in the processing of organic waste using anaerobic digestion. Therefore, the studies on the processing method for increasing the anaerobic digestion waste water. But it is very difficult to solid-liquid separation, because the characteristics of anaerobic digestion waste water. So this study evaluate solid-liquid separation efficiency of anaerobic digestion sludge using CST(Capillary Suction Time), TTF(Time to Filter). To address this problem, a membrane filter press of the lab scale was produced and the anaerobic digestion wastewater was applied to it. Polymer coagulants were found to be most suitable 7192PLUS and 1T60, It is necessary to minimum injection concentration is 7192PLUS (200 mg/L), 1T60 (100 mg/L). To evaluate dehydration efficiency, it was measured the moisture content of the dehydrated cake and suspended solids of decanted water. As a result, showed that a high removal efficiency of 97.4% when the solid-liquid separation using the membrane filter press. And the moisture content of the dehydrated cake was less than 65%.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.4
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• pp.775-784
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• 2000

Nitrate dry deposition fluxes were directly measured using knife-leading-edge surrogate surface (KSS) covered with greased strips and a water surface sampler (WSS). The average gaseous flux ($8.3mg/m^2/day$) was much higher than the average particulate one ($3.0mg/m^2/day$). The best fit gas phase mass transfer coefficient (MTC) of $HNO_3$ was obtained by linear regression analysis between measured gaseous flux containing nitrogen compounds and measured ambient $HNO_3$ concentration. The result showed that the MTCs of $HNO_3$ were approximately two times higher than those of $SO_2$. Especially, during the ozone action day, measured gaseous fluxes containing nitrogen compounds were much higher than those ones calculated as the product of measured ambient $HNO_3$ concentration and gas phase MTC of $HNO_3$, which is calculated from MTC of $SO_2$ using Graham's diffusion law. This result indicated that other nitrogen compounds except $HNO_3$ contributed to gaseous flux containing nitrogen compounds into the water surface sampler. The theoretical calculations suggest the contributions of nitrous acid ($HNO_2$) and PAN to the gaseous dry deposition flux of nitrogen containing compounds to the WSS.

• Resources Recycling
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• v.26 no.3
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• pp.79-91
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• 2017

The core of Hydrogen Fuel Cell Vehicles (FCV) is polymer solid fuel cell (PEFC), and the core material that generates electrochemical electricity in the cell is platinum catalyst. Platinum is localized in South Africa and Russia, and the world production of Pt is about 178 tons per year, which is expensive and recycled. At present, the amount of Pt used in PEFC is $0.2{\sim}0.1mg/cm^2$. In order to reduce the price of the battery and increase the FCV supply, the target is to reduce the amount of Pt used to $0.05{\sim}0.03mg/cm^2$. $Pt-Pd/Al_2O_3$, Pt/C, Pt/GCB, Pt/Au/C, PtCo/C, PtPd/C, etc. by using polyol method using nano Pt, improved Cu-UPD/Pt substitution method and nano-capsule method, Have been researched and developed, and there have been reported techniques for improving the activity of Pt catalysts and stabilizing them. This paper investigates the production technology of nano-Pt and nano-Pt catalysts, recycling of spent Pt catalysts and application trends of Pt catalysts.